GB709033A - Improvements in or relating to adhesive compositions - Google Patents

Improvements in or relating to adhesive compositions

Info

Publication number
GB709033A
GB709033A GB30444/51A GB3044451A GB709033A GB 709033 A GB709033 A GB 709033A GB 30444/51 A GB30444/51 A GB 30444/51A GB 3044451 A GB3044451 A GB 3044451A GB 709033 A GB709033 A GB 709033A
Authority
GB
United Kingdom
Prior art keywords
vinyl
dichlorobutadiene
chlorinated
butadiene
styrene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB30444/51A
Inventor
Leroy Benjamin Kuhn
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bridgestone Firestone Inc
Original Assignee
Firestone Tire and Rubber Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Firestone Tire and Rubber Co filed Critical Firestone Tire and Rubber Co
Priority to GB30444/51A priority Critical patent/GB709033A/en
Publication of GB709033A publication Critical patent/GB709033A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J119/00—Adhesives based on rubbers, not provided for in groups C09J107/00 - C09J117/00
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
    • C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
    • C08L2666/04—Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

An adhesive composition comprises (1) a resinous polymer of 2, 3-dichlorobutadiene-1, 3 or a copolymer thereof containing at least 60 per cent. 2, 3-dichlorobutadiene-1, 3, (2) a bodying resin comprising (a) neoprene, polyvinyl or polyvinylidene chloride or (b) rubber, balata, gutta percha, Chilte gum, polybutadiene, polyisoprene or a butadiene-styrene copolymer, all the resins under (a) being chlorinated and all under (b) being chlorinated, hydrochlorinated or chlorinated-hydrochlorinated, and (3) an organic solvent. It is preferred that crude 2, 3-dichlorobutadiene-1, 3 is used since this contains minor proportions of such compounds as 1, 2-dichlorobutadiene-1, 3 and the chlorovinyl acetylenes which copolymerize therewith to form the basic resin. Specified copolymeriz-, able monomers are vinyl chloride, fluoride bromide, acetate, propionate, benzoate and alkyl sulphones, vinyl ethyl ether, vinyl ethyl sulphide, vinyl b -chloro-ethyl ether, vinyl phenyl ether, vinyl ethyl ketone, vinyl phenyl ketone, styrene, a -methyl styrene, nuclearly chlorinated styrene, vinyl carbazole, methyl acrylate, methyl methacrylate, ethyl chloroacrylate, acrylonitrile, methacrylonitrile, acrolein, vinylidene chloride or bromide, 1-fluoro-1-chloro-ethylene, coumarone, indene, 4-methylene-1, 3-dioxolane, butadiene, chloroprene, isoprene, 2-3-dimethyl butadiene-1, 3, piperylene and divinyl ketone. Specified solvents are carbon tetrachloride, trichloroethylene, orthodichlorobenzene, chlorobenzene, benzene, toluene, xylene, ethylene dichloride, hexane, cyclohexane, acetone, methyl ethyl ketone and ethyl acetate. Petronizing agents such as thiourea, di-o-tolylthiourea, hexamethylenetetramine, diphenylguanidine, di-o-tolylguanidine, 2-mercaptobenzothiazole and zinc butylxanthate as well as non-reinforcing carbon black may also be present. The composition may be in the form of a broken-down gel, said gel having been formed by heating the composition to above 60 DEG C., to dissolve the mass and then cooling with vigorous agitation.ALSO:An adhesive composition comprises (1) a resinous polymer of 2, 3-dichlorobutadiene- 1, 3 or a copolymer thereof containing at least 60 per cent. 2-3-dichlorobutadiene- 1, 3, (2) a bodying resin, comprising rubber, balata, gutta percha, Chilte gum, neoprene, polybutadiene, polyisoprene or a butadiene-styrene copolymer which has been chlorinated, hydrochlorinated or chlorinated-hydrochlorinated and (3) an organic solvent. Specified solvents are carbon tetrachloride, trichloroethylene, a dichlorbenzene, chlorobenzene, benzene, toluene, xylane, ethylene dichloride, hexane, cyclo-hexane, acetone, methylethylketone and ethyl acetate. Petronizing agents such as thiourea, di-o-tolythiourea, hexamethylenetetramine, diphenylbuanidine, di-o-tolyl guanidine, 2-mercapto-benzothiazole and zinc butyl xanthate as well as non-reinforcing carbon black may also be present. The composition may be in the form of a broken-down gel, said gel having been formed by heating the composition to above 60 DEG C. to dissolve the mass and then cooling with vigorous agitation. The adhesive composition may be employed in the production of adhered structures in which the substrate is metal and the superstrate is an elastomer, e.g. rubber, a butadiene-styrene or butadiene-acrylonitrile copolymer, polychloroprene, lactoprene, polyisoprene, butyl rubber or polybutadiene.
GB30444/51A 1951-12-31 1951-12-31 Improvements in or relating to adhesive compositions Expired GB709033A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB30444/51A GB709033A (en) 1951-12-31 1951-12-31 Improvements in or relating to adhesive compositions

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB30444/51A GB709033A (en) 1951-12-31 1951-12-31 Improvements in or relating to adhesive compositions

Publications (1)

Publication Number Publication Date
GB709033A true GB709033A (en) 1954-05-12

Family

ID=10307775

Family Applications (1)

Application Number Title Priority Date Filing Date
GB30444/51A Expired GB709033A (en) 1951-12-31 1951-12-31 Improvements in or relating to adhesive compositions

Country Status (1)

Country Link
GB (1) GB709033A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1263307B (en) * 1963-11-04 1968-03-14 Borg Warner Process for the preparation of dichlorobutadiene copolymers
DE1570245B1 (en) * 1964-03-25 1970-04-23 Borg Warner Process for the preparation of copolymers of 2,3-dichlorobutadiene (1,3)
EP0509721A1 (en) * 1991-04-17 1992-10-21 Lord Corporation Halofunctional monomeric adhesion promoters and adhesive compositions
CN113008050A (en) * 2021-03-25 2021-06-22 常熟市江南粘合剂有限公司 Special glue for PVC cooling tower filler, production method and production device thereof

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1263307B (en) * 1963-11-04 1968-03-14 Borg Warner Process for the preparation of dichlorobutadiene copolymers
DE1570245B1 (en) * 1964-03-25 1970-04-23 Borg Warner Process for the preparation of copolymers of 2,3-dichlorobutadiene (1,3)
EP0509721A1 (en) * 1991-04-17 1992-10-21 Lord Corporation Halofunctional monomeric adhesion promoters and adhesive compositions
CN113008050A (en) * 2021-03-25 2021-06-22 常熟市江南粘合剂有限公司 Special glue for PVC cooling tower filler, production method and production device thereof
CN113008050B (en) * 2021-03-25 2022-07-19 常熟市江南粘合剂有限公司 Special glue for PVC cooling tower filler, production method and production device thereof

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