GB700731A - Improvements in or relating to the production of cation exchangers - Google Patents
Improvements in or relating to the production of cation exchangersInfo
- Publication number
- GB700731A GB700731A GB30176/51A GB3017651A GB700731A GB 700731 A GB700731 A GB 700731A GB 30176/51 A GB30176/51 A GB 30176/51A GB 3017651 A GB3017651 A GB 3017651A GB 700731 A GB700731 A GB 700731A
- Authority
- GB
- United Kingdom
- Prior art keywords
- capacity
- acid
- treatment
- volume
- ion
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J39/00—Cation exchange; Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
- B01J39/08—Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
- B01J39/24—Carbon, coal or tar
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treatment Of Water By Ion Exchange (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
The ion-exchanging capacity by volume of cation-exchange material prepared from solid carbonaceous materials by the process of the parent Specification is increased by a subsequent treatment with an acid to bring about a decrease in volume of the material. The preferred acid is hydrochloric; sulphuric acid of a concentration greater than 50 per cent. by weight and nitric acid of all concentrations are unsuitable because of their water-adsorbing and oxidizing actions on the material. To avoid the use of large volumes of solution the pH value of the acid solution should be less than 2. The treatment is effected preferably at normal temperatures but the temperature should not exceed 60 to 70 DEG C. With material having a capacity of approximately 1,000 m.eq. CaO per litre the treatment may be effected with 100 ml. 38 per cent. HCl or 1 litre normal HCl, the resulting volume-decrease being about 25 per cent. of the original volume. The amount of acid required varies directly as the ion-exchanging capacity. Since the total-weight-capacity of the material is increased a little by the treatment the increase in volume-capacity amounts to from 30 to 35 per cent. The "breakthrough" capacity of the material in the H-ion-exchanging p form is less than that of the material in the neutral form. The material is therefore transformed, after the acid-treatment (which has converted it into the H-ion-exchanging form), into the salt form, by washing with a neutral or weakly-alkaline salt solution such as sodium carbonate or sodium acetate. Liquids exhibiting a more alkaline reaction should not be used since they cause a swelling of the material. Examples of the process are given in the Specification.ALSO:The ion-exchanging capacity by volume of cation-exchange material prepared from solid carbonaceous materials by the process of the parent Specification is increased by a subsequent treatment with an acid to bring about a decrease in volume of the material. The preferred acid is hydrochloric; sulphuric acid of a concentration greater than 50 per cent by weight and nitric acid of all concentrations are unsuitable because of their water-absorbing and oxidizing actions on the material. To avoid the use of large volumes of solution the pH value of the acid solution should be less than 2. The treatment is effected preferably at normal temperatures but the temperature should not be above 60 to 70 DEG C. With material having a capacity of approximately 1000 m.e.q. CaO per litre the treatment may be effected with 100 ml. 38 per cent HCl or 1 litre normal HCl, the resulting volume-decrease being about 25 per cent of the original volume. The amount of acid required varies directly as the ion-exchanging capacity. Since the total weight-capacity of the material is increased a little by the treatment the increase in volume-capacity amounts to from 30 to 35 per cent. The "break-through" capacity of the material in the H-ion-exchanging form is less than that of the material in the neutral form. The material is therefore transformed after the acid-treatment (which has converted it into the H-ion-exchanging form), into the salt form, by washing with a neutral or weakly-alkaline salt solution such as sodium carbonate or sodium acetate. Liquids exhibiting a more alkaline reaction should not be used since they cause a swelling of the material. Examples of the process are given in the Specification.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
NL700731X | 1950-12-29 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB700731A true GB700731A (en) | 1953-12-09 |
Family
ID=19810118
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB30176/51A Expired GB700731A (en) | 1950-12-29 | 1951-12-24 | Improvements in or relating to the production of cation exchangers |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB700731A (en) |
-
1951
- 1951-12-24 GB GB30176/51A patent/GB700731A/en not_active Expired
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