GB694489A - Benzoxazine derivatives - Google Patents
Benzoxazine derivativesInfo
- Publication number
- GB694489A GB694489A GB104150A GB104150A GB694489A GB 694489 A GB694489 A GB 694489A GB 104150 A GB104150 A GB 104150A GB 104150 A GB104150 A GB 104150A GB 694489 A GB694489 A GB 694489A
- Authority
- GB
- United Kingdom
- Prior art keywords
- paraformaldehyde
- aliphatic hydrocarbon
- substituted
- octylphenol
- obtainable
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D265/00—Heterocyclic compounds containing six-membered rings having one nitrogen atom and one oxygen atom as the only ring hetero atoms
- C07D265/04—1,3-Oxazines; Hydrogenated 1,3-oxazines
- C07D265/12—1,3-Oxazines; Hydrogenated 1,3-oxazines condensed with carbocyclic rings or ring systems
- C07D265/14—1,3-Oxazines; Hydrogenated 1,3-oxazines condensed with carbocyclic rings or ring systems condensed with one six-membered ring
- C07D265/16—1,3-Oxazines; Hydrogenated 1,3-oxazines condensed with carbocyclic rings or ring systems condensed with one six-membered ring with only hydrogen or carbon atoms directly attached in positions 2 and 4
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
Abstract
The invention comprises 3 : 4-dihydro 1 : 3-benzoxazines substituted in the 3 (N) position by aliphatic hydrocarbon radicles which may carry a OH group, in the 6-position by halogen or saturated aliphatic hydrocarbon, and in the 5, 7 or 8 positions by hydrogen, halogen or saturated aliphatic hydrocarbon, obtainable by interacting p-substituted phenols with formaldehyde and aliphatic primary amines in the molecular ratio of 1 : 2 : 1. At least one of the substituents must be a radicle of at least 8 C atoms. The intermediately obtainable o-alkylaminomethyl - p - substituted phenol, or N : N-dimethylolamine may be isolated, if desired. In examples 2 : 4 di-t-octyl-phenol and p-t-octylphenol are condensed with paraformaldehyde and methylamine, p-cresol with paraformaldehyde and octadecylamine, p-tert. octylphenol with paraformaldehyde and monoethanolamine, or n-propylamine, 3 : 4-dimethylphenol with paraformaldehyde and dodecylamine. Other phenols specified include p-dodecylphenol, and 2 : 4-dichlorphenol.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB104150A GB694489A (en) | 1950-01-16 | 1950-01-16 | Benzoxazine derivatives |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB104150A GB694489A (en) | 1950-01-16 | 1950-01-16 | Benzoxazine derivatives |
Publications (1)
Publication Number | Publication Date |
---|---|
GB694489A true GB694489A (en) | 1953-07-22 |
Family
ID=9715120
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB104150A Expired GB694489A (en) | 1950-01-16 | 1950-01-16 | Benzoxazine derivatives |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB694489A (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2897113A (en) * | 1956-04-30 | 1959-07-28 | Dow Chemical Co | Fungicidal compositions comprising 6-alkyl - 3 - cyclohexyl - 3,4 - dihydro-2h-1,3-benzoxazines and method of use |
US3519624A (en) * | 1966-07-20 | 1970-07-07 | Ciba Ltd | Antimicrobial preparations containing n-acyl-3,4-dihydro-oxazines-(1,3) |
FR2043464A1 (en) * | 1969-05-09 | 1971-02-19 | Squibb & Sons Inc | Benzoxazine and benzothiazine derivs cns depressants |
WO1995031447A1 (en) * | 1994-05-18 | 1995-11-23 | Edison Polymer Innovation Corporation | Preparation of benzoxazine compounds in solventless systems |
-
1950
- 1950-01-16 GB GB104150A patent/GB694489A/en not_active Expired
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2897113A (en) * | 1956-04-30 | 1959-07-28 | Dow Chemical Co | Fungicidal compositions comprising 6-alkyl - 3 - cyclohexyl - 3,4 - dihydro-2h-1,3-benzoxazines and method of use |
US3519624A (en) * | 1966-07-20 | 1970-07-07 | Ciba Ltd | Antimicrobial preparations containing n-acyl-3,4-dihydro-oxazines-(1,3) |
FR2043464A1 (en) * | 1969-05-09 | 1971-02-19 | Squibb & Sons Inc | Benzoxazine and benzothiazine derivs cns depressants |
WO1995031447A1 (en) * | 1994-05-18 | 1995-11-23 | Edison Polymer Innovation Corporation | Preparation of benzoxazine compounds in solventless systems |
US5543516A (en) * | 1994-05-18 | 1996-08-06 | Edison Polymer Innovation Corporation | Process for preparation of benzoxazine compounds in solventless systems |
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