GB692184A - Improvements in or relating to crease proofing cotton and linen fabrics - Google Patents

Improvements in or relating to crease proofing cotton and linen fabrics

Info

Publication number
GB692184A
GB692184A GB23149/48A GB2314948A GB692184A GB 692184 A GB692184 A GB 692184A GB 23149/48 A GB23149/48 A GB 23149/48A GB 2314948 A GB2314948 A GB 2314948A GB 692184 A GB692184 A GB 692184A
Authority
GB
United Kingdom
Prior art keywords
acid
per cent
fabric
solution
lbs
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB23149/48A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Joseph Bancroft and Sons Co
Original Assignee
Joseph Bancroft and Sons Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Joseph Bancroft and Sons Co filed Critical Joseph Bancroft and Sons Co
Publication of GB692184A publication Critical patent/GB692184A/en
Expired legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/51—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof
    • D06M11/55—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof with sulfur trioxide; with sulfuric acid or thiosulfuric acid or their salts
    • D06M11/56—Sulfates or thiosulfates other than of elements of Groups 3 or 13 of the Periodic Table
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/38—Oxides or hydroxides of elements of Groups 1 or 11 of the Periodic Table
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/44—Oxides or hydroxides of elements of Groups 2 or 12 of the Periodic Table; Zincates; Cadmates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/51—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof
    • D06M11/55—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof with sulfur trioxide; with sulfuric acid or thiosulfuric acid or their salts
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/58—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides
    • D06M11/59—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides with ammonia; with complexes of organic amines with inorganic substances
    • D06M11/62—Complexes of metal oxides or complexes of metal salts with ammonia or with organic amines
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/58—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides
    • D06M11/66—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides with sulfamic acid or its salts
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/68—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with phosphorus or compounds thereof, e.g. with chlorophosphonic acid or salts thereof
    • D06M11/70—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with phosphorus or compounds thereof, e.g. with chlorophosphonic acid or salts thereof with oxides of phosphorus; with hypophosphorous, phosphorous or phosphoric acids or their salts
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/68—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with phosphorus or compounds thereof, e.g. with chlorophosphonic acid or salts thereof
    • D06M11/70—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with phosphorus or compounds thereof, e.g. with chlorophosphonic acid or salts thereof with oxides of phosphorus; with hypophosphorous, phosphorous or phosphoric acids or their salts
    • D06M11/71—Salts of phosphoric acids
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/192—Polycarboxylic acids; Anhydrides, halides or salts thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/402—Amides imides, sulfamic acids
    • D06M13/432—Urea, thiourea or derivatives thereof, e.g. biurets; Urea-inclusion compounds; Dicyanamides; Carbodiimides; Guanidines, e.g. dicyandiamides
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/402—Amides imides, sulfamic acids
    • D06M13/438—Sulfonamides ; Sulfamic acids
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/39—Aldehyde resins; Ketone resins; Polyacetals
    • D06M15/423—Amino-aldehyde resins
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/39—Aldehyde resins; Ketone resins; Polyacetals
    • D06M15/423—Amino-aldehyde resins
    • D06M15/43—Amino-aldehyde resins modified by phosphorus compounds
    • D06M15/433—Amino-aldehyde resins modified by phosphorus compounds by phosphoric acids

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

Cotton and linen fabrics are impregnated with an aqueous solution of a polybasic acid and a nitrogen-containing compound basic toward the acid, baked to produce a complex of the acid, nitrogen compound and cellulose, swollen and finally neutralized. The treated fabric is crease-resistant. The acid may have at least two replaceable hydrogen atoms or at least three replaceable hydrogen atoms only one of which is replaced by a metal. Thus any acid of phosphorus or sulphur with at least two replaceable hydrogens, free of constituents yielding active oxygen or chlorine during the processing, substantially non-volatile and not containing organic groups of more than 4 carbon atoms, and salts of such acids wherein the replaceable hydrogens are replaced by an anion volatile during the process to give the acid may be employed. The acid may also be a polycarboxylic acid having a molecular weight not over 200 such as phthalic, malonic, succinic or glutaric acid. It may be used in concentrations of between 2 and 30 per cent by weight of the solution. The preferred range is from 2 to 16 per cent with 100 per cent pick-up on the fabric, but concentrations above 16 per cent are preferred when using organic acids. The nitrogen - containing compound may be an organic base having an atomic ratio of carbon to nitrogen of not more than 2 to 1, such as urea, dicyandiamide, biuret, acetamide, cyanoacetamide, guanidine bicarbonate, aminoguanidine carbonate, biguanide, guanidine, or mixtures thereof. For ease of control, strong bases may be mixed with more weakly basic compounds. Preferably the base is used in amounts of 1 to 4 mols. per mol. of acid; higher amounts up to 10 mols. are permissible. The temperature of baking may be between 400 DEG and 280 DEG F. (preferably 350 DEG to 300 DEG F.) and the time of baking from 2 to 30 minutes (preferably 4 to 15 minutes). The conditions of treatment, concentration, &c. may be selected so that sufficient of the acid-forming element or acyl radical will remain in the fabric after washing and drying. In the case of orthophosphoric acid, the cured, washed and dried fabric may contain from 0.5 to 5 per cent of phosphorus, equivalent to 1.5 to 15 per cent of acid. The proportion of nitrogen carried into the fabric varies with the basic compound used; for urea it may be 0.25 to 1.5 per cent by weight of the dry fabric, and with more complex compounds from 0.5 to 6 per cent. During the curing a pH of 2 to 7 should be reached on the fabric. After curing or baking, and, if desired, washing or washing and drying, the fabric is swollen, preferably with 30 per cent sodium hydroxide solution for 45 seconds at room temperature. The concentration may, however, vary from 10 to 50 per cent and the time of swelling from 5 to 180 seconds. Preferably the fabric is under tension and is immediately washed after swelling whilst still under tension and neutralized with a weakly acidic solution or sodium bicarbonate. Other conventional swelling agents except those liberating free halogens may be used, such as caustic soda-cuprammonium, caustic soda-sodium zincate, or concentrated calcium thiocyanate. Caustic soda supercooled to -10 DEG C. may also be employed. The fabric, after washing and neutralizing, is finally dried. Prior to, or after drying, the fabric may be treated with a solution of a softening agent. If desired, aldehydes such as formaldehyde (paraformaldehyde, hexamethylene tetramine) or glyoxal may be incorporated in the solution containing the acid and nitrogen-containing compound, in amounts from 0.2 to 3 mols. of aldehyde per mol. of acid on the basis of phosphoric acid. Part or all of the aldehyde and some of the nitrogen-containing compound may be replaced by water-soluble condensates such as those of urea-formaldehyde, urea-glyoxal, and melamine-formaldehyde, added either directly to the impregnating solution or used as a pretreatment. In these circumstances, it is preferred to adjust the pH of the solution to neutral or slightly alkaline with ammonia to prevent condensation and consequent precipitation of the resin. In an example an impregnating solution is prepared from 60 lbs. of 75 per cent orthophosphoric acid, 40 lbs. of dicyandiamide, 120 lbs. of urea, 60 lbs. of 28 per cent ammonia and 80 lbs. of 37 per cent formaldehyde, made up to 100 U.S. gallons with water. A printed cotton fabric is impregnated, squeezed, dried and baked for 6 minutes at 320 DEG F. It is then swollen with 30 per cent caustic soda in a mercerizer, washed with warm water while still under tension, and then with sodium bicarbonate solution. It is finally impregnated with a 2 per cent solution of a cationic softener, squeezed and dried. Specifications 604,197 and 648,883, [both in Group VIII], are referred to. The Specification as open to inspection under Sect. 91 also includes an example in which the impregnating solution is prepared from 200 lbs. of sulphamic acid and 200 lbs. urea made up to 100 gallons with water. This subject-matter does not appear in the Specification as accepted.
GB23149/48A 1948-04-07 1948-09-02 Improvements in or relating to crease proofing cotton and linen fabrics Expired GB692184A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US692184XA 1948-04-07 1948-04-07

Publications (1)

Publication Number Publication Date
GB692184A true GB692184A (en) 1953-06-03

Family

ID=22087495

Family Applications (1)

Application Number Title Priority Date Filing Date
GB23149/48A Expired GB692184A (en) 1948-04-07 1948-09-02 Improvements in or relating to crease proofing cotton and linen fabrics

Country Status (4)

Country Link
BE (1) BE485739A (en)
FR (1) FR973934A (en)
GB (1) GB692184A (en)
NL (1) NL76349C (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1079586B (en) * 1956-12-05 1960-04-14 Phrix Werke Ag Process for the finishing of textiles made from natural or regenerated cellulose

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0044172A1 (en) * 1980-07-03 1982-01-20 Lintrend Licensing Company Limited Fibrous product containing viscose

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1079586B (en) * 1956-12-05 1960-04-14 Phrix Werke Ag Process for the finishing of textiles made from natural or regenerated cellulose
DE1083777B (en) * 1956-12-05 1960-06-23 Phrix Werke Ag Process for the finishing of textiles made from natural or regenerated cellulose
DE1086206B (en) * 1956-12-05 1960-08-04 Phrix Werke Ag Process for the finishing of textiles made from natural or regenerated cellulose

Also Published As

Publication number Publication date
BE485739A (en)
FR973934A (en) 1951-02-16
NL76349C (en)

Similar Documents

Publication Publication Date Title
US2482756A (en) Flameproofing of fibrous materials
GB890515A (en) Preventing odours in filamentary or sheet material treated with thermosetting aldehyde resins
US3784356A (en) Cellulosic flame retardant system
JPS5921782A (en) Improved fabric treating agent and method
US2530261A (en) Fireproofing and creaseproofing of cellulose and protein textiles
US3357784A (en) Exposure to intense ultraviolet light to improve characteristics of cellulosic fabrics in divinyl sulfone and glyoxal cross-linking processes
US3101278A (en) Flame proofing of cellulosic materials
GB692184A (en) Improvements in or relating to crease proofing cotton and linen fabrics
US2602017A (en) Monomethylol dimethyl hydantoin to shrinkproof cellulose fabrics
US2654720A (en) Treatment of textiles and n-halogenated amine-aldehyde agents therefor
US2911326A (en) Treatment of cellulosic fiber and composition therefor
US3441366A (en) Wrinkle-resistant cotton fabrics with improved moisture absorption
US3090665A (en) Reaction mixture of formaldehyde-hydrazide-triazone for treating cellulosic textiles
US4219631A (en) Modified urea-formaldehyde resin
US3058849A (en) Crease-resistant resin composition for textiles
US3948600A (en) Selected ammonium sulfonate catalysts for an improved process utilizing mild curing conditions in durable press finishing of cellulose-containing fabrics
US4376633A (en) Zwitterion compounds as catalysts in easy-care finishing
US4307146A (en) Process for resin-finishing of textile fabrics and knitted goods
US2928758A (en) Treating process
US2850407A (en) Textile finishing compositions containing adduct of beta-amino lower alkyl carbamateand formaldehyde, method of applying same, and the treated textile
Chance et al. The treatment of cotton with formaldehyde in calcium chloride solutions
GB871105A (en) Improvements in the incorporation of thermosetting synthetic resins in linen textilefabrics
US3002859A (en) Compositions, textiles treated therewith and processes for the treatment thereof
US2738292A (en) Fabric stabilized with non-chlorine retentive resin, method of producing the same, and method of preparing the resin
US4039282A (en) Durable-press finishing of cellulose-containing textiles with aluminum chlorhydroxide-hydrogen peroxide catalyst system