GB680322A - Improvements in or relating to a method of and apparatus for pickling of iron and steel materials - Google Patents
Improvements in or relating to a method of and apparatus for pickling of iron and steel materialsInfo
- Publication number
- GB680322A GB680322A GB16435/48A GB1643548A GB680322A GB 680322 A GB680322 A GB 680322A GB 16435/48 A GB16435/48 A GB 16435/48A GB 1643548 A GB1643548 A GB 1643548A GB 680322 A GB680322 A GB 680322A
- Authority
- GB
- United Kingdom
- Prior art keywords
- tank
- pipe
- passes
- pickling
- liquor
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/36—Regeneration of waste pickling liquors
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/02—Cleaning or pickling metallic material with solutions or molten salts with acid solutions
- C23G1/08—Iron or steel
- C23G1/081—Iron or steel solutions containing H2SO4
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G3/00—Apparatus for cleaning or pickling metallic material
- C23G3/02—Apparatus for cleaning or pickling metallic material for cleaning wires, strips, filaments continuously
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G3/00—Apparatus for cleaning or pickling metallic material
- C23G3/02—Apparatus for cleaning or pickling metallic material for cleaning wires, strips, filaments continuously
- C23G3/027—Associated apparatus, e.g. for pretreating or after-treating
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S423/00—Chemistry of inorganic compounds
- Y10S423/01—Waste acid containing iron
- Y10S423/02—Sulfuric acid
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
- Vaporization, Distillation, Condensation, Sublimation, And Cold Traps (AREA)
Abstract
<PICT:0680322/III/1> <PICT:0680322/III/2> In a continuous process of pickling iron and steel and regenerating the spent liquor by precipitating ferrous sulphate, the liquor, both during pickling and regenerating, is maintained at a temperature between 180 DEG and 220 DEG F, the ferrous sulphate being thus precipitated as the monohydrate. Steel strip passes through pickling tanks 10...13, concurrently with pickling acid, the latter being withdrawn from the tank 13 by a pump 16 whence it passes to regenerating tanks comprising a mixing tank 21 where fresh acid is added (at 22), an evaporating tank 23 to which heat is supplied, a settling tank 25 and a dilution tank 30 to which fresh water is supplied at 37. The sulphate slurry <PICT:0680322/III/3> from the tank 25 and any crystals settling in the tanks 21, 23, pass to a filter 32 to which cold water is supplied at 33, the filtered liquor being pumped at 35 to the tank 30. The liquid level is controlled by a float 40 in the tank 30 which also has an overflow 41. A hot air inlet 38 is also provided in the filter 32. In the form shown in Fig. 2, the strip is heated at 57 to 240-250 DEG F before immersion in the first of the pickling tanks 50...53, is sprayed with warm water at 60, as it passes from the first to the second tank, and at 61 and immersed in warm water in a tank 64 after leaving the last pickling tank 53. The spent liquor from the tank 53 passes through the pipe 56 to a surge tank 71, pipes 70 being provided for flushing when necessary, and thence is pumped at 72 to the filter 73 and mixing tank 75 where acid is added from the tank 76 via the pump 77. From the tank 75, the liquor is pumped at 80 to a spray 82 in a stream of hot gas supplied from the furnace 83, an air byepass 87 being provided to regulate the temperature. 85 is a blower supplying the furnace and byepass. The liquor and gases pass to a centrifugal evaporator 90 from which the gases are withdrawn through the pipe 92 and to which additional water may be supplied through the sprays 91. The rinse water from the tanks 62, 64, passes through the pipe 63 and is introduced into the pipe 92 through the spray 93, whence together with the cooled gases and condensate, it passes to the separator 94, gas then passing to a precipitator 96 from which any precipitated acid may be passed to the tank 75 through the pipe 97. The concentrated liquid from the separator 90 passes to a settling tank 101 from which moisture laden air passes through the pipe 103 to the pipe 92 and to which hot gases are supplied from the furnace 83 through the pipe 104; steam coils 107 are also provided in the tank 101. Recirculation of liquor through the spray 82 and tank 101 may be ensured by provision of a pipe 105 and pump 106 discharging into the pipe 81. Supernatant liquid from the tank 101 passes to a dilution tank 111 to which water is supplied from the separator 94 through the pipe 112, the diluted liquor passing through the pipe 54 to the first pickling tank 50. The sulphate precipitated in the tank 101 discharges to a filter 114 where it is washed with cold water and removed to a drier 117. The liquid from the filter 114 passes to a receiver 121 whence it may be pumped at 122 to the dilution tank 111. Vapour from the receiver 121 passes to a condenser 125 and moisture trap 126, condensate from both passing to the pump 122.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US757008A US2668130A (en) | 1947-06-25 | 1947-06-25 | Apparatus and method for continuous pickling and regeneration of contact acid |
Publications (1)
Publication Number | Publication Date |
---|---|
GB680322A true GB680322A (en) | 1952-10-01 |
Family
ID=25045981
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB16435/48A Expired GB680322A (en) | 1947-06-25 | 1948-06-18 | Improvements in or relating to a method of and apparatus for pickling of iron and steel materials |
Country Status (4)
Country | Link |
---|---|
US (1) | US2668130A (en) |
BE (1) | BE483353A (en) |
FR (1) | FR967824A (en) |
GB (1) | GB680322A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112675378A (en) * | 2020-12-17 | 2021-04-20 | 中国人民解放军陆军军医大学第一附属医院 | Perineum flusher |
Families Citing this family (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL99543C (en) * | 1952-09-05 | |||
US2741250A (en) * | 1953-01-07 | 1956-04-10 | Cornelius A Rauh | Process for pickling metal |
US2884728A (en) * | 1954-08-16 | 1959-05-05 | Turco Products Inc | Apparatus and method for removing metal from the surface of a metal object |
US2877146A (en) * | 1955-05-31 | 1959-03-10 | Puriron Chemicals Inc | Metallurgical pickling |
US2970890A (en) * | 1957-08-23 | 1961-02-07 | Du Pont | Method of purifying dilute sodium sulfate solution |
US3083129A (en) * | 1958-10-01 | 1963-03-26 | Gen Dynamics Corp | Method of etching copper with rejuvenation and recycling |
US2960391A (en) * | 1958-10-29 | 1960-11-15 | Singmaster & Breyer Inc | Regeneration of spent pickle liquor |
FR1237923A (en) * | 1959-06-26 | 1960-08-05 | Fakler & Cie O | Sulfuric pickling bath control process |
US3352723A (en) * | 1962-07-17 | 1967-11-14 | Universal Container Corp | Method of cleaning used steel drums of organic residues |
US3445284A (en) * | 1963-11-18 | 1969-05-20 | Dravo Corp | Process for pickling of steel strip and regeneration of the contact acid |
US3623532A (en) * | 1969-03-20 | 1971-11-30 | Southwire Co | Continuous pickling of cast rod |
US3760069A (en) * | 1971-05-07 | 1973-09-18 | M & T Chemicals Inc | Process for producing ferrous sulfate |
ATE7050T1 (en) * | 1980-01-18 | 1984-04-15 | Boliden Aktiebolag | METHOD OF REGENERATION OF PICKLING SOLUTIONS. |
KR101629592B1 (en) * | 2012-01-18 | 2016-06-13 | 제이에프이 스틸 가부시키가이샤 | Method for prevention of yellowing on surface of steel sheet after pickling |
US10689765B2 (en) * | 2014-09-10 | 2020-06-23 | Nakagawa Special Steel Inc. | Method for cleaning wire and device therefor |
US9738542B2 (en) * | 2014-12-09 | 2017-08-22 | Kronos International, Inc. | Method for the further processing of iron sulfate heptahydrate |
CN112708898B (en) * | 2020-12-22 | 2021-11-19 | 徐州瑞马智能技术有限公司 | Recycling device and method for treating steel pickling waste liquid |
CN114318355B (en) * | 2021-11-19 | 2024-02-13 | 盐城市冉峰机械设备制造有限公司 | Steel cord pickling device and cleaning method thereof |
Family Cites Families (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1045723A (en) * | 1909-12-11 | 1912-11-26 | American Sheet & Tin Plate | Process of treating waste ferrous sulfate liquors. |
US1146071A (en) * | 1914-10-17 | 1915-07-13 | Addison F Hoffman | Process of pickling iron and steel. |
US1865607A (en) * | 1924-08-29 | 1932-07-05 | Gen Chemical Corp | Apparatus for the manufacture of sulphuric acid |
US2005120A (en) * | 1932-02-03 | 1935-06-18 | American Sheet & Tin Plate | Method of recovering salts and other compounds |
US2017773A (en) * | 1932-08-02 | 1935-10-15 | Noah B Smith | Process of recovering waste pickling solutions |
US2118272A (en) * | 1935-01-14 | 1938-05-24 | Guggenheim Brothers | Recovery of salts from aqueous solutions |
US2050355A (en) * | 1935-09-03 | 1936-08-11 | Timken Roller Bearing Co | Pickling of metal |
US2078088A (en) * | 1935-11-22 | 1937-04-20 | Mantius | Process of recovering sulphuric acid from sulphuric acid solutions of sulphates |
US2203606A (en) * | 1936-09-24 | 1940-06-04 | Reynolds Metals Co | Apparatus for coating metal strips |
US2155854A (en) * | 1937-05-26 | 1939-04-25 | American Rolling Mill Co | Pickling process |
US2185095A (en) * | 1938-10-29 | 1939-12-26 | Chemical Construction Corp | Regeneration of waste ferrous sulphate liquor |
US2322134A (en) * | 1939-09-29 | 1943-06-15 | Mellon Inst Of Ind Res | Process for recovery of by-products from waste pickle liquors |
US2372599A (en) * | 1940-03-29 | 1945-03-27 | John S Nachtman | Electrolytic cleaning and pickling of metal surfaces |
US2381652A (en) * | 1941-07-24 | 1945-08-07 | Nat Steel Corp | Continuous strip pickling |
US2379823A (en) * | 1942-01-01 | 1945-07-03 | Standard Oil Dev Co | Acid recovery process |
US3541901A (en) * | 1968-08-30 | 1970-11-24 | Mark M Murata | Adjustable socket |
-
0
- BE BE483353D patent/BE483353A/xx unknown
-
1947
- 1947-06-25 US US757008A patent/US2668130A/en not_active Expired - Lifetime
-
1948
- 1948-06-18 GB GB16435/48A patent/GB680322A/en not_active Expired
- 1948-06-19 FR FR967824D patent/FR967824A/en not_active Expired
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112675378A (en) * | 2020-12-17 | 2021-04-20 | 中国人民解放军陆军军医大学第一附属医院 | Perineum flusher |
CN112675378B (en) * | 2020-12-17 | 2022-05-13 | 中国人民解放军陆军军医大学第一附属医院 | Perineum flusher |
Also Published As
Publication number | Publication date |
---|---|
BE483353A (en) | |
US2668130A (en) | 1954-02-02 |
FR967824A (en) | 1950-11-13 |
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