GB672180A - Production of arylchlorosilanes - Google Patents
Production of arylchlorosilanesInfo
- Publication number
- GB672180A GB672180A GB20347/50A GB2034750A GB672180A GB 672180 A GB672180 A GB 672180A GB 20347/50 A GB20347/50 A GB 20347/50A GB 2034750 A GB2034750 A GB 2034750A GB 672180 A GB672180 A GB 672180A
- Authority
- GB
- United Kingdom
- Prior art keywords
- silicon
- methyltrichlorosilane
- biphenyl
- prepared
- benzene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract 6
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical compound C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 abstract 4
- VXEGSRKPIUDPQT-UHFFFAOYSA-N 4-[4-(4-methoxyphenyl)piperazin-1-yl]aniline Chemical compound C1=CC(OC)=CC=C1N1CCN(C=2C=CC(N)=CC=2)CC1 VXEGSRKPIUDPQT-UHFFFAOYSA-N 0.000 abstract 2
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 abstract 2
- 235000010290 biphenyl Nutrition 0.000 abstract 2
- 239000004305 biphenyl Substances 0.000 abstract 2
- 239000005055 methyl trichlorosilane Substances 0.000 abstract 2
- JLUFWMXJHAVVNN-UHFFFAOYSA-N methyltrichlorosilane Chemical compound C[Si](Cl)(Cl)Cl JLUFWMXJHAVVNN-UHFFFAOYSA-N 0.000 abstract 2
- 229910052710 silicon Inorganic materials 0.000 abstract 2
- 239000010703 silicon Substances 0.000 abstract 2
- 239000005049 silicon tetrachloride Substances 0.000 abstract 2
- 150000005840 aryl radicals Chemical class 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 239000002245 particle Substances 0.000 abstract 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 1
- 150000003254 radicals Chemical class 0.000 abstract 1
- FAQYAMRNWDIXMY-UHFFFAOYSA-N trichloroborane Chemical compound ClB(Cl)Cl FAQYAMRNWDIXMY-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/12—Organo silicon halides
- C07F7/121—Preparation or treatment not provided for in C07F7/14, C07F7/16 or C07F7/20
- C07F7/122—Preparation or treatment not provided for in C07F7/14, C07F7/16 or C07F7/20 by reactions involving the formation of Si-C linkages
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
Abstract
Aryltrichlorosilanes and arylmethyldichlorosilanes in which the aryl radical is a phenyl or xenyl radical are prepared by reacting benzene or biphenyl with silicon tetrachloride or methyltrichlorosilane in the presence of silicon at a temperature of from 275 DEG to 500 DEG C. and at a pressure of at least 75 p.s.i. Aluminium chloride or boron trichloride may be employed as a catalyst for the reaction, e.g. in an amount of from 0.1 to 15 mol. per cent based on the total mols. of benzene or biphenyl and silicon tetrachloride or methyltrichlorosilane. The silicon may have a particle size of less than 20 mesh per inch. In the examples phenyltrichlorodiphenyldichloro-, phenylmethyldichloro-p-xenyltrichloro- and m-xenyltrichlorosilanes are prepared.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US672180XA | 1949-10-03 | 1949-10-03 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB672180A true GB672180A (en) | 1952-05-14 |
Family
ID=22074506
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB20347/50A Expired GB672180A (en) | 1949-10-03 | 1950-08-16 | Production of arylchlorosilanes |
Country Status (4)
Country | Link |
---|---|
BE (1) | BE497956A (en) |
DE (1) | DE862894C (en) |
FR (1) | FR1024246A (en) |
GB (1) | GB672180A (en) |
-
1950
- 1950-08-16 GB GB20347/50A patent/GB672180A/en not_active Expired
- 1950-09-04 FR FR1024246D patent/FR1024246A/en not_active Expired
- 1950-09-06 BE BE497956D patent/BE497956A/xx unknown
- 1950-09-27 DE DED6154A patent/DE862894C/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
FR1024246A (en) | 1953-03-30 |
BE497956A (en) | 1951-01-02 |
DE862894C (en) | 1953-01-15 |
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