GB669187A - Improvements in or relating to textile finishing materials and methods of treating yarns, fibres and fabrics therewith - Google Patents
Improvements in or relating to textile finishing materials and methods of treating yarns, fibres and fabrics therewithInfo
- Publication number
- GB669187A GB669187A GB21289/48A GB2128948A GB669187A GB 669187 A GB669187 A GB 669187A GB 21289/48 A GB21289/48 A GB 21289/48A GB 2128948 A GB2128948 A GB 2128948A GB 669187 A GB669187 A GB 669187A
- Authority
- GB
- United Kingdom
- Prior art keywords
- salt
- styrene
- copolymer
- heavy metal
- treated
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000004744 fabric Substances 0.000 title abstract 11
- 238000000034 method Methods 0.000 title abstract 6
- 239000000463 material Substances 0.000 title abstract 4
- 238000009988 textile finishing Methods 0.000 title 1
- 150000003839 salts Chemical class 0.000 abstract 14
- -1 amine salt Chemical class 0.000 abstract 8
- 229920001577 copolymer Polymers 0.000 abstract 8
- 229910001385 heavy metal Inorganic materials 0.000 abstract 8
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 6
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 abstract 6
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 abstract 6
- 239000000243 solution Substances 0.000 abstract 5
- YBYIRNPNPLQARY-UHFFFAOYSA-N 1H-indene Chemical compound C1=CC=C2CC=CC2=C1 YBYIRNPNPLQARY-UHFFFAOYSA-N 0.000 abstract 4
- PYSRRFNXTXNWCD-UHFFFAOYSA-N 3-(2-phenylethenyl)furan-2,5-dione Chemical compound O=C1OC(=O)C(C=CC=2C=CC=CC=2)=C1 PYSRRFNXTXNWCD-UHFFFAOYSA-N 0.000 abstract 4
- ZRALSGWEFCBTJO-UHFFFAOYSA-N Guanidine Chemical class NC(N)=N ZRALSGWEFCBTJO-UHFFFAOYSA-N 0.000 abstract 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract 4
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 abstract 4
- 229920000297 Rayon Polymers 0.000 abstract 4
- 229920000147 Styrene maleic anhydride Polymers 0.000 abstract 4
- 150000002148 esters Chemical class 0.000 abstract 4
- FJKIXWOMBXYWOQ-UHFFFAOYSA-N ethenoxyethane Chemical compound CCOC=C FJKIXWOMBXYWOQ-UHFFFAOYSA-N 0.000 abstract 4
- 239000011976 maleic acid Substances 0.000 abstract 4
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 abstract 4
- 150000003440 styrenes Chemical class 0.000 abstract 4
- 239000003513 alkali Substances 0.000 abstract 3
- 239000006185 dispersion Substances 0.000 abstract 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 abstract 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract 2
- SBYMUDUGTIKLCR-UHFFFAOYSA-N 2-chloroethenylbenzene Chemical compound ClC=CC1=CC=CC=C1 SBYMUDUGTIKLCR-UHFFFAOYSA-N 0.000 abstract 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 abstract 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 abstract 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 abstract 2
- 229910052684 Cerium Inorganic materials 0.000 abstract 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 abstract 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract 2
- 229920000742 Cotton Polymers 0.000 abstract 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 abstract 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 abstract 2
- CHJJGSNFBQVOTG-UHFFFAOYSA-N N-methyl-guanidine Natural products CNC(N)=N CHJJGSNFBQVOTG-UHFFFAOYSA-N 0.000 abstract 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 abstract 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 abstract 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 abstract 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 abstract 2
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 abstract 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract 2
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 abstract 2
- 239000002253 acid Substances 0.000 abstract 2
- 150000003973 alkyl amines Chemical class 0.000 abstract 2
- 239000004411 aluminium Substances 0.000 abstract 2
- 229910052782 aluminium Inorganic materials 0.000 abstract 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 2
- 150000003863 ammonium salts Chemical class 0.000 abstract 2
- 229910052787 antimony Inorganic materials 0.000 abstract 2
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 abstract 2
- 239000007864 aqueous solution Substances 0.000 abstract 2
- 229910052785 arsenic Inorganic materials 0.000 abstract 2
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 abstract 2
- 229910052788 barium Inorganic materials 0.000 abstract 2
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 abstract 2
- 229910052790 beryllium Inorganic materials 0.000 abstract 2
- ATBAMAFKBVZNFJ-UHFFFAOYSA-N beryllium atom Chemical compound [Be] ATBAMAFKBVZNFJ-UHFFFAOYSA-N 0.000 abstract 2
- 229910052797 bismuth Inorganic materials 0.000 abstract 2
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 abstract 2
- 229910052793 cadmium Inorganic materials 0.000 abstract 2
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 abstract 2
- 229910052791 calcium Inorganic materials 0.000 abstract 2
- 239000011575 calcium Substances 0.000 abstract 2
- ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 abstract 2
- 229910052804 chromium Inorganic materials 0.000 abstract 2
- 239000011651 chromium Substances 0.000 abstract 2
- 229910017052 cobalt Inorganic materials 0.000 abstract 2
- 239000010941 cobalt Substances 0.000 abstract 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- 229910052802 copper Inorganic materials 0.000 abstract 2
- 239000010949 copper Substances 0.000 abstract 2
- SWSQBOPZIKWTGO-UHFFFAOYSA-N dimethylaminoamidine Natural products CN(C)C(N)=N SWSQBOPZIKWTGO-UHFFFAOYSA-N 0.000 abstract 2
- PBZROIMXDZTJDF-UHFFFAOYSA-N hepta-1,6-dien-4-one Chemical compound C=CCC(=O)CC=C PBZROIMXDZTJDF-UHFFFAOYSA-N 0.000 abstract 2
- KETWBQOXTBGBBN-UHFFFAOYSA-N hex-1-enylbenzene Chemical compound CCCCC=CC1=CC=CC=C1 KETWBQOXTBGBBN-UHFFFAOYSA-N 0.000 abstract 2
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 abstract 2
- 229910052749 magnesium Inorganic materials 0.000 abstract 2
- 239000011777 magnesium Substances 0.000 abstract 2
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 abstract 2
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 abstract 2
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 abstract 2
- 229910052753 mercury Inorganic materials 0.000 abstract 2
- 229910052750 molybdenum Inorganic materials 0.000 abstract 2
- 239000011733 molybdenum Substances 0.000 abstract 2
- 229910052759 nickel Inorganic materials 0.000 abstract 2
- DPBLXKKOBLCELK-UHFFFAOYSA-N pentan-1-amine Chemical class CCCCCN DPBLXKKOBLCELK-UHFFFAOYSA-N 0.000 abstract 2
- 229910052697 platinum Inorganic materials 0.000 abstract 2
- 239000011591 potassium Substances 0.000 abstract 2
- 229910052700 potassium Inorganic materials 0.000 abstract 2
- 229910052709 silver Inorganic materials 0.000 abstract 2
- 239000004332 silver Substances 0.000 abstract 2
- 239000011734 sodium Substances 0.000 abstract 2
- 229910052708 sodium Inorganic materials 0.000 abstract 2
- 229910052712 strontium Inorganic materials 0.000 abstract 2
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 abstract 2
- 239000004753 textile Substances 0.000 abstract 2
- 229910052718 tin Inorganic materials 0.000 abstract 2
- FUSUHKVFWTUUBE-UHFFFAOYSA-N vinyl methyl ketone Natural products CC(=O)C=C FUSUHKVFWTUUBE-UHFFFAOYSA-N 0.000 abstract 2
- 229910052725 zinc Inorganic materials 0.000 abstract 2
- 239000011701 zinc Substances 0.000 abstract 2
- 229910052726 zirconium Inorganic materials 0.000 abstract 2
- 240000008564 Boehmeria nivea Species 0.000 abstract 1
- 244000025254 Cannabis sativa Species 0.000 abstract 1
- 235000012766 Cannabis sativa ssp. sativa var. sativa Nutrition 0.000 abstract 1
- 235000012765 Cannabis sativa ssp. sativa var. spontanea Nutrition 0.000 abstract 1
- 240000000491 Corchorus aestuans Species 0.000 abstract 1
- 235000011777 Corchorus aestuans Nutrition 0.000 abstract 1
- 235000010862 Corchorus capsularis Nutrition 0.000 abstract 1
- 240000006240 Linum usitatissimum Species 0.000 abstract 1
- 235000004431 Linum usitatissimum Nutrition 0.000 abstract 1
- 239000004677 Nylon Substances 0.000 abstract 1
- UVTGXFAWNQTDBG-UHFFFAOYSA-N [Fe].[Pb] Chemical compound [Fe].[Pb] UVTGXFAWNQTDBG-UHFFFAOYSA-N 0.000 abstract 1
- 229910021529 ammonia Inorganic materials 0.000 abstract 1
- 229910000019 calcium carbonate Inorganic materials 0.000 abstract 1
- 235000009120 camo Nutrition 0.000 abstract 1
- 235000005607 chanvre indien Nutrition 0.000 abstract 1
- RCJVRSBWZCNNQT-UHFFFAOYSA-N dichloridooxygen Chemical compound ClOCl RCJVRSBWZCNNQT-UHFFFAOYSA-N 0.000 abstract 1
- 239000000835 fiber Substances 0.000 abstract 1
- 239000011521 glass Substances 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 239000011487 hemp Substances 0.000 abstract 1
- 229910052742 iron Inorganic materials 0.000 abstract 1
- 239000011133 lead Substances 0.000 abstract 1
- 150000002736 metal compounds Chemical class 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 229920001778 nylon Polymers 0.000 abstract 1
- CMOAHYOGLLEOGO-UHFFFAOYSA-N oxozirconium;dihydrochloride Chemical compound Cl.Cl.[Zr]=O CMOAHYOGLLEOGO-UHFFFAOYSA-N 0.000 abstract 1
- 102000004169 proteins and genes Human genes 0.000 abstract 1
- 108090000623 proteins and genes Proteins 0.000 abstract 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 abstract 1
- 239000002964 rayon Substances 0.000 abstract 1
- 238000003756 stirring Methods 0.000 abstract 1
- 238000005406 washing Methods 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
- 210000002268 wool Anatomy 0.000 abstract 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
Textile fabrics, yarns or fibres are treated with an aqueous solution or dispersion of an alkali or amine salt of a copolymer of styrene or a substituted styrene with maleic anhydride or a partial ester of maleic acid, dried and also treated at some stage of the process with an aqueous bath containing a heavy metal salt as defined in the Specification. Sodium, potassium, ammonium or quarternary ammonium salts (such as phenyl-trimethylammonium salts) may be used, as well as the salts of guanidine and the alkylamines such as the methyl-, butyl-, and amylamines. When the heavy metal salt is water-soluble it may be applied before or after the copolymer salt, and when it is insoluble it should be dispersed in the aqueous bath of the copolymer salt before being applied, the treated material being then dried. Suitable heavy metal salts are those of aluminium, antimony, arsenic, barium, beryllium, bismuth, cadmium, calcium, cerium, chromium, cobalt, copper, iron, lead, magnesium, manganese, mercury, molybdenum, nickel, platinum, silver, strontium, tin, zinc and zirconium, e.g. the oxychloride. The copolymer is prepared by known methods. Substituted styrenes which may be used are methyl- or butyl-styrene or chlorstyrene, and a suitable partial ester of maleic acid is isopropyl acid maleate. Small amounts of other unsaturated compounds such as vinyl acetate, vinyl chloride, vinyl ethyl ether, indene, vinyl methyl ketone and acrylic acid may be copolymerized with the styrene-maleic anhydride.ALSO:Textile fabrics, yarns or fibres are treated with an aqueous solution or dispersion of an alkali or amine salt of a copolymer of styrene or a substituted styrene with maleic anhydride or a partial ester of maleic acid, in amount sufficient to provide from 4 to 7 per cent by weight of the salt based on the fabrics, yarns or fibres, dried and also treated at some stage of the process with an aqueous bath containing a heavy metal salt as defined in the Specification. The yarn, fibre, or fabric may be sprayed with or dipped in the solution or dispersion of the copolymer salt. Sodium, potassium, ammonium or quaternary ammonium salts (such as phenyl-trimethylammonium salts) may be used, as well as the salts of guanidine and the alkylamines such as the methyl-, butyl- and amylamines. When the heavy metal salt is water-soluble it may be applied before or after the copolymer salt before being applied, the treated material being then dried. Suitable heavy metal salts are those of aluminium, antimony, arsenic, barium, beryllium, bismuth, cadmium, calcium, cerium, chromium, cobalt, copper, iron lead, magnesium, manganese, mercury, molybdenum, nickel, platinum, silver, strontium, tin, zinc and zirconium. The copolymer is prepared by known methods. Substituted styrenes which may be used are methyl- or butyl-styrene or chlorstyrene, and a suitable partial ester of maleic acid is isopropyl acid maleate. Small amounts of other unsaturated compounds such as vinyl acetate, vinyl chloride, vinyl ethyl ether, indene, vinyl methyl ketone, and acrylic acid may be copolymerized with the styrenemaleic anhydride. The process is applicable to cotton, viscose, acetate rayon, nylon, glass, linen, flax, hemp, jute, ramie, wool, silk, cuprammonium rayon and artificial protein fabrics and to mixtures of these materials. If desired the alkali or amine salt may be applied to yarns which are then woven into fabrics and the fabric treated with the heavy metal salt. In an example (all parts by weight) a solution of the ammonium salt of a styrene maleic anhydride copolymer is prepared by mixing 600 parts of styrene-maleic anhydride, 400 parts of 26 per cent ammonia and 9000 parts of water, and heating at 200-212 DEG F. with stirring until a transparent solution is obtained. Spun viscose rayon fabric and cotton sheeting are dipped in the solution at 120 DEG F. and squeezed to 100 per cent pick-up. The treated fabric is then dried, immersed in 2 per cent zirconium oxychloride solution for 10 minutes at 120 DEG F., rinsed and dried. The finished fabric is resistant to washing and possesses good water-repellency. Example 3 describes the use of an insoluble heavy metal compound (calcium carbonate).
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US770943A US2586477A (en) | 1947-08-27 | 1947-08-27 | Treatment of textile materials |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB669187A true GB669187A (en) | 1952-03-26 |
Family
ID=25090178
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB21289/48A Expired GB669187A (en) | 1947-08-27 | 1948-08-12 | Improvements in or relating to textile finishing materials and methods of treating yarns, fibres and fabrics therewith |
Country Status (2)
| Country | Link |
|---|---|
| US (1) | US2586477A (en) |
| GB (1) | GB669187A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9775324B2 (en) | 2011-12-22 | 2017-10-03 | Delaval Holding Ab | Milk conduit, and a milk conduit assembly |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2651587A (en) * | 1947-06-02 | 1953-09-08 | Monsanto Chemicals | Treatment of textile materials |
| US2799914A (en) * | 1953-05-14 | 1957-07-23 | Monsanto Chemicals | Sized yarn and fabric containing same |
| US3012978A (en) * | 1954-10-26 | 1961-12-12 | Celanese Corp | Process of treating filaments with a peroxygen compound |
| US2864808A (en) * | 1954-12-15 | 1958-12-16 | Monsanto Chemicals | Terpolymer system |
| DE1052942B (en) * | 1955-06-04 | 1959-03-19 | Hoechst Ag | Process for making textile materials with a content of hydrophobic synthetic fibers antistatic |
| US2919964A (en) * | 1956-12-24 | 1960-01-05 | Leonard T Evans | Journal box lubrication |
| US3084070A (en) * | 1958-09-02 | 1963-04-02 | Dow Chemical Co | Warp size comprising high molecular weight styrene/maleic anhydride copolymer |
| US3005802A (en) * | 1958-09-04 | 1961-10-24 | Johnson & Johnson | Adhesive salt of an ester of a maleic anhydride copolymer |
| JPS4826933B1 (en) * | 1968-02-01 | 1973-08-17 | ||
| CN103923418B (en) * | 2014-05-06 | 2016-02-03 | 南京信息工程大学 | A kind of high ultraviolet absorption ability material and preparation method thereof |
| CN106087087B (en) * | 2016-06-01 | 2018-02-23 | 恒天纤维集团有限公司 | Antibacterial regenerated celulose fibre and preparation method thereof |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE623404C (en) * | 1930-05-26 | |||
| US2319852A (en) * | 1939-02-02 | 1943-05-25 | Carbide & Carbon Chem Corp | Coating composition |
| US2356879A (en) * | 1939-12-12 | 1944-08-29 | Pense Walter | Process of preparing lustrous coatings |
-
1947
- 1947-08-27 US US770943A patent/US2586477A/en not_active Expired - Lifetime
-
1948
- 1948-08-12 GB GB21289/48A patent/GB669187A/en not_active Expired
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9775324B2 (en) | 2011-12-22 | 2017-10-03 | Delaval Holding Ab | Milk conduit, and a milk conduit assembly |
Also Published As
| Publication number | Publication date |
|---|---|
| US2586477A (en) | 1952-02-19 |
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