GB655541A - Improvements in or relating to softening of textiles - Google Patents

Improvements in or relating to softening of textiles

Info

Publication number
GB655541A
GB655541A GB13321/46A GB1332146A GB655541A GB 655541 A GB655541 A GB 655541A GB 13321/46 A GB13321/46 A GB 13321/46A GB 1332146 A GB1332146 A GB 1332146A GB 655541 A GB655541 A GB 655541A
Authority
GB
United Kingdom
Prior art keywords
aliphatic
carbon atoms
acid
disodium
urea
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB13321/46A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Wyeth Holdings LLC
Original Assignee
American Cyanamid Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by American Cyanamid Co filed Critical American Cyanamid Co
Publication of GB655541A publication Critical patent/GB655541A/en
Expired legal-status Critical Current

Links

Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/402Amides imides, sulfamic acids
    • D06M13/432Urea, thiourea or derivatives thereof, e.g. biurets; Urea-inclusion compounds; Dicyanamides; Carbodiimides; Guanidines, e.g. dicyandiamides

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

A softening composition for textiles comprises the condensation product of mixed aliphatic amine and aliphatic-substituted guanidine salts of N-aliphatic carbamic acids in which the aliphatic radicals contain 12-18 carbon atoms with 2-10 mols. of an alkylene oxide of 2-4 carbon atoms, in admixture with a smaller quantity of an anionic surface-active agent containing a single long aliphatic radical of at least twelve carbon atoms. The condensation product is made according to Specification 654,163. The composition softens cotton wool, rayon, nylon, vinyl chloride-vinyl acetate copolymer, and other fibres or fabrics. The mixtures may also contain 0.1-4 per cent of a polyvalent metal salt, such as aluminium sulphate, zinc sulphate, or zirconium acetate, which is preferably used together with a water-soluble amide such as urea or thiourea. The compositions may be applied together with starch or resin finishes, e.g. methylol melamines having 3-6 methylol groups, dimethylol urea, alkylated methylolmelamines such as tri-tetra-, penta-, or hexa-methylated methylol melamines, or dimethylated dimethylol urea, from an aqueous bath containing an acidic or acid-releasing curing agent such as diammonium hydrogen phosphate, phthalic acid, or oxalic acid. The amines employed may be unsaturated. Alkylene oxides specified are ethylene, propylene, or butylene. Anionic surface-active agents specified are dodecyl, hexadecyl, and octadecyl sulphates, keryl benzene sulphonate, and the monoesters or mono-amides of aliphatic sulphocarboxylic acids, e.g. the monolauryl, monocetyl, monostearyl, and mono-oleyl esters of sulphosuccinic acid, used as the disodium salts, and the corresponding sulphosuccinamate disodium or diammonium salts. The impregnated cloth is heated to 200-400 DEG F. In an example, octadecylamine, or a mixture of hexadecylamine, octadecylamine, and unsaturated primary amines of 18 carbon atoms is dissolved in isopropyl alcohol, and reacted with carbon dioxide in presence of water, and then with cyanamide solution followed by reaction with ethylene oxide. Various examples are given of compositions comprising the product of this example mixed with octadecyl disodium sulphosuccinamate and varying quantities of hydrochloric acid, acetic acid, alcohol, water, aluminium sulphate and urea. Lauryl, tetradecyl and octadecyl disodium sulphosuccinamates are made from the corresponding amines and maleic anhydride, followed by neutralization with caustic soda and reaction with sodium bisulphite. Specification 608,375, [Group IV (c)], is referred to.ALSO:A softening composition for textiles comprises the condensation product of mixed aliphatic amine and aliphatic-substituted guanidine salts of N-aliphatic carbamic acids in which the aliphatic radicals contain 12-18 carbon atoms with 2-10 mols. of an alkylene oxide of 2-4 carbon atoms, in admixture with a smaller quantity of an anionic surface-active agent containing a single long aliphatic radical of at least twelve carbon atoms. The condensation product is made according to Specification 654,163, [Group IV (b)]. The compositions soften cotton, wool, rayon, nylon, vinyl chloridevinyl acetate copolymer, and other fibres or fabrics. The mixtures may also contain 0.1 to 4 per cent of a polyvalent metal salt, such as aluminium sulphate, zinc sulphate, or zirconium acetate, which is preferably used together with a water-soluble amide such as urea or thiourea. The compositions may be applied together with starch or resin finishes, e.g. methylol melamines having 3-6 methylol groups, dimethylol urea, alkylated methylol-melamines such as tri-, tetra-, penta-, or hexamethylated methylol melamines, or dimethylated dimethylol urea, from an aqueous bath containing an acidic or acid-releasing curing agent such as diammonium hydrogen phosphate, phthalic acid, or oxalic acid. The amines employed may be unsaturated. Alkylene oxides specified are ethylene, propylene, or butylene. Anionic surface-active agents specified are dodecyl, hexadecyl, and octadecyl sulphates, keryl benzene sulphonate, and the monoesters or monoamides of aliphatic sulphocarboxylic acids, e.g. the monolauryl, monocetyl, monostearyl, and mono-oleyl esters of sulphosuccinic acid, used as p the disodium salts, and the corresponding sulphosuccinamate disodium or diammonium salts. The impregnated cloth is heated to 200-400 DEG F. In an example, octadecylamine, or a mixture of hexadecylamine, octadecylamine, and unsaturated primary amines of 18 carbon atoms is dissolved in isopropyl alcohol, and reacted with carbon dioxide in presence of water, and then with cyanamide solution followed by reaction with ethylene oxide. Various examples are given of compositions comprising the product of this example mixed with octadecyl disodium sulphosuccinamate and varying quantities of hydrochloric acid, acetic acid, alcohol, water, aluminium sulphate, and urea. Lauryl, tetradecyl and octadecyl disodium sulphosuccinamates are made from the corresponding amines and maleic anhydride, followed by neutralisation with caustic soda and reaction with sodium bisulphite. Specification 608,375 is referred to.
GB13321/46A 1945-05-14 1946-05-02 Improvements in or relating to softening of textiles Expired GB655541A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US655541XA 1945-05-14 1945-05-14

Publications (1)

Publication Number Publication Date
GB655541A true GB655541A (en) 1951-07-25

Family

ID=22063517

Family Applications (1)

Application Number Title Priority Date Filing Date
GB13321/46A Expired GB655541A (en) 1945-05-14 1946-05-02 Improvements in or relating to softening of textiles

Country Status (1)

Country Link
GB (1) GB655541A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2321565A1 (en) * 1975-08-18 1977-03-18 Procter & Gamble COMPOSITION GIVING SOFTENING AND ANTISTATIC PROPERTIES TO TEXTILES

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2321565A1 (en) * 1975-08-18 1977-03-18 Procter & Gamble COMPOSITION GIVING SOFTENING AND ANTISTATIC PROPERTIES TO TEXTILES

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