GB653325A - Improvements in or relating to the production of ammonium sulphate and the recovery of pyridine - Google Patents

Improvements in or relating to the production of ammonium sulphate and the recovery of pyridine

Info

Publication number
GB653325A
GB653325A GB4642/48A GB464248A GB653325A GB 653325 A GB653325 A GB 653325A GB 4642/48 A GB4642/48 A GB 4642/48A GB 464248 A GB464248 A GB 464248A GB 653325 A GB653325 A GB 653325A
Authority
GB
United Kingdom
Prior art keywords
pyridine
saturator
ammonium sulphate
liquor
make
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB4642/48A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Beazer East Inc
Original Assignee
Koppers Co Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Koppers Co Inc filed Critical Koppers Co Inc
Publication of GB653325A publication Critical patent/GB653325A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01CAMMONIA; CYANOGEN; COMPOUNDS THEREOF
    • C01C1/00Ammonia; Compounds thereof
    • C01C1/24Sulfates of ammonium
    • C01C1/242Preparation from ammonia and sulfuric acid or sulfur trioxide

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Treating Waste Gases (AREA)
  • Gas Separation By Absorption (AREA)

Abstract

<PICT:0653325/IV (b)/1> A process for the recovery of pyridine from gas containing ammonia and pyridine comprises the steps of bringing the gas into contact with dilute sulphuric acid containing ammonium sulphate, the time of contact being sufficient adequately to absorb ammonia but insufficient adequately to absorb pyridine, crystallizing ammonium sulphate in the solution, separating the crystals of ammonium sulphate and incorporating make-up sulphuric acid in the solution; bringing the effluent from this contact into contact with another solution of sulphuric acid which is unsaturated with ammonium sulphate and has a greater affinity for pyridine than the first-mentioned dilute sulphuric acid; and treating both solutions containing pyridine to recover pyridine therefrom and returning the treated solutions to the process. As shown in Fig. 1, coke, oven gas containing ammonia and pyridine bases is led into a saturator 10 via an inlet 12 and a bell-shaped cracker pipe 14 at or below the normal liquid level. The saturator solution has a concentration of 1-8 per cent sulphuric acid and a temperature of 35-70 DEG C. It is maintained in circulation being withdrawn through a suction head 28 and returned to the bottom of the saturator through a collecting-plate 34 by means of a pump 32. An overflow 26 controls the liquid level, liquid passing there-through and through a tar skimmer 36 (which receives part of the make-up acid through a line 42) into a storage tank 40. The balance of the make-up acid is introduced through a line 43 into the saturator. Ammonium sulphate crystals are withdrawn by a suction head 44, and after settling in a cone 48 and filtration at 52 the filtrate passes to the storage tank. Liquor from the cone 48 overflows into a line 58 and part thereof passes through a line 62 for pyridine recovery at 64, pyridine-free liquor passing through line 56 to the storage tank. Effluent gases leaving the saturator through an uptake 76 are sprayed with make-up liquors fed from the storage tank via a sprayer 74. This liquor is maintained below saturation and at a higher acidity by virtue of the make-up acid introduced at 42, and removes the remaining pyridine and ammonia from the gas, the effluent liquor joining the solution in the saturator. The effluent gas passes out via a spray catcher 80. According to a modification (Fig. 2, not shown), the effluent gas from the saturator is sprayed with ammonium sulphate liquor by-product of the pyridine recovery after it has been acidified with sulphuric acid and the liquid effluent from the scrubber is passed directly into the pyridine recovery unit, thus completing the cycle, whilst the make-up liquor is fed directly to the saturator from the storage tank. Specification 615,641, [Group III], is referred to.ALSO:<PICT:0653325/III/1> A process for the manufacture of ammonium sulphate and for the recovery of pyridine from gas containing ammonia and pyridine comprises the steps of bringing the gas into contact with dilute sulphuric acid containing ammonium sulphate, the time of contact being sufficient adequately to absorb ammonia but insufficient adequately to absorb pyridine, crystallizing ammonium sulphate in the solution, separating the crystals of ammonium sulphate and incorporating make-up sulphuric acid in the solution; bringing the effluent from this contact into contact with another solution of sulphuric acid which is unsaturated with ammonium sulphate and has a greater affinity for pyridine than the first mentioned dilute sulphuric acid; and treating both solutions containing pyridine to recover pyridine therefrom and returning the treated solutions to the process. As shown in Fig. 1, coke, oven gas containing ammonia and pyridine bases is led into a saturator 10 via an inlet 12 and a bell shaped cracker pipe 14 at or below the normal liquid level. The saturator solution has a concentration of 1-8 per cent sulphuric acid and a temperature of 35-70 DEG C. It is maintained in circulation being withdrawn through a suction head 28 and returned to the bottom of the saturator through a collecting plate 34 by means of a pump 32. An overflow 26 controls the liquid level, liquid passing therethrough and through a tar skimmer 36 (which receives part of the make-up acid through a line 42), into a storage tank 40. The balance of the make-up acid is introduced through a line 43 into the saturator. Ammonium sulphate crystals are withdrawn by a suction head 44, and after settling in a cone 48 and filtration at 52 the filtrate passes to the storage tank. Liquor from the cone 48 overflows into a line 58 and part thereof passes through a line 62 for pyridine recovery at 64, pyridine free liquor passing through line 56 to the storage tank. Effluent gases leaving the saturator through an uptake 76 are sprayed with make-up liquors fed from the storage tank via a sprayer 74. This liquor is maintained below saturation and at a higher acidity by virtue of the make-up acid introduced at 42, and removes the remaining pyridine and ammonia from the gas, the effluent liquor joining the solution in the saturator. The effluent gas passes out via a spray catcher 80. According to a modification (Fig. 2, not shown), the effluent gas from the saturator is sprayed with ammonium sulphate liquor by-product of the pyridine recovery after it has been acidified with sulphuric acid and the liquid effluent from the scrubber is passed directly into the pyridine recovery unit thus completing the cycle, whilst the make-up liquor is fed directly to the saturator from the storage tank. Specification 615,641 is referred to.
GB4642/48A 1947-09-17 1948-02-17 Improvements in or relating to the production of ammonium sulphate and the recovery of pyridine Expired GB653325A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US653325XA 1947-09-17 1947-09-17

Publications (1)

Publication Number Publication Date
GB653325A true GB653325A (en) 1951-05-16

Family

ID=22061972

Family Applications (1)

Application Number Title Priority Date Filing Date
GB4642/48A Expired GB653325A (en) 1947-09-17 1948-02-17 Improvements in or relating to the production of ammonium sulphate and the recovery of pyridine

Country Status (1)

Country Link
GB (1) GB653325A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2786739A (en) * 1954-05-10 1957-03-26 Allied Chem & Dye Corp Continuous process for the production of methacrylic acid esters and ammonium sulphate
CN114653298A (en) * 2022-04-12 2022-06-24 广东韶钢松山股份有限公司 Acid preparation method for preventing saturator from being blocked and coal gas washing equipment

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2786739A (en) * 1954-05-10 1957-03-26 Allied Chem & Dye Corp Continuous process for the production of methacrylic acid esters and ammonium sulphate
CN114653298A (en) * 2022-04-12 2022-06-24 广东韶钢松山股份有限公司 Acid preparation method for preventing saturator from being blocked and coal gas washing equipment
CN114653298B (en) * 2022-04-12 2023-06-27 广东韶钢松山股份有限公司 Acid preparation method for preventing saturator from being blocked and coal gas washing equipment

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