GB641945A - Improvements in or relating to the production of feed gases for the synthesis of hydrocarbons - Google Patents

Improvements in or relating to the production of feed gases for the synthesis of hydrocarbons

Info

Publication number
GB641945A
GB641945A GB737747A GB737747A GB641945A GB 641945 A GB641945 A GB 641945A GB 737747 A GB737747 A GB 737747A GB 737747 A GB737747 A GB 737747A GB 641945 A GB641945 A GB 641945A
Authority
GB
United Kingdom
Prior art keywords
iron
nickel
zinc
per cent
catalyst
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB737747A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Standard Oil Development Co
Original Assignee
Standard Oil Development Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Standard Oil Development Co filed Critical Standard Oil Development Co
Priority to GB737747A priority Critical patent/GB641945A/en
Priority to FR948258D priority patent/FR948258A/en
Priority to NL133259A priority patent/NL65449C/xx
Publication of GB641945A publication Critical patent/GB641945A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/22Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds
    • C01B3/24Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons
    • C01B3/28Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons using moving solid particles
    • C01B3/30Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons using moving solid particles using the fluidised bed technique
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/1836Heating and cooling the reactor
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/40Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts characterised by the catalyst
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041Composition of the catalyst
    • C01B2203/1047Group VIII metal catalysts
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041Composition of the catalyst
    • C01B2203/1047Group VIII metal catalysts
    • C01B2203/1052Nickel or cobalt catalysts
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041Composition of the catalyst
    • C01B2203/1076Copper or zinc-based catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

<PICT:0641945/III/1> Feed gases for the synthesis of hydrocarbons consisting of hydrogen and carbon monoxide are obtained by oxidizing a hydrocarbon gas such as methane in the presence of a fluidized solid catalyst of finely-divided iron, cobalt, nickel, or combinations of these with or without zinc, under 200-300 p.s.i. pressure and between 1200-2200 DEG F., by means of a reducible metal oxide, preferably iron, present in such amount as to furnish one atom of oxygen combined as reducible oxide per atom of carbon. The iron oxide is formed and maintained by circulating a small percentage of the iron through an oxidation zone, while maintaining the greater part, at least 70 per cent and preferably 90-95 per cent of the catalyst in the form of a metal. The hydrocarbon gases enter reaction zone 1 via pipes 2 and 9, the product being withdrawn at 3. The iron catalyst is circulated through pipe 4 to the oxidation zone 5 and back via pipe 8 and 10. A heat transfer system containing fused salt is defined by the closed circuit 11, 12, 13, 14, 15, 16. Preferred catalysts are iron-nickel or iron-zinc combinations wherein 90-95 per cent is nickel or zinc and the remainder iron. Preferred operating conditions are under 100 p.s.i. pressure and at a temperature between 1700 DEG and 1900 DEG F.
GB737747A 1947-03-17 1947-03-17 Improvements in or relating to the production of feed gases for the synthesis of hydrocarbons Expired GB641945A (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
GB737747A GB641945A (en) 1947-03-17 1947-03-17 Improvements in or relating to the production of feed gases for the synthesis of hydrocarbons
FR948258D FR948258A (en) 1947-03-17 1947-06-20 Synthesis of hydrocarbons
NL133259A NL65449C (en) 1947-03-17 1947-07-04

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB737747A GB641945A (en) 1947-03-17 1947-03-17 Improvements in or relating to the production of feed gases for the synthesis of hydrocarbons

Publications (1)

Publication Number Publication Date
GB641945A true GB641945A (en) 1950-08-23

Family

ID=9831971

Family Applications (1)

Application Number Title Priority Date Filing Date
GB737747A Expired GB641945A (en) 1947-03-17 1947-03-17 Improvements in or relating to the production of feed gases for the synthesis of hydrocarbons

Country Status (3)

Country Link
FR (1) FR948258A (en)
GB (1) GB641945A (en)
NL (1) NL65449C (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE953160C (en) * 1951-07-13 1956-11-29 Humphreys & Glasgow Ltd Process for the preferably continuous regeneration of catalysts

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE953160C (en) * 1951-07-13 1956-11-29 Humphreys & Glasgow Ltd Process for the preferably continuous regeneration of catalysts

Also Published As

Publication number Publication date
NL65449C (en) 1950-03-15
FR948258A (en) 1949-07-27

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