GB238319A - Improvements in the manufacture and production of oxygenated organic compounds - Google Patents

Improvements in the manufacture and production of oxygenated organic compounds

Info

Publication number
GB238319A
GB238319A GB1279424A GB1279424A GB238319A GB 238319 A GB238319 A GB 238319A GB 1279424 A GB1279424 A GB 1279424A GB 1279424 A GB1279424 A GB 1279424A GB 238319 A GB238319 A GB 238319A
Authority
GB
United Kingdom
Prior art keywords
zinc oxide
hydrogen
copper
mixture
methanol
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1279424A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Badische Anilin and Sodafabrik AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE, Badische Anilin and Sodafabrik AG filed Critical BASF SE
Priority to GB1279424A priority Critical patent/GB238319A/en
Publication of GB238319A publication Critical patent/GB238319A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/153—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/1512—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by reaction conditions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/153—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used
    • C07C29/154—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used containing copper, silver, gold, or compounds thereof

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Apparatus for the production of oxygenated organic compounds by the catalytic interaction of carbon oxides and hydrogen is made of metals such as copper, silver, or aluminium, or alloys thereof such as copper-manganese alloy, or special steels containing a substantial percentage of chromium, tungsten, vanadium, or molybdenum. Alternatively, iron or steel apparatus may be lined with such metals in sheet form or by electroplating, &c. Catalytic agents, preparation of.-According to the examples, catalytic materials for use in the reaction mentioned above are prepared by (1) introducing zinc oxide into fused potassium bichromate and reducing the product with hydrogen; (2) mixing chromium trioxide with zinc oxide and baryta, (3) adding tungstic acid to copper oxide and lead oxide, (4) heating a mixture of ammonium bichromate, zinc oxide, and potassium carbonate, (5) introducing zinc oxide into molten sodium bichromate and reducing with a mixture of carbon monoxide and hydrogen, and (6) mixing zinc oxide and chromium trioxide with monganeous carbonate. Specifications 227,147, [Class 2 (iii), Dyes &c.], 229,714 and 229,715 are referred to. Reference has been directed by the Comptroller to Specification 20488/13.ALSO:Oxygenated organic compounds of a higher order than methanol are obtained by passing a mixture of carbon monoxide or dioxide with hydrogen at elevated temperature and pressure over a methanol-forming catalyst but at a diminished speed compared with that required for the formation of methanol under otherwise similar conditions. Iron, nickel and cobalt must be excluded from the contact material, apparatus and reaction gases. In the case of the apparatus, this should either consist of metals such as copper, silver, aluminium, or alloys thereof such as copper-manganese alloy, or special steels containing a substantial percentage of chromium, tungsten, vanadium or molybdenum, or alternatively, iron or steel apparatus may be lined with such metals in the sheet form or by electroplating &c. Catalysts suitable for the reaction comprise metallic oxides which are non-reducible under the conditions of working and preferably p contain an alkali metal compound. The constituent gases may be employed in any proportions and nitrogen or gaseous hydrocarbons may also be present. Examples are given of the production of oily bodies consisting mainly of higher alcohols with some aldehydes and methanol by passing mixtures of carbon monoxide and hydrogen at stated gas velocities, temperatures and pressures over catalytic materials prepared by (1) introducing zinc oxide into fused potassium bichromate and reducing the product with hydrogen, (2) mixing chromium trioxide with zinc oxide and baryta, (3) adding tungstic acid to copper oxide and lead oxide, (4) heating a mixture of ammonium bichromate, zinc oxide and potassium carbonate, (5) introducing zinc oxide into molten sodium bichromate and reducing with a mixture of carbon monoxide and hydrogen, and (6) mixing zinc oxide and chromic trioxide with manganous carbonate. In some instances, the gas velocity for the formation of substantially pure methanol is given for purposes of comparison. Specifications 227,147, 229,714, and 229,715, are referred to. Reference has been directed by the Comptroller to Specification 20488/13.
GB1279424A 1924-05-24 1924-05-24 Improvements in the manufacture and production of oxygenated organic compounds Expired GB238319A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB1279424A GB238319A (en) 1924-05-24 1924-05-24 Improvements in the manufacture and production of oxygenated organic compounds

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB1279424A GB238319A (en) 1924-05-24 1924-05-24 Improvements in the manufacture and production of oxygenated organic compounds

Publications (1)

Publication Number Publication Date
GB238319A true GB238319A (en) 1925-08-20

Family

ID=10011254

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1279424A Expired GB238319A (en) 1924-05-24 1924-05-24 Improvements in the manufacture and production of oxygenated organic compounds

Country Status (1)

Country Link
GB (1) GB238319A (en)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4540713A (en) * 1978-05-15 1985-09-10 The Standard Oil Company Preparation of alcohols from synthesis gas
US4593015A (en) * 1978-05-15 1986-06-03 The Standard Oil Company Catalyst for the preparation of alcohols from synthesis gas
US4609678A (en) * 1978-05-15 1986-09-02 The Standard Oil Company Preparation of alcohols from synthesis gas
US4668656A (en) * 1978-05-15 1987-05-26 The Standard Oil Company Catalyst for the preparation of alcohols from synthesis gas
US4749724A (en) * 1983-03-18 1988-06-07 The Dow Chemical Company Process for producing alcohols from synthesis gas
US4752622A (en) * 1984-07-30 1988-06-21 The Dow Chemical Company Process for producing alcohols from synthesis gas
US4762858A (en) * 1985-09-16 1988-08-09 The Dow Chemical Company Syngas conversion to oxygenates by reduced yttrium/lanthanide/actinide-modified catalyst

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4540713A (en) * 1978-05-15 1985-09-10 The Standard Oil Company Preparation of alcohols from synthesis gas
US4593015A (en) * 1978-05-15 1986-06-03 The Standard Oil Company Catalyst for the preparation of alcohols from synthesis gas
US4609678A (en) * 1978-05-15 1986-09-02 The Standard Oil Company Preparation of alcohols from synthesis gas
US4668656A (en) * 1978-05-15 1987-05-26 The Standard Oil Company Catalyst for the preparation of alcohols from synthesis gas
US4749724A (en) * 1983-03-18 1988-06-07 The Dow Chemical Company Process for producing alcohols from synthesis gas
US4752622A (en) * 1984-07-30 1988-06-21 The Dow Chemical Company Process for producing alcohols from synthesis gas
US4762858A (en) * 1985-09-16 1988-08-09 The Dow Chemical Company Syngas conversion to oxygenates by reduced yttrium/lanthanide/actinide-modified catalyst

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