GB635213A - Improvements in or relating to heterogeneous plastic compositions and method of making the same - Google Patents

Improvements in or relating to heterogeneous plastic compositions and method of making the same

Info

Publication number
GB635213A
GB635213A GB1886346A GB1886346A GB635213A GB 635213 A GB635213 A GB 635213A GB 1886346 A GB1886346 A GB 1886346A GB 1886346 A GB1886346 A GB 1886346A GB 635213 A GB635213 A GB 635213A
Authority
GB
United Kingdom
Prior art keywords
composition
butadiene
carbon black
vinyl
polymeric material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1886346A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to GB1886346A priority Critical patent/GB635213A/en
Publication of GB635213A publication Critical patent/GB635213A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00Processes of treating or compounding macromolecular substances
    • C08J3/005Processes for mixing polymers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B60VEHICLES IN GENERAL
    • B60CVEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
    • B60C1/00Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
    • B60C1/0016Compositions of the tread
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L21/00Compositions of unspecified rubbers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

A heterogeneous plastic composition suitable for forming rubber-like articles is prepared by forming a first composition containing carbon black and a polymeric material, this first composition being plastic but vulcanizable to the elastic state characteristic of soft rubber, forming a second composition containing a polymeric material and also if desired containing carbon black, this second composition being of substantially greater plasticity, preferably at least 20 points, as measured by the Mooney plastometer, than the first composition, but also vulcanizable to the elastic state characteristic of soft rubber, and incorporating the first composition as discrete dispersed particles throughout the second composition as a matrix. Portions of the first composition may be added to a mass of the second composition while the latter is being masticated and a major proportion of the carbon black of the first composition may be incorporated therein by adding it to a latex of the polymeric material in the first composition, coagulating the latex and subjecting the coagulum to shear treatment prior to the incorporation of the first into the second composition, at least a portion of this shear treatment preferably taking place while the composition contains 5 per cent or more moisture, and the coagulum may be pelletized while wet to cause smearing of the carbon black. The amount of carbon black within the first composition is preferably greater than that within the second composition, preferred proportions being 40-100 parts by weight and 20-35 parts by weight respectively per 100 parts of composition. A major portion of the carbon black in the first composition is preferably a channel black, while the major portion of the carbon black used in the matrix is preferably a type giving less stiffening action per volume than the carbon black of the first composition and is preferably a furnace black. The polymeric material may be natural rubber or a polymer of one or more of butadiene or butadiene compounds such as butadiene-1,3, isoprene, haloprenes such as chlor-2-butadiene-1,3, 2,3-dichlorobutadiene-1,3, dimethyl butadiene and cyano-2-butadiene-1,3. It is preferred, however, especially for the disperse phase, to use copolymers of a major proportion of one or more such conjugated dienes, particularly butadiene and/or isoprene, with a minor proportion of one or more other polymerizable unsaturated materials, especially those containing an aliphatic olefin or vinyl group including aryl vinyl compounds such as styrene, alpha-alkyl styrenes, halogen-substituted aryl vinyl compounds such as mono-, di-and tri-chlor-substituted styrenes having chlorine substituents either in the nuclear or aliphatic portion thereof and including meta-, ortho- or para-chlorostyrenes, 2,5-, 2,4- and 1,2-dichlorostyrenes, acrylic acid, ethyl acrylate, methyl acrylate, methyl methacrylate, dimethyl-vinylethinyl carbinol, vinyl pyridine and lower olefin hydrocarbons such as isobutylene. There may also be present other materials such as methacrylylurea and vinyl ketones, substituted vinyl ketones, unsaturated, low molecular weight acids, such as fumaric acid, crotonic acid, their esters and amides, with or without polyhydric alcohols, mixtures of vinyl amide and phthalic anhydride or vinyl phthalamide, to modify the properties of the polymer. There may also be used rubbery products produced by condensation such as the reaction products of dibasic acids such as sebacic acid with glycols and diamines, and vulcanizable olefin polysulphide rubbers. Preferably a substantial proportion of the first composition is a synthetic rubber while a substantial proportion of the matric composition is a natural rubber. Normal compounding ingredients such as curing agents, particularly sulphur, pigments, activators, particularly zinc oxides, plasticizers, particularly pine tar, stearic acid, antioxidants and accelerators, particularly mercaptobenzothiazole, may be incorporated. The matrix composition is preferably plasticized with a polymerizable liquid or semi-solid which is capable of being further polymerized preferably to a rubbery polymer, a preferred plasticizer being obtained by polymerizing butadiene or a mixture of butadiene and carbon black to a liquid of syrupy consistency. Specification 328,812, [Class 70], is referred to.ALSO:A heterogeneous plastic composition suitable for forming rubberlike articles is prepared by forming a first composition containing carbon black and a polymeric material, this first composition being plastic but vulcanizable to the elastic state characteristic of soft rubber, forming a second composition containing a polymeric material and also if desired containing carbon black, this second composition being of substantially greater plasticity, preferably at least 20 points as measured by the Mooney plastometer, than the first composition but also vulcanizable to the elastic state characteristic of soft rubber, and incorporating the first composition as discrete dispersed particles throughout the second composition as a matrix. Portions of the first composition may be added to a mass of the second composition while the latter is being masticated and a major proportion of the carbon black of the first composition may be incorporated therein by adding it to a latex of the polymeric material in the first composition, coagulating the latex and subjecting the coagulum to shear treatment prior to the incorporation of the first into the second composition, at least a portion of this shear treatment preferably taking place while the composition contains 5 per cent or more moisture, and the coagulum may be pelletized while wet to cause smearing of the carbon black. The amount of carbon black within the first composition is preferably greater than that within the second composition, preferred proportions being 40-100 parts by weight and 20-35 parts by weight respectively per 100 parts of composition. A major portion of the carbon black in the first composition is preferably a channel black, while the major portion of the carbon black used in the matrix is preferably a type giving less stiffening action per volume than the carbon black of the first composition and is preferably a furnace black. The polymeric material utilised may be natural rubber or a polymer of one or more of butadiene or butadiene compounds such as butadiene-1,3, isoprene, haloprenes such as chlor-2-butadiene-1,3,2-3 dichlorobutadiene 1,3, dimethyl butadiene and cyano-2-butadiene 1,3. It is preferred, however, especially for the disperse phase, to use copolymers of a major proportion of one or more such conjugated dienes, particularly butadiene and/or isoprene, with a minor proportion of one or more other polymerizable unsaturated materials, especially those containing an aliphatic olefin or vinyl group including aryl vinyl compounds such as styrene, alpha-alkyl styrenes, halogen-substituted aryl vinyl compounds such as mono-, di- and trichlor-substituted styrenes having chlorine substituents either in the nuclear or aliphatic portion thereof and including meta-, ortho-or para-chlorostyrenes, 2,5-, 2,4- and 1,2-dichlorostyrenes, acrylic acid, ethyl acrylate, methyl acrylate, methyl methacrylate, dimethyl-vinylethinylcarbinol, vinyl pyridine and lower olefin hydrocarbons such as isobutylene. There may also be present other materials such as methacrylylurea and vinyl ketones, substituted vinyl ketones, unsaturated, low molecular weight acids, such as fumaric acid, crotonic acid, their esters and amides, with or without polyhydric alcohols, mixtures of vinyl amide and phthalic anhydride or vinyl phtalamide, to modify the properties of the polymer. There may also be used rubbery products produced by condensation such as the reaction products of dibasic acids such as sebacic acid with glycols and diamines and vulcanizable olefin polysulphide rubbers. Preferably a substantial proportion of the first composition is a synthetic rubber while a substantial proportion of the matrix composition is a natural rubber. Normal compounding ingredients such as curing agents, pigments, activators, plasticizers, stearic acid, anti-oxidants and accelerators may be incorporated. The matrix composition is preferably plasticized with a polymerizable liquid or semi-solid which is capable of being further polymerized preferably to a rubbery polymer, a preferred plasticizer being obtained by polymerizing butadiene or a mixture of butadiene and carbon black to a liquid of syrupy consistency. Specification 328,812, [Class 70], is referred to.
GB1886346A 1946-06-24 1946-06-24 Improvements in or relating to heterogeneous plastic compositions and method of making the same Expired GB635213A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB1886346A GB635213A (en) 1946-06-24 1946-06-24 Improvements in or relating to heterogeneous plastic compositions and method of making the same

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB1886346A GB635213A (en) 1946-06-24 1946-06-24 Improvements in or relating to heterogeneous plastic compositions and method of making the same

Publications (1)

Publication Number Publication Date
GB635213A true GB635213A (en) 1950-04-05

Family

ID=10119704

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1886346A Expired GB635213A (en) 1946-06-24 1946-06-24 Improvements in or relating to heterogeneous plastic compositions and method of making the same

Country Status (1)

Country Link
GB (1) GB635213A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1100269B (en) * 1952-07-17 1961-02-23 Monsanto Chemicals Process for tableting finely divided solid substances
EP0051450A1 (en) * 1980-10-31 1982-05-12 Polysar Limited Polymer-carbon black mixing
EP0942043A2 (en) * 1998-03-11 1999-09-15 The Goodyear Tire & Rubber Company Elastomer blend and use in tires

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1100269B (en) * 1952-07-17 1961-02-23 Monsanto Chemicals Process for tableting finely divided solid substances
EP0051450A1 (en) * 1980-10-31 1982-05-12 Polysar Limited Polymer-carbon black mixing
EP0942043A2 (en) * 1998-03-11 1999-09-15 The Goodyear Tire & Rubber Company Elastomer blend and use in tires
EP0942043A3 (en) * 1998-03-11 2001-11-07 The Goodyear Tire & Rubber Company Elastomer blend and use in tires

Similar Documents

Publication Publication Date Title
US2868754A (en) Stable latex composition comprising carboxyl-containing elastomer and alkali/metal/aluminate or the like as water-soluble curing agent
US4410656A (en) Method for rubber treatment
GB737086A (en) Improvements in pneumatic tyres and methods of making same
GB807018A (en) Improvements in self-sealing articles
GB684125A (en) Compositions comprising vulcanisation accelerators
GB936527A (en) Polymeric compositions
GB635213A (en) Improvements in or relating to heterogeneous plastic compositions and method of making the same
US2543844A (en) Plasticizing synthetic rubber with a reaction product of an alkyl mercaptan and a rubbery diolefin polymer
US4493925A (en) Rubber compositions and method for treating rubber with hydroxymethyl sulfinic salts
US2477015A (en) Vulcanization of butadiene elastomers
US2543867A (en) Process of making plasticizer for synthetic rubber by reacting a rubbery polymer of a diolefin with an alkyl mercaptan
GB623600A (en) Process of compounding elastogenic material
US2476341A (en) Rubberlike copolymers of allyl esters
US2340699A (en) Synthetic rubber composition
GB599937A (en) Modified rubber compositions
GB828643A (en) Improvements in latex sponge rubber
GB769823A (en) Improvements in rubber treatment
US3085990A (en) Heat treating rubbers with dinitrosoresorcinol
US2969341A (en) Vulcanizable butyl rubber-gr-s blends and process of making same
GB818285A (en) Improvements in vulcanizable compositions
GB741646A (en) Improvements in the production of rubber-resin products
GB572720A (en) Synthetic rubber compositions
US2696476A (en) Vulcanizable copolymers of diolefins with a thiophene
GB1302983A (en)
GB793548A (en) Improved vulcanisation process for rubber