GB634570A - Improvements in or relating to modified resin compositions - Google Patents
Improvements in or relating to modified resin compositionsInfo
- Publication number
- GB634570A GB634570A GB1677646A GB1677646A GB634570A GB 634570 A GB634570 A GB 634570A GB 1677646 A GB1677646 A GB 1677646A GB 1677646 A GB1677646 A GB 1677646A GB 634570 A GB634570 A GB 634570A
- Authority
- GB
- United Kingdom
- Prior art keywords
- drying
- oil
- heating
- styrene
- semi
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000011342 resin composition Substances 0.000 title 1
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 8
- 238000001035 drying Methods 0.000 abstract 7
- 239000003921 oil Substances 0.000 abstract 7
- 235000019198 oils Nutrition 0.000 abstract 7
- 238000010438 heat treatment Methods 0.000 abstract 5
- RSWGJHLUYNHPMX-UHFFFAOYSA-N 1,4a-dimethyl-7-propan-2-yl-2,3,4,4b,5,6,10,10a-octahydrophenanthrene-1-carboxylic acid Chemical compound C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 abstract 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 abstract 3
- 150000005846 sugar alcohols Polymers 0.000 abstract 3
- MLKXDPUZXIRXEP-UHFFFAOYSA-N 2-[6-fluoro-2-methyl-3-[(4-methylsulfinylphenyl)methylidene]-1-indenyl]acetic acid Chemical class CC1=C(CC(O)=O)C2=CC(F)=CC=C2C1=CC1=CC=C(S(C)=O)C=C1 MLKXDPUZXIRXEP-UHFFFAOYSA-N 0.000 abstract 1
- 241000016649 Copaifera officinalis Species 0.000 abstract 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 abstract 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 1
- 239000004606 Fillers/Extenders Substances 0.000 abstract 1
- 244000068988 Glycine max Species 0.000 abstract 1
- 235000010469 Glycine max Nutrition 0.000 abstract 1
- 240000006240 Linum usitatissimum Species 0.000 abstract 1
- 235000004431 Linum usitatissimum Nutrition 0.000 abstract 1
- 235000004443 Ricinus communis Nutrition 0.000 abstract 1
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 abstract 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 239000008199 coating composition Substances 0.000 abstract 1
- 230000032050 esterification Effects 0.000 abstract 1
- 238000005886 esterification reaction Methods 0.000 abstract 1
- 150000002148 esters Chemical class 0.000 abstract 1
- 239000000945 filler Substances 0.000 abstract 1
- 235000021323 fish oil Nutrition 0.000 abstract 1
- 235000004426 flaxseed Nutrition 0.000 abstract 1
- 239000000976 ink Substances 0.000 abstract 1
- 235000021388 linseed oil Nutrition 0.000 abstract 1
- 239000000944 linseed oil Substances 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 239000000025 natural resin Substances 0.000 abstract 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 abstract 1
- 239000000049 pigment Substances 0.000 abstract 1
- 229920001223 polyethylene glycol Polymers 0.000 abstract 1
- 229940068917 polyethylene glycols Drugs 0.000 abstract 1
- 239000002685 polymerization catalyst Substances 0.000 abstract 1
- -1 polypentaerythritol Chemical compound 0.000 abstract 1
- QROGIFZRVHSFLM-UHFFFAOYSA-N prop-1-enylbenzene Chemical class CC=CC1=CC=CC=C1 QROGIFZRVHSFLM-UHFFFAOYSA-N 0.000 abstract 1
- 238000010992 reflux Methods 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- 239000000600 sorbitol Substances 0.000 abstract 1
- 150000003440 styrenes Chemical class 0.000 abstract 1
- 238000006467 substitution reaction Methods 0.000 abstract 1
- 239000003784 tall oil Substances 0.000 abstract 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F212/02—Monomers containing only one unsaturated aliphatic radical
- C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
- C08F212/06—Hydrocarbons
- C08F212/08—Styrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F242/00—Copolymers of drying oils with other monomers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/08—Printing inks based on natural resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09F—NATURAL RESINS; FRENCH POLISH; DRYING-OILS; OIL DRYING AGENTS, i.e. SICCATIVES; TURPENTINE
- C09F1/00—Obtaining purification, or chemical modification of natural resins, e.g. oleo-resins
- C09F1/04—Chemical modification, e.g. esterification
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Materials Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
Styrene and/or its polymerizable substitution derivatives is interpolymerized by heating with a resin acid, e.g. a natural resin containing at least one free carboxyl group, i.e. rosin, cracked copals, tall oil, the resin acid forming 10-90 per cent of the mixture. Specified styrene compounds are mono- and di-chloro- and methyl styrenes and commercial styrene. The product may be at least partially esterified by heating, if desired in presence of an esterifying catalyst, with an alcohol, preferably a polyhydric alcohol or a drying oil partial ester, e.g. an oil obtained by heating a drying or semi-drying oil with a polyhydric alcohol. The product may be mixed and dispersed by heating with a drying or semi-drying oil, or the oils may be added prior to the interpolymerization or esterification. The oils may be conjugated, listed are linseed, soybean, dehydrated castor, chinawood, oiticica and a fish oil extract resembling linseed oil. Polyhydric alcohols specified include glycerol, pentaerythritol, polypentaerythritol, sorbitol and mono- and poly-ethylene glycols. The interpolymerization is effected by heating, preferably at the reflux temperature of styrene. The styrene may be added portion-wise during the reaction. Percompound polymerization catalysts may be employed. The products may be used as coating compositions or printing inks, if desired with addition of drying or semi-drying oils, pigments, fillers, extenders, driers and solvents.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB1677646A GB634570A (en) | 1946-06-03 | 1946-06-03 | Improvements in or relating to modified resin compositions |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB1677646A GB634570A (en) | 1946-06-03 | 1946-06-03 | Improvements in or relating to modified resin compositions |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB634570A true GB634570A (en) | 1950-03-22 |
Family
ID=10083464
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB1677646A Expired GB634570A (en) | 1946-06-03 | 1946-06-03 | Improvements in or relating to modified resin compositions |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB634570A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE974217C (en) * | 1951-07-03 | 1960-10-20 | Herberts & Co Gmbh Dr Kurt | Process for the production of copolymers from aromatic vinyl hydrocarbons and for the production of alkyd resins, polyhydric alcohols, polyhydric and monohydric carboxylic acids |
| EP0134592A2 (en) * | 1983-07-09 | 1985-03-20 | Rütgerswerke Aktiengesellschaft | Acid-modified aromatic hydrocarbon resins and process for their preparation |
-
1946
- 1946-06-03 GB GB1677646A patent/GB634570A/en not_active Expired
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE974217C (en) * | 1951-07-03 | 1960-10-20 | Herberts & Co Gmbh Dr Kurt | Process for the production of copolymers from aromatic vinyl hydrocarbons and for the production of alkyd resins, polyhydric alcohols, polyhydric and monohydric carboxylic acids |
| EP0134592A2 (en) * | 1983-07-09 | 1985-03-20 | Rütgerswerke Aktiengesellschaft | Acid-modified aromatic hydrocarbon resins and process for their preparation |
| EP0134592A3 (en) * | 1983-07-09 | 1986-08-20 | Rutgerswerke Aktiengesellschaft | Acid-modified aromatic hydrocarbon resins and process for their preparation |
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