GB630525A - Process for the manufacture of new acid dyestuffs of the anthraquinone series - Google Patents

Process for the manufacture of new acid dyestuffs of the anthraquinone series

Info

Publication number
GB630525A
GB630525A GB17608/47A GB1760847A GB630525A GB 630525 A GB630525 A GB 630525A GB 17608/47 A GB17608/47 A GB 17608/47A GB 1760847 A GB1760847 A GB 1760847A GB 630525 A GB630525 A GB 630525A
Authority
GB
United Kingdom
Prior art keywords
amino
condensed
bromanthraquinone
disulphonic acid
sulpho
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB17608/47A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sandoz AG
Original Assignee
Sandoz AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sandoz AG filed Critical Sandoz AG
Publication of GB630525A publication Critical patent/GB630525A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09BORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B1/00Dyes with anthracene nucleus not condensed with any other ring
    • C09B1/16Amino-anthraquinones
    • C09B1/20Preparation from starting materials already containing the anthracene nucleus
    • C09B1/26Dyes with amino groups substituted by hydrocarbon radicals
    • C09B1/28Dyes with amino groups substituted by hydrocarbon radicals substituted by alkyl, aralkyl or cyclo alkyl groups
    • C09B1/30Dyes with amino groups substituted by hydrocarbon radicals substituted by alkyl, aralkyl or cyclo alkyl groups sulfonated
    • C09B1/303Dyes with amino groups substituted by hydrocarbon radicals substituted by alkyl, aralkyl or cyclo alkyl groups sulfonated only sulfonated in the anthracene nucleus

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Dyes are made by condensing an aminoanthraquinone of the formula <FORM:0630525/IV (c)/1> where X is chlorine, bromine, or sulpho, Y is chlorine or bromine, and one Z is sulpho, the other being hydrogen, with a hydroaromatic amine of the formula <FORM:0630525/IV (c)/2> where R stands for H, methyl, or ethyl, or where two adjacent R's form starting points of an aromatic or hydroaromatic nucleus, the other R's being hydrogen. Where X is chlorine or bromine, it is subsequently replaced by sulpho by reaction with an alkali metal sulphite. Various mono-, di-, and tri-alkyl cyclohexylamines are specified, and also 1-amino-or 2-amino-1.2.3.4-tetra- or decahydronaphthalene. In examples: (1) 1-amino-4-bromanthraquinone - 2.8 - or 2.5 - disulphonic acid sodium salt is condensed with aminocyclohexane, 1-amino-2.4-diethylcyclohexane, or the corresponding dimethyl body; (2) 1-amino-4 - chlor - anthraquinone - 2.5 - disulphonic acid sodium salt is condensed with each of the possible monoethyl- or monomethyl-cyclohexylamines; (3) 1-amino-4-bromanthraquinone-2.5- or 2.8-disulphonic acid potassium salt is condensed with 3.4-dimethyl- or diethyl-3.4-methylethyl- or 3.5-dimethyl-cyclohexylamine; (4) 1-amino-2.4-dibromanthraquinone-5-sulphonic acid potassium salt is condensed with 1-amino-2.4.6-trimethylcyclohexane or its isomers, followed by reaction with a sulphite; (5) 1-amino-4-bromanthraquinone-2.5- or 2.8-disulphonic acid potassium salt is condensed with 1 - amino - 3.4.5 - trimethylcyclohexane; (6) 1 - amino - 4 - bromanthraquinone - 2.8 - or 2.5-disulphonic acid potassium or other salt is condensed with 2-amino-1.2.3.4-tetrahydronaphthalene; (7) 1 - amino - 4 - bromanthraquinone-2.5-disulphonic acid is condensed with 1 - amino - 1.2.3.4 - tetrahydronaphthalene, or 1- or 2-amino-decahydronaphthalene. Specification 276,408, [Class 2 (iii)], is referred to.
GB17608/47A 1946-07-05 1947-07-03 Process for the manufacture of new acid dyestuffs of the anthraquinone series Expired GB630525A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CH630525X 1946-07-05

Publications (1)

Publication Number Publication Date
GB630525A true GB630525A (en) 1949-10-14

Family

ID=4524712

Family Applications (1)

Application Number Title Priority Date Filing Date
GB17608/47A Expired GB630525A (en) 1946-07-05 1947-07-03 Process for the manufacture of new acid dyestuffs of the anthraquinone series

Country Status (1)

Country Link
GB (1) GB630525A (en)

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