GB614456A - Improvements in and relating to the oxidation of aliphatic olefinic hydrocarbons - Google Patents

Improvements in and relating to the oxidation of aliphatic olefinic hydrocarbons

Info

Publication number
GB614456A
GB614456A GB1943146A GB1943146A GB614456A GB 614456 A GB614456 A GB 614456A GB 1943146 A GB1943146 A GB 1943146A GB 1943146 A GB1943146 A GB 1943146A GB 614456 A GB614456 A GB 614456A
Authority
GB
United Kingdom
Prior art keywords
hydroperoxide
oxygen
unsaturated
cnh2n
olefines
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1943146A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
HERBERT MAX EMIL STEINER
PETROCARBON Ltd
VINCENT RICHARD GRAY
Original Assignee
HERBERT MAX EMIL STEINER
PETROCARBON Ltd
VINCENT RICHARD GRAY
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by HERBERT MAX EMIL STEINER, PETROCARBON Ltd, VINCENT RICHARD GRAY filed Critical HERBERT MAX EMIL STEINER
Priority to GB1943146A priority Critical patent/GB614456A/en
Publication of GB614456A publication Critical patent/GB614456A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C409/00—Peroxy compounds
    • C07C409/02—Peroxy compounds the —O—O— group being bound between a carbon atom, not further substituted by oxygen atoms, and hydrogen, i.e. hydroperoxides
    • C07C409/04—Peroxy compounds the —O—O— group being bound between a carbon atom, not further substituted by oxygen atoms, and hydrogen, i.e. hydroperoxides the carbon atom being acyclic
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C407/00—Preparation of peroxy compounds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Aliphatic mono-olefines other than ethylene are treated in the liquid phase at -50 DEG to 150 DEG C. and at atmospheric, raised or reduced pressure with oxygen or a gas containing oxygen in the absence of a catalyst, but under the influence of ultra-violet light. Under these conditions an olefine CnH2n yields an unsaturated hydroperoxide CnH2n-1OOH as the main reaction product, but unsaturated aldehydes, ketones and acids may also be produced. An example is given in which amylene (mainly trimethylethylene) is treated with oxygen at atmospheric temperature and pressure in an irradiated quartz tube to yield a product containing 3 - methyl - 2 - butenyl hydroperoxide (Me2C : CHCH2OOH) and 2-methyl-2-butenyl hydroperoxide (MeCH : CMeCH2OOH); these compounds yield unsaturated alcohols by reduction with sodium sulphite. Other specified starting materials are propylene, n-butene-1, n-butene-2, isobutene, n-pentene-1, n-pentene-2, n-hexene-2, n-heptene-3 and mixtures of mono-olefines with one another or with other substances, e.g. paraffins.
GB1943146A 1946-06-28 1946-06-28 Improvements in and relating to the oxidation of aliphatic olefinic hydrocarbons Expired GB614456A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB1943146A GB614456A (en) 1946-06-28 1946-06-28 Improvements in and relating to the oxidation of aliphatic olefinic hydrocarbons

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB1943146A GB614456A (en) 1946-06-28 1946-06-28 Improvements in and relating to the oxidation of aliphatic olefinic hydrocarbons

Publications (1)

Publication Number Publication Date
GB614456A true GB614456A (en) 1948-12-15

Family

ID=10129272

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1943146A Expired GB614456A (en) 1946-06-28 1946-06-28 Improvements in and relating to the oxidation of aliphatic olefinic hydrocarbons

Country Status (1)

Country Link
GB (1) GB614456A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3109800A (en) * 1960-08-22 1963-11-05 Monsanto Chemicals Olefin separation

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3109800A (en) * 1960-08-22 1963-11-05 Monsanto Chemicals Olefin separation

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