GB608052A - Improvements in or relating to phenol-formaldehyde resins - Google Patents
Improvements in or relating to phenol-formaldehyde resinsInfo
- Publication number
- GB608052A GB608052A GB35252/45A GB3525245A GB608052A GB 608052 A GB608052 A GB 608052A GB 35252/45 A GB35252/45 A GB 35252/45A GB 3525245 A GB3525245 A GB 3525245A GB 608052 A GB608052 A GB 608052A
- Authority
- GB
- United Kingdom
- Prior art keywords
- phenol
- formaldehyde
- paper
- mols
- per cent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G14/00—Condensation polymers of aldehydes or ketones with two or more other monomers covered by at least two of the groups C08G8/00 - C08G12/00
- C08G14/02—Condensation polymers of aldehydes or ketones with two or more other monomers covered by at least two of the groups C08G8/00 - C08G12/00 of aldehydes
- C08G14/04—Condensation polymers of aldehydes or ketones with two or more other monomers covered by at least two of the groups C08G8/00 - C08G12/00 of aldehydes with phenols
- C08G14/06—Condensation polymers of aldehydes or ketones with two or more other monomers covered by at least two of the groups C08G8/00 - C08G12/00 of aldehydes with phenols and monomers containing hydrogen attached to nitrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G8/00—Condensation polymers of aldehydes or ketones with phenols only
- C08G8/04—Condensation polymers of aldehydes or ketones with phenols only of aldehydes
- C08G8/08—Condensation polymers of aldehydes or ketones with phenols only of aldehydes of formaldehyde, e.g. of formaldehyde formed in situ
- C08G8/10—Condensation polymers of aldehydes or ketones with phenols only of aldehydes of formaldehyde, e.g. of formaldehyde formed in situ with phenol
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Phenolic Resins Or Amino Resins (AREA)
Abstract
Phenol-formaldehyde resins having substantially no odour are prepared by refluxing for 90 to 135 (e.g. 125) minutes in aqueous medium 1 mol. of phenol with 1.15 to 1.35 mols. (e.g. 1.25 mols.) of formaldehyde in the presence as catalyst of .45 to .55 per cent (e.g. .5 per cent) (by weight of phenol) of ethylene diamine or an equivalent amount of another aliphatic amine, and distilling off volatile material under a pressure of about .1 to .01 atmosphere at 100-150 DEG C. and adding a solvent, e.g. toluene, benzene, alcohol, or mixtures thereof, to stop the reaction and dissolve the condensate. Formaldehyde may be replaced by its polymers, e.g. paraformaldehyde. Other amine catalysts referred to are p hexamethylene tetramine, dimethylamine, methylamine and ethylamine. The solution may be used for impregnating fibrous materials, e.g. kraft paper, a -cellulose paper, cotton duck, glass cloth, asbestos cloth or paper, which after drying may be pressed to give laminated articles, e.g. refrigerator door panels, or be shredded and moulded. The Specification as open to inspection under Sect. 91 refers to the use of substances engendering formaldehyde and to distillation at 0.2 atmospheres pressure. This subject-matter does not appear in the Specification as accepted.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US608052XA | 1945-01-01 | 1945-01-01 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB608052A true GB608052A (en) | 1948-09-09 |
Family
ID=22031858
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB35252/45A Expired GB608052A (en) | 1945-01-01 | 1945-12-31 | Improvements in or relating to phenol-formaldehyde resins |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB608052A (en) |
-
1945
- 1945-12-31 GB GB35252/45A patent/GB608052A/en not_active Expired
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