GB608052A - Improvements in or relating to phenol-formaldehyde resins - Google Patents

Improvements in or relating to phenol-formaldehyde resins

Info

Publication number
GB608052A
GB608052A GB35252/45A GB3525245A GB608052A GB 608052 A GB608052 A GB 608052A GB 35252/45 A GB35252/45 A GB 35252/45A GB 3525245 A GB3525245 A GB 3525245A GB 608052 A GB608052 A GB 608052A
Authority
GB
United Kingdom
Prior art keywords
phenol
formaldehyde
paper
mols
per cent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB35252/45A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Westinghouse Electric International Co
Original Assignee
Westinghouse Electric International Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Westinghouse Electric International Co filed Critical Westinghouse Electric International Co
Publication of GB608052A publication Critical patent/GB608052A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G14/00Condensation polymers of aldehydes or ketones with two or more other monomers covered by at least two of the groups C08G8/00 - C08G12/00
    • C08G14/02Condensation polymers of aldehydes or ketones with two or more other monomers covered by at least two of the groups C08G8/00 - C08G12/00 of aldehydes
    • C08G14/04Condensation polymers of aldehydes or ketones with two or more other monomers covered by at least two of the groups C08G8/00 - C08G12/00 of aldehydes with phenols
    • C08G14/06Condensation polymers of aldehydes or ketones with two or more other monomers covered by at least two of the groups C08G8/00 - C08G12/00 of aldehydes with phenols and monomers containing hydrogen attached to nitrogen
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G8/00Condensation polymers of aldehydes or ketones with phenols only
    • C08G8/04Condensation polymers of aldehydes or ketones with phenols only of aldehydes
    • C08G8/08Condensation polymers of aldehydes or ketones with phenols only of aldehydes of formaldehyde, e.g. of formaldehyde formed in situ
    • C08G8/10Condensation polymers of aldehydes or ketones with phenols only of aldehydes of formaldehyde, e.g. of formaldehyde formed in situ with phenol

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Phenolic Resins Or Amino Resins (AREA)

Abstract

Phenol-formaldehyde resins having substantially no odour are prepared by refluxing for 90 to 135 (e.g. 125) minutes in aqueous medium 1 mol. of phenol with 1.15 to 1.35 mols. (e.g. 1.25 mols.) of formaldehyde in the presence as catalyst of .45 to .55 per cent (e.g. .5 per cent) (by weight of phenol) of ethylene diamine or an equivalent amount of another aliphatic amine, and distilling off volatile material under a pressure of about .1 to .01 atmosphere at 100-150 DEG C. and adding a solvent, e.g. toluene, benzene, alcohol, or mixtures thereof, to stop the reaction and dissolve the condensate. Formaldehyde may be replaced by its polymers, e.g. paraformaldehyde. Other amine catalysts referred to are p hexamethylene tetramine, dimethylamine, methylamine and ethylamine. The solution may be used for impregnating fibrous materials, e.g. kraft paper, a -cellulose paper, cotton duck, glass cloth, asbestos cloth or paper, which after drying may be pressed to give laminated articles, e.g. refrigerator door panels, or be shredded and moulded. The Specification as open to inspection under Sect. 91 refers to the use of substances engendering formaldehyde and to distillation at 0.2 atmospheres pressure. This subject-matter does not appear in the Specification as accepted.
GB35252/45A 1945-01-01 1945-12-31 Improvements in or relating to phenol-formaldehyde resins Expired GB608052A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US608052XA 1945-01-01 1945-01-01

Publications (1)

Publication Number Publication Date
GB608052A true GB608052A (en) 1948-09-09

Family

ID=22031858

Family Applications (1)

Application Number Title Priority Date Filing Date
GB35252/45A Expired GB608052A (en) 1945-01-01 1945-12-31 Improvements in or relating to phenol-formaldehyde resins

Country Status (1)

Country Link
GB (1) GB608052A (en)

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