GB602886A - Improvements in and relating to pigment emulsions, the manufacture thereof and the dyeing of fabrics therewith - Google Patents

Improvements in and relating to pigment emulsions, the manufacture thereof and the dyeing of fabrics therewith

Info

Publication number
GB602886A
GB602886A GB1850345A GB1850345A GB602886A GB 602886 A GB602886 A GB 602886A GB 1850345 A GB1850345 A GB 1850345A GB 1850345 A GB1850345 A GB 1850345A GB 602886 A GB602886 A GB 602886A
Authority
GB
United Kingdom
Prior art keywords
pigment
organic liquid
resins
alkylolamine
ammonia
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1850345A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Geigy Co Ltd
Original Assignee
Geigy Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Geigy Co Ltd filed Critical Geigy Co Ltd
Priority to GB1850345A priority Critical patent/GB602886A/en
Publication of GB602886A publication Critical patent/GB602886A/en
Expired legal-status Critical Current

Links

Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Paints Or Removers (AREA)

Abstract

An emulsion for use in dyeing and printing comprises an aqueous continuous phase containing a pigment dispersed therein with the aid of a water-soluble compound formed from a non-convertible alkyd resin and ammonia or an alkylolamine, e.g. triethanolamine, and a disperse phase comprising a thermo-hardening synthetic resin binder dissolved in a water-immiscible organic liquid. In an example a castor oil-modified alkyd resin of acid value 25 to 30, mixed with ethylene glycol monoethyl ether, is used. Suitable thermo-hardening synthetic resins are those formed from formaldehyde and urea, thiourea, buiret and melamine, and heat-convertible phenol-aldehyde and alkyd resins. Plasticisers such as dibutyl phthalate and tricresyl phosphate may be included. Organic liquids which may be present are benzene, toluene, xylene, white spirit, solvent naphtha, butanol, and cyclohexanol. The pigments used may be azo pigments, metal salts of nitroso-beta-naphthol, phthalocyanine pigments, iron oxides, chrome yellows, and titanium dioxide. Thickeners, such as sodium alginate, gum tragacanth, British gum, and methyl cellulose may be added to the emulsions. A fatty acid such as oleic acid may be present in a quantity insufficient to combine with all the ammonia or alkylolamine. In preparing the emulsion, the thermo-hardening synthetic resin dissolved in the organic liquid may be dispersed in a mixture of the pigment, water, and dispersing agent; alternatively, the alkyd resin component of the dispersing agent may be originally present in the organic liquid. Another method of preparation involves emulsifying a mixture of the pigment, organic liquid, and resins in an aqueous solution containing the ammonia or alkylolamine; the pigment migrates into the aqueous phase. The emulsions are applied by padding to fabrics, paper, or chome leather, and the material then dried and heated to harden the binder. According to the Provisional Specification the emulsion may include thermoplastic resins, such as polyvinyl esters, polystyrene, and polyacrylic acid derivatives.ALSO:An emulsion for use in dyeing and printing comprises an aqueous continuous phase containing a pigment dispersed therein with the aid of a water-soluble compound formed from a non-convertible alkyd resin and ammonia or an alkylolamine, e.g. triethanolamine, and a disperse phase comprising a thermo-hardening synthetic resin binder dissolved in a water-immiscible organic liquid. In an example, a castor oil-modified alkyd resin of acid value 25 to 30, mixed with ethylene glycol monoethyl ether, is used. Suitable thermo-hardening synthetic resins are those formed from formaldehyde and urea, thiourea, buiret and melamine, and heat-convertible phenol-aldehyde and alkyd resins. Plasticisers such as dibutyl phthalate and tricresyl phosphate may be included. Organic liquids which may be present are benzene, toluene, xylene, white spirit, solvent naphtha, butanol and cyclohexanol. The pigments used may be azo pigments, metal salts of nitroso-beta-naphthol, phthalocyanine pigments, iron oxides, chrome yellows and titanium dioxide. Thickeners, such as sodium alginate, gum tragacanth, British gum and methyl cellulose may be added to the emulsions. A fatty acid such as oleic acid may be present in a quantity insufficient to combine with all the ammonia or alkylolamine. In preparing the emulsion, the thermo-hardening synthetic resin dissolved in the organic liquid may be dispersed in a mixture of the pigment, water and dispersing agent; alternatively, the alkyd resin component of the dispersing agent may be originally present in the organic liquid. Another method of preparation involves emulsifying a mixture of the pigment, organic liquid and resins in an aqueous solution containing the ammonia or alkylolamine; the pigment migrates into the aqueous phase. The emulsions are applied by padding to fabrics, paper, or chrome leather, and the material then dried and heated to harden the binder. According to the Provisional Specification, the emulsion may include thermoplastic resins, such as polyvinyl esters, polystyrene and polyacrylic acid derivatives.ALSO:An emulsion for use in dyeing and printing comprises an aqueous continuous phase containing a pigment dispersed therein with the aid of a water-soluble compound formed from a non-convertible alkyd resin and ammonia or an alkylolamine, e.g. triethanolamine, and a disperse phase comprising a thermo-hardening synthetic resin binder dissolved in a water-immiscible organic liquid. In an example a castor oil-modified alkyd resin of acid value 25 to 30, mixed with ethylene glycol monoethyl ether, is used. Suitable thermo-hardening synthetic resins are those formed from formaldehyde and urea, thiourea, biuret and melamine, and heat-convertible phenol-aldehyde and alkyd resins. Plasticisers such as dibutyl phthalate and tricresyl phosphate may be included. Organic liquids which may be present are benzene, toluene, xylene, white spirit, solvent naphtha, butanol, and cyclohexanol. The pigments used may be azo pigments, metal salts of nitroso-beta-naphthol, phthalocyanine pigments, iron oxides, chrome yellows, and titanium dioxide. Thickeners, such as sodium alginate, gum tragacanth, British gum, and methyl cellulose may be added to the emulsions. A fatty acid such as oleic acid may be present in a quantity insufficient to combine with all the ammonia or alkylolamine. In preparing the emulsion, the thermo-hardening synthetic resin dissolved in the organic liquid may be dispersed in a mixture of the pigment, water, and dispersing agent; alternatively the alkyd resin component of the dispersing agent may be originally present in the organic liquid. Another method of preparation involves emulsifying a mixture of the pigment, organic liquid, and resins in an aqueous solution containing the ammonia or alkylolamine; the pigment migrates into the aqueous phase. The emulsions are applied by padding to fabrics, paper, or chrome leather, and the material then dried and heated to harden the binder. According to the Provisional Specification the emulsion may include thermoplastic resins, such as polyvinyl esters, polystyrene, and polyacrylic acid derivatives.
GB1850345A 1945-07-19 1945-07-19 Improvements in and relating to pigment emulsions, the manufacture thereof and the dyeing of fabrics therewith Expired GB602886A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB1850345A GB602886A (en) 1945-07-19 1945-07-19 Improvements in and relating to pigment emulsions, the manufacture thereof and the dyeing of fabrics therewith

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB1850345A GB602886A (en) 1945-07-19 1945-07-19 Improvements in and relating to pigment emulsions, the manufacture thereof and the dyeing of fabrics therewith

Publications (1)

Publication Number Publication Date
GB602886A true GB602886A (en) 1948-06-04

Family

ID=10113543

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1850345A Expired GB602886A (en) 1945-07-19 1945-07-19 Improvements in and relating to pigment emulsions, the manufacture thereof and the dyeing of fabrics therewith

Country Status (1)

Country Link
GB (1) GB602886A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20190264030A1 (en) * 2017-12-01 2019-08-29 Sanyo Color Works, Ltd. Pigment composition

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20190264030A1 (en) * 2017-12-01 2019-08-29 Sanyo Color Works, Ltd. Pigment composition
US11549018B2 (en) * 2017-12-01 2023-01-10 Sanyo Color Works, Ltd. Pigment composition

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