GB595447A - Improvements in or relating to the manufacture of synthetic resins - Google Patents
Improvements in or relating to the manufacture of synthetic resinsInfo
- Publication number
- GB595447A GB595447A GB2027843A GB2027843A GB595447A GB 595447 A GB595447 A GB 595447A GB 2027843 A GB2027843 A GB 2027843A GB 2027843 A GB2027843 A GB 2027843A GB 595447 A GB595447 A GB 595447A
- Authority
- GB
- United Kingdom
- Prior art keywords
- acid
- alpha
- esters
- specified
- ethenoid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000004519 manufacturing process Methods 0.000 title 1
- 229920003002 synthetic resin Polymers 0.000 title 1
- 239000000057 synthetic resin Substances 0.000 title 1
- 150000002148 esters Chemical class 0.000 abstract 5
- 150000001875 compounds Chemical class 0.000 abstract 4
- WBYWAXJHAXSJNI-VOTSOKGWSA-M .beta-Phenylacrylic acid Natural products [O-]C(=O)\C=C\C1=CC=CC=C1 WBYWAXJHAXSJNI-VOTSOKGWSA-M 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- LGXVIGDEPROXKC-UHFFFAOYSA-N 1,1-Dichloroethene Chemical compound ClC(Cl)=C LGXVIGDEPROXKC-UHFFFAOYSA-N 0.000 abstract 1
- CUGZWHZWSVUSBE-UHFFFAOYSA-N 2-(oxiran-2-ylmethoxy)ethanol Chemical compound OCCOCC1CO1 CUGZWHZWSVUSBE-UHFFFAOYSA-N 0.000 abstract 1
- SZTBMYHIYNGYIA-UHFFFAOYSA-N 2-chloroacrylic acid Chemical compound OC(=O)C(Cl)=C SZTBMYHIYNGYIA-UHFFFAOYSA-N 0.000 abstract 1
- OYUNTGBISCIYPW-UHFFFAOYSA-N 2-chloroprop-2-enenitrile Chemical compound ClC(=C)C#N OYUNTGBISCIYPW-UHFFFAOYSA-N 0.000 abstract 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N 2-methyl-2-propenoic acid methyl ester Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 abstract 1
- ROOXNKNUYICQNP-UHFFFAOYSA-N Ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 abstract 1
- 239000004160 Ammonium persulphate Substances 0.000 abstract 1
- 239000004342 Benzoyl peroxide Substances 0.000 abstract 1
- LDHQCZJRKDOVOX-NSCUHMNNSA-N Crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 abstract 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract 1
- 125000001931 aliphatic group Chemical group 0.000 abstract 1
- 235000019395 ammonium persulphate Nutrition 0.000 abstract 1
- 235000019400 benzoyl peroxide Nutrition 0.000 abstract 1
- 229930016911 cinnamic acid Natural products 0.000 abstract 1
- 235000013985 cinnamic acid Nutrition 0.000 abstract 1
- 239000000839 emulsion Substances 0.000 abstract 1
- 150000002170 ethers Chemical class 0.000 abstract 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N fumaric acid Chemical compound OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 abstract 1
- CTKINSOISVBQLD-UHFFFAOYSA-N glycidol Chemical compound OCC1CO1 CTKINSOISVBQLD-UHFFFAOYSA-N 0.000 abstract 1
- 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 150000002367 halogens Chemical class 0.000 abstract 1
- 239000003701 inert diluent Substances 0.000 abstract 1
- 239000011976 maleic acid Substances 0.000 abstract 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- HETCEOQFVDFGSY-UHFFFAOYSA-N prop-1-en-2-yl acetate Chemical compound CC(=C)OC(C)=O HETCEOQFVDFGSY-UHFFFAOYSA-N 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 abstract 1
Landscapes
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
A mixture of a halogen-containing ethenoid compound and an ester or ether-ester containing both a glycidyl radicle and an unsaturated aliphatic group is polymerized by the action of heat and/or actinic light and/or a peroxidic catalyst. Specified esters are those obtained from glycidol and crotonic acid, maleic acid, acrylic acid, alpha-chloracrylic acid, methacrylic acid and cinnamic acid. Specified ether-esters are the maleic and crotonic esters of ethylene glycol monoglycidyl ether. Specified ethenoid compounds are vinylchloride, vinylidene chloride, alpha-chloracrylonitrile, alpha-chloracrylic esters and alpha-chlorvinyl ethers. Specified catalysts are crotonyl peroxide, benzoyl peroxide and ammonium persulphate. Non-halogenated ethenoid compounds such as methyl methacrylate and vinyl acetate may also be present. The polymerization may be effected in aqueous emulsion or in the presence of a solvent or inert diluent, preferably at between 20 DEG C. and 80 DEG C., the preferred proportion of ester being from 1 to 50 per cent by weight of the halogen-ethenoid compound. Specifications 572,767 and 586,715 are referred to.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US567527A US2470324A (en) | 1943-12-03 | 1944-12-09 | Glycidyl ester copolymers |
| FR947258D FR947258A (en) | 1943-12-03 | 1947-05-28 | Improvements in the manufacture of polymerization products from polymerizable organic chlorine compounds |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB595447A true GB595447A (en) | 1947-12-05 |
Family
ID=1735335
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB2027843A Expired GB595447A (en) | 1943-12-03 | 1943-12-03 | Improvements in or relating to the manufacture of synthetic resins |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB595447A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2687405A (en) * | 1950-02-16 | 1954-08-24 | Du Pont | Allyl glycidyl ether/acrylate ester copolymers |
| US4146698A (en) | 1977-10-06 | 1979-03-27 | Stauffer Chemical Company | Process for the polymerization of vinyl chloride in the presence of calcium & zinc acrylate |
-
1943
- 1943-12-03 GB GB2027843A patent/GB595447A/en not_active Expired
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2687405A (en) * | 1950-02-16 | 1954-08-24 | Du Pont | Allyl glycidyl ether/acrylate ester copolymers |
| US4146698A (en) | 1977-10-06 | 1979-03-27 | Stauffer Chemical Company | Process for the polymerization of vinyl chloride in the presence of calcium & zinc acrylate |
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