GB575652A - The formation and polymerization of esters of dicarbamic acids - Google Patents
The formation and polymerization of esters of dicarbamic acidsInfo
- Publication number
- GB575652A GB575652A GB5358/44A GB535844A GB575652A GB 575652 A GB575652 A GB 575652A GB 5358/44 A GB5358/44 A GB 5358/44A GB 535844 A GB535844 A GB 535844A GB 575652 A GB575652 A GB 575652A
- Authority
- GB
- United Kingdom
- Prior art keywords
- condensed
- allyl alcohol
- esters
- diisocyanate
- polymerization
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F18/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
- C08F18/24—Esters of carbonic or haloformic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F18/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
- C08F18/22—Esters containing nitrogen
Abstract
Allyl alcohol is condensed with organic diisocyanates to give diallyl esters of the corresponding dicarbamic acids. Aliphatic, cycloaliphatic, aromatic and heterocyclic diisocyanates are specified and derivatives of allyl alcohol with substituents in the 1- and 2-positions may also be used. The products are polymerised by heating to 80-150 DEG C. with a catalyst such as benzoyl peroxide, acetyl peroxide, sodium peroxide, sodium perborate or tertiary butyl chromate. In the examples: (1) allyl alcohol is condensed with hexamethylene diisocyanate, meta-phenylene diisocyanate or cyclohexylene diisocyanate; (2) 2-methallyl alcohol is condensed with hexamethylene diisocyanate.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US575652XA | 1943-09-02 | 1943-09-02 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB575652A true GB575652A (en) | 1946-02-27 |
Family
ID=22011379
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB5358/44A Expired GB575652A (en) | 1943-09-02 | 1944-03-22 | The formation and polymerization of esters of dicarbamic acids |
Country Status (3)
Country | Link |
---|---|
BE (1) | BE462146A (en) |
FR (1) | FR915809A (en) |
GB (1) | GB575652A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0059561A1 (en) * | 1981-02-19 | 1982-09-08 | Toray Industries, Inc. | Highly refractive urethane polymers for use in optical lenses and lenses prepared therefrom |
WO1994014902A1 (en) * | 1992-12-23 | 1994-07-07 | Coates Brothers Plc | Hot melt ink jet printing |
EP1233045A2 (en) * | 2001-02-07 | 2002-08-21 | Bayer Aktiengesellschaft | Bonding agent for improving the adhesion between rubbers and reinforcing elements |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BE548885A (en) * | 1956-06-22 | |||
DE1132331B (en) * | 1957-12-11 | 1962-06-28 | Basf Ag | Process for the production of pliable, elastic, hardenable synthetic resins |
-
0
- BE BE462146D patent/BE462146A/xx unknown
-
1944
- 1944-03-22 GB GB5358/44A patent/GB575652A/en not_active Expired
-
1945
- 1945-10-12 FR FR915809D patent/FR915809A/en not_active Expired
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0059561A1 (en) * | 1981-02-19 | 1982-09-08 | Toray Industries, Inc. | Highly refractive urethane polymers for use in optical lenses and lenses prepared therefrom |
WO1994014902A1 (en) * | 1992-12-23 | 1994-07-07 | Coates Brothers Plc | Hot melt ink jet printing |
EP1233045A2 (en) * | 2001-02-07 | 2002-08-21 | Bayer Aktiengesellschaft | Bonding agent for improving the adhesion between rubbers and reinforcing elements |
EP1233045A3 (en) * | 2001-02-07 | 2003-05-14 | Bayer Aktiengesellschaft | Bonding agent for improving the adhesion between rubbers and reinforcing elements |
Also Published As
Publication number | Publication date |
---|---|
FR915809A (en) | 1946-11-19 |
BE462146A (en) |
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