GB571919A - Processes for waterproofing cellulose fibres and the resulting products - Google Patents
Processes for waterproofing cellulose fibres and the resulting productsInfo
- Publication number
- GB571919A GB571919A GB10048/43A GB1004843A GB571919A GB 571919 A GB571919 A GB 571919A GB 10048/43 A GB10048/43 A GB 10048/43A GB 1004843 A GB1004843 A GB 1004843A GB 571919 A GB571919 A GB 571919A
- Authority
- GB
- United Kingdom
- Prior art keywords
- acid
- solution
- chloromethyl
- formaldehyde
- acetate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/39—Aldehyde resins; Ketone resins; Polyacetals
- D06M15/423—Amino-aldehyde resins
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/39—Aldehyde resins; Ketone resins; Polyacetals
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
Cellulose fibres or textile materials formed thereof are waterproofed by treatment in an acid solution of a water-soluble condensation product of a compound of the urea or guanidine group which contains either the group =N-CO-N= or =N-C(NH)-N= and formaldehyde, the acid solution also containing a salt of a metal of the 2nd, 3rd or 4th group of the periodic system, rendering the resin insoluble on the fibre by heating to a high temperature, and after-treating with a water-soluble salt of a carboxylic acid containing a high molecular aliphatic or alicyclic residue with more than 11 carbon atoms. The salt of the carboxylic acid may be included in the impregnating bath. A carboxylic acid or a derivative thereof may be added. Compounds of the urea or guanidine group specified are dicyandiamide, cyanurea, dicyandiamidine, biguanides, biurets, and melamine. High-molecular carboxylic acids specified are lauric, stearic, cocoanut fatty acids, tallow-grease, 4-stearoylamino-l-hydroxybenzene-2-carboxylic acid, 4-stearoylamino-l-mercaptobenzene-2-carboxylic acid, 1-hydroxy-2-carboxylic acid stearophenone, 5-octadecylhydroxy-methyl-2-hydroxybenzoic acid, 5 - octadecylhydroxy - methyl-o-cresotinic acid, 3 : 5-di-(octadecylhydroxymethyl) - 2 - hydroxybenzoic acid, the reaction products of ethyloctadecyl aniline and chloromethylene salicylic acid, of p-hydroxy-methyl-o-cresotinic acid and ethyloctadecyl aniline, of o-chloromethyl-p-cresotinic acid and ethyloctadecylaniline, of o:p-di-(chloromethyl)-salicylic acid and ethyloctadecyl aniline, of p-chloromethyl-o-cresotinic acid and octadecyl-anthranilic acid, of o:p-di-(chloromethyl)-salicylic acid and octadecylanthranilic acid, of chloromethylsalicylic acid and as - diethyl - stearoyl-p-phenylenediamine, of chloromethyl-salicylic acid and p-dimethylamino-benzyl-N-stearoylamine, of chloromethyl-salicylic acid and p - ethylbenzylamino - benzyl - N - stearoylamine, and of chloromethyl-salicylic acid and 2 - heptadecyl - benzimidazole. Aluminium, barium, zirconium, copper, lead, tin, zinc, and mercury salts may be used. Carboxylic acids specified are benzoic, o- and p-chlorobenzoic, toluylic, o - benzoylbenzoic, o - (p1 - chloro - or methyl - benzoyl) - benzoic, sulphobenzoic, sulphosalicylic, sulphophthalic, resorcylic, cresotinic, maleic, and phthalic acids. In example 1, dicyandiamine or cyanurea is heated with formaldehyde, acetic acid, and water for 4-5 hours on a water bath, and regenerated cellulose fibre is treated with an aqueous solution of this condensation product and aluminium acetate, thoroughly squeezed, dried, and after-treated with a soap solution. In example 2, dicyandiamidine sulphate is refluxed with formaldehyde and sodium acetate, aluminium acetate solution is added, and regenerated cellulose fibre is foularded twice cold in the solution, dried, rinsed, treated with a soap solution, centrifuged and dried. Aluminium acetate may be replaced by calcium chloride, strontium nitrate, barium chloride, magnesium chloride, or zinc chloride, and the soap solution by a solution of the sodium salt of 4-stearoylamino-l-of one of the high-molecular carboxylic acids previously specified. In example 3, biguanide sulphate is refluxed with formaldehyde and sodium acetate, aluminium acetate (or zirconium oxychloride, copper acetate, or tin chloride) solution is added, and regenerated cellulose fibre is foularded twice cold in the solution, hot dried, soaked, soaped and finished. Alternatively, the soap solution or a solution of the sodium salt of the high-molecular carboxylic acid may be added to the impregnation bath. In example 4, dicyandiamide is refluxed with formaldehyde, formic acid, and benzoic acid, aluminium acetate solution is added, and cotton fabric is soaked in the solution, rinsed, centrifuged, soaped, rinsed, centrifuged, and dried. Specifications 511,102, 517,337 and 526,550 are referred to.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CH571919X | 1942-06-23 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB571919A true GB571919A (en) | 1945-09-14 |
Family
ID=4520965
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB10048/43A Expired GB571919A (en) | 1942-06-23 | 1943-06-22 | Processes for waterproofing cellulose fibres and the resulting products |
Country Status (3)
Country | Link |
---|---|
CH (4) | CH231697A (en) |
FR (2) | FR895776A (en) |
GB (1) | GB571919A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE967187C (en) * | 1942-07-31 | 1957-10-17 | American Cyanamid Co | Process for making paper with improved wet strength |
DE3500408A1 (en) * | 1985-01-08 | 1986-07-10 | Skw Trostberg Ag, 8223 Trostberg | METHOD FOR THE PRODUCTION OF PAPER, CARDBOARD, PAPERBOARDS AND OTHER MATERIALS CONTAINING CELLULOSE UNDER NEUTRAL TO LOW BASIC PH CONDITIONS |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1034858B (en) * | 1952-03-18 | 1958-07-24 | Jacques Wolf & Co | Process for the production of a resin from dicyandiamide and formaldehyde which is stable in aqueous solution and does not gel |
DE1040236B (en) * | 1952-11-14 | 1958-10-02 | Lucien Sellet | Process for the production of water-soluble, modified aminoplast resins |
-
1942
- 1942-06-23 CH CH231697D patent/CH231697A/en unknown
- 1942-06-23 CH CH233160D patent/CH233160A/en unknown
-
1943
- 1943-01-12 CH CH236680D patent/CH236680A/en unknown
- 1943-01-12 CH CH237722D patent/CH237722A/en unknown
- 1943-06-22 GB GB10048/43A patent/GB571919A/en not_active Expired
- 1943-06-22 FR FR895776D patent/FR895776A/en not_active Expired
- 1943-06-22 FR FR895775D patent/FR895775A/en not_active Expired
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE967187C (en) * | 1942-07-31 | 1957-10-17 | American Cyanamid Co | Process for making paper with improved wet strength |
DE3500408A1 (en) * | 1985-01-08 | 1986-07-10 | Skw Trostberg Ag, 8223 Trostberg | METHOD FOR THE PRODUCTION OF PAPER, CARDBOARD, PAPERBOARDS AND OTHER MATERIALS CONTAINING CELLULOSE UNDER NEUTRAL TO LOW BASIC PH CONDITIONS |
Also Published As
Publication number | Publication date |
---|---|
CH231697A (en) | 1944-04-15 |
CH237722A (en) | 1945-05-15 |
CH233160A (en) | 1944-07-15 |
CH236680A (en) | 1945-02-28 |
FR895775A (en) | 1945-02-02 |
FR895776A (en) | 1945-02-02 |
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