GB541071A - Manufacture and application of new condensation products - Google Patents
Manufacture and application of new condensation productsInfo
- Publication number
- GB541071A GB541071A GB4799/40A GB479940A GB541071A GB 541071 A GB541071 A GB 541071A GB 4799/40 A GB4799/40 A GB 4799/40A GB 479940 A GB479940 A GB 479940A GB 541071 A GB541071 A GB 541071A
- Authority
- GB
- United Kingdom
- Prior art keywords
- products
- aliphatic
- aromatic
- thiourea
- converted
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/402—Amides imides, sulfamic acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C335/00—Thioureas, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups
- C07C335/30—Isothioureas
- C07C335/32—Isothioureas having sulfur atoms of isothiourea groups bound to acyclic carbon atoms
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/402—Amides imides, sulfamic acids
- D06M13/432—Urea, thiourea or derivatives thereof, e.g. biurets; Urea-inclusion compounds; Dicyanamides; Carbodiimides; Guanidines, e.g. dicyandiamides
Abstract
541,071. Carboxylic acid amide derivatives; waterproofing fabrics ; wetting &c. agents. SOC. OF CHEMICAL INDUSTRY IN BASLE. March 14, 1940, Nos. 4799 and 4800. Convention dates, March 15, 1939 and Feb. 9, 1940. Addition to 537,221. Sample furnished. [Classes 2 (iii) and 15 (ii)] [Also in Group VIII] Carboxylic acid amides and urethanes which may be substituted once at the nitrogen atom are condensed with halogenmethyl ethers of unsubstituted alcohols containing at the most 5 carbon atoms. The products, which contain halogen may be converted into quaternary ammonium compounds to render them soluble by treatment with tertiary amines such as trimethylamine, triethylamine, triethanolamine, pyridine or N-methylpyridine. They may also be treated with thiourea or its derivatives which re-act in the iso form. When the products contain a radicle having at least 12 carbon atoms, they are wetting, foaming and softening agents. They are also disinfectants and preservatives. By de-composing the products, by heating or saponifying, while on a base such as a textile material, the latter is rendered water-repellent. Salts, such as sodium or ammonium acetate and aluminium formate, solvents, ureas, thioureas, ammonium sulphocyanide, soaps, protective colloids, methylolureas and weighting, softening and matting agents may be used in conjunction with the products. Their use in the leather and paper industries is mentioned. The amides used as starting material may be derived from mono or polybasic carboxylic acids of the aliphatic, aromatic or aliphatic-aromatic series, e.g. formic, propionic, valeric, capric, lauric, behenic, undecylenic, linoleic, chloracetic, bromacetic, α-bromlauric, succinic, adipic, maleic, benzoic, salicylic, oxynaphthoic, phenylacetic, phthalic, hexahydrobenzoic, naphthenic and resin acids and aliphatic, cycloaliphatic, aromatic or aliphatic-aromatic amines, e.g. methyl, amyl, dodecyl, diethylaminoethylamine, ethanolamine, triethylenetetramine, methylcyclohexylamine, #-naphthylamine and benzylamine, chloraniline, dimethylaminoaniline and toluidine. Chlor- and brommethylethers of methyl, propyl, butyl and amyl alcohols are mentioned. In examples the amide of hardened train oil acid and also stearic acid anilide are condensed with chlormethyl ethylether, and the products, dissolved in acetone, reacted with thiourea. Dyed cotton poplin is rendered soft and waterrepellent by immersing in a bath containing alcohol, sodium acetate and the product obtained from stearic acid anilide, pressing and heating. A sample has been furnished under Sect. 2 (5) of the Acts of a product obtained by reacting pyridine with the condensation products of octadecylurethane and chlormethylethylether. The Specification, as open to inspection under Sect. 91 comprises also the condensation of any compound containing an amide group, e.g. urea, with α-halogen methyl ethers of alcohols containing no reactive substituents, and the halogen present in the products may be converted into any group which produces or enhances water solubility, e.g. sulphonic, thiosulphuric, phosphonium, sulphonium and polyether groups. Instead of treating with thiourea, amino, cyanamide, dicyandiamide, or dicyandiamidine groups may be introduced and the products converted into salts. This subject-matter does not appear in the Specification as accepted.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CH541071X | 1939-03-15 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB541071A true GB541071A (en) | 1941-11-12 |
Family
ID=4519071
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB4799/40A Expired GB541071A (en) | 1939-03-15 | 1940-03-14 | Manufacture and application of new condensation products |
Country Status (2)
Country | Link |
---|---|
US (1) | US2338178A (en) |
GB (1) | GB541071A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2554846A (en) * | 1945-11-01 | 1951-05-29 | Armour & Co | Preparation of n,n' diacyldiaminoalkanes |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2426790A (en) * | 1942-06-03 | 1947-09-02 | Du Pont | Chloro-methylene derivative of fatty acid amides |
US2487382A (en) * | 1945-04-18 | 1949-11-08 | Ciba Ltd | Urea derivatives and process of making same |
US2510739A (en) * | 1947-08-09 | 1950-06-06 | Abbott Lab | Cyclic-alkyl isothiuronium halides |
US2681931A (en) * | 1951-12-07 | 1954-06-22 | Searle & Co | Basic amides of bicyclo [2. 2.1]-5-heptene-2-carboxylic acid and 2-norcamphanecarboxylic acid and derivatives thereof |
US2810718A (en) * | 1953-07-02 | 1957-10-22 | Abbott Lab | Basic salicylamides |
US2909566A (en) * | 1955-09-15 | 1959-10-20 | Monsanto Chemicals | Polyamides |
US3268324A (en) * | 1965-10-11 | 1966-08-23 | Monsanto Co | Herbicidal composition and method employing oxa aliphatic acetamide |
US4148926A (en) * | 1977-10-04 | 1979-04-10 | Stauffer Chemical Company | Dialkyl amino ethyl amides as anti-ripening agents |
US4148927A (en) * | 1977-10-04 | 1979-04-10 | Stauffer Chemical Company | Dialkyl amino ethyl amides, their salts and their use as anti-ripening agents |
KR910005747B1 (en) * | 1988-09-03 | 1991-08-02 | 재단법인 한국화학연구소 | S-cn-alkoxycarbonyl,n-substitute amino methyl isothiourea derivatives |
-
1940
- 1940-03-01 US US321806A patent/US2338178A/en not_active Expired - Lifetime
- 1940-03-14 GB GB4799/40A patent/GB541071A/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2554846A (en) * | 1945-11-01 | 1951-05-29 | Armour & Co | Preparation of n,n' diacyldiaminoalkanes |
Also Published As
Publication number | Publication date |
---|---|
US2338178A (en) | 1944-01-04 |
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