GB478854A - Improvements in or relating to the manufacture of cellulosic pellicles - Google Patents
Improvements in or relating to the manufacture of cellulosic pelliclesInfo
- Publication number
- GB478854A GB478854A GB89/37A GB8937A GB478854A GB 478854 A GB478854 A GB 478854A GB 89/37 A GB89/37 A GB 89/37A GB 8937 A GB8937 A GB 8937A GB 478854 A GB478854 A GB 478854A
- Authority
- GB
- United Kingdom
- Prior art keywords
- per cent
- cellulose
- ether
- deformation
- aqueous solution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/402—Amides imides, sulfamic acids
- D06M13/425—Carbamic or thiocarbamic acids or derivatives thereof, e.g. urethanes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Preparing Plates And Mask In Photomechanical Process (AREA)
Abstract
Cellulosic films are softened by means of a high-boiling softening agent belonging to one of the four classes mentioned below, and which is appreciably water-soluble and has a hygroscopicity of from 1 to 80. The four classes of substances are compounds containing (a) both ether and ester groups, (b) keto and ester groups with or without ether groups, (c) hydroxyl and ester groups with or without ether groups, but which do not contain more than one hydroxyl group for each ester group, and (d) compounds of carbamic acid esterified with an alcohol containing an ether group. A number of compounds of each class are specified. By a hygroscopicity of 80, is meant that the substance will absorb 80 per cent of its weight of water when exposed in a thin layer to an atmosphere of 95 per cent relative humidity at a temperature of 25 DEG C. over a period of 120 hours. The cellulosic films so treated should have a degree of deformation not in excess of 3,0 when measured in the machine or longitudinal direction of the film. By degree of deformation is meant the percentage change in length of a strip of film, in equilibrium in an atmosphere of 95 per cent relative humidity at 35 DEG C., when it is allowed to reach equilibrium in a dry atmosphere at the same temperature. The softener employed should have a boiling point not less than 135 DEG C. at a pressure of 12 mm. of mercury. The softener may be applied to the film from aqueous solution or from an aqueous solution containing small amounts of water-miscible organic solvents, e.g. methanol, ethanol or acetone. The process is applicable to the treatment of foils from viscose, cuprammonium cellulose solutions, or aqueous alkaline solutions of cellulose glycollic acid, glycol cellulose, lowly etherified or lowly esterified celluloses. In an example, a gel sheet of regenerated cellulose is impregnated with a 4 per cent aqueous solution of bis-ethoxyethyl malate and dried. It has a deformation of 2,3 compared with 4,0 to 4,4 for glycerol. Specification 439,084 is referred to.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US57634A US2170827A (en) | 1936-01-04 | 1936-01-04 | Cellulosic pellicles and methods for producing same |
Publications (1)
Publication Number | Publication Date |
---|---|
GB478854A true GB478854A (en) | 1938-01-26 |
Family
ID=22011831
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB89/37A Expired GB478854A (en) | 1936-01-04 | 1937-01-01 | Improvements in or relating to the manufacture of cellulosic pellicles |
Country Status (2)
Country | Link |
---|---|
US (1) | US2170827A (en) |
GB (1) | GB478854A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8586522B2 (en) | 2011-09-02 | 2013-11-19 | Dow Global Technologies Llc | Glycol dilevulinates as coupling agents in cleaning formulations |
WO2014035445A1 (en) | 2012-08-31 | 2014-03-06 | Dow Global Technologies Llc | Glycol dilevulinates as coupling agents in cleaning formulations |
-
1936
- 1936-01-04 US US57634A patent/US2170827A/en not_active Expired - Lifetime
-
1937
- 1937-01-01 GB GB89/37A patent/GB478854A/en not_active Expired
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8586522B2 (en) | 2011-09-02 | 2013-11-19 | Dow Global Technologies Llc | Glycol dilevulinates as coupling agents in cleaning formulations |
WO2014035445A1 (en) | 2012-08-31 | 2014-03-06 | Dow Global Technologies Llc | Glycol dilevulinates as coupling agents in cleaning formulations |
Also Published As
Publication number | Publication date |
---|---|
US2170827A (en) | 1939-08-29 |
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