GB497335A - Improvements in or relating to the preparation of coated materials - Google Patents
Improvements in or relating to the preparation of coated materialsInfo
- Publication number
- GB497335A GB497335A GB1665337A GB1665337A GB497335A GB 497335 A GB497335 A GB 497335A GB 1665337 A GB1665337 A GB 1665337A GB 1665337 A GB1665337 A GB 1665337A GB 497335 A GB497335 A GB 497335A
- Authority
- GB
- United Kingdom
- Prior art keywords
- cellulose
- phenol
- formaldehyde
- prepared
- coating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/042—Coating with two or more layers, where at least one layer of a composition contains a polymer binder
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/043—Improving the adhesiveness of the coatings per se, e.g. forming primers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/048—Forming gas barrier coatings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2301/00—Characterised by the use of cellulose, modified cellulose or cellulose derivatives
- C08J2301/06—Cellulose hydrate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2477/00—Characterised by the use of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Derivatives of such polymers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31801—Of wax or waxy material
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31844—Of natural gum, rosin, natural oil or lac
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31942—Of aldehyde or ketone condensation product
- Y10T428/31949—Next to cellulosic
- Y10T428/31953—Modified or regenerated cellulose
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Paper (AREA)
- Laminated Bodies (AREA)
- Paints Or Removers (AREA)
Abstract
Resins prepared by condensing a non-aromatic amine, a phenol and an aldehyde, in any order, are used as an anchoring layer between a water-sensitive cellulosic base material and a coating material. The resins must be substantially insoluble in water and 5 per cent aqueous ammonia but must be soluble in 2 per cent acetic acid. The resins may be used in the form of aqueous solutions of their salts with acids such as acetic, formic citric, glycollic, malic, maleic, succinic, adipic, phthalic, tartaric, benzoic or hydrochloric acids. Glycerine may be added as a plasticizer. On drying the coating it becomes hard and insoluble. The cellulosic base materials include sheets of regenerated cellulose (which may be derived from viscose or cuprammonium cellulose), cellulose ethers (ethylcellulose, methylcellulose, glycolcellulose or cellulose glycollic acid) or cellulose esters (cellulose phthalate) tubes, sausage casings, bottle caps, bands or moulded articles or various cellulosic materials, rayon fabrics, paper or cotton cloth. The coating material to be anchored may be discontinuous such as printing on regenerated cellulose sheets, tubes, caps and sausage casings. The surface coating may be any coating composition containing a cellulose derivative base such as cellulose nitrate, cellulose acetate, ethyl cellulose, or benzyl cellulose or, preferably, a moisture proofing coating comprising a cellulose derivative, a wax or wax-like material, a blending agent and a plasticizer. In an example, regenerated cellulose sheet in the gel state prepared from viscose is coated with a composition prepared by dissolving a resin prepared from phenol or m-cresol, formaldehyde, dimethylamine and ammonia in a mixture of aqueous acetic acid and glycerine with or without the addition of de-acetylated chitin, the sheet is then dried and coated with a moisture-proofing composition comprising pyroxylin, gum dammar, dibutyl phthalate, paraffin wax, zinc stearate, ethyl stearate, toluene, alcohol and acetone. Specifications 282,435, [Class 2 (iii)], 283,109, [Class 95], 317,452, [Class 2 (ii)], and 458,814, are referred to.ALSO:Resins prepared by condensing a non-aromatic amine, a phenol and an aldehyde, in any order, are used as an anchoring layer between a water - sensitive cellulosic base material and a coating material. The resins must be substantially insoluble in water and 5 per cent aqueous ammonia but must be soluble in 2 per cent acetic acid. The resins may be used in the form of aqueous solutions of their salts with acids such as acetic, formic, citric, glycollic, malic, maleic, succinic, adipic, phthalic, tartaric, benzoic or hydrochloric acids. Glycerine may be added as a plasticizer. On drying the coating it becomes hard and insoluble. Preferably the phenolic body has at least two free reactive positions and only organic groups as ring constituents and the amine contains not more than six carbon atoms and at least one amino-nitrogen atom joined to a carbon atom which is not part of an aromatic ring and also to at least one hydrogen atom. The cellulosic base materials include sheets of regenerated cellulose (which may be derived from viscose or cuprammonium cellulose), cellulose ethers (ethylcellulose, methylcellulose, glycolcellulose or cellulose glycollic acid) or cellulose esters (cellulose phthalate) tubes, sausage casings, bottle caps, bands or moulded articles of various cellulosic materials, rayon fabrics, paper or cotton cloth. The coating material to be anchored may be discontinuous such as printing on regenerated cellulose sheets, tubes, caps and sausage casings. The surface coating may be any coating-composition containing a cellulose derivative base such as cellulose nitrate, cellulose acetate, ethyl cellulose, or benzyl cellulose or, preferably, a moistureproofing coating comprising a cellulose derivative, a wax or wax-like material, a blending agent and a plasticizer. In examples suitable resins are prepared from (a) phenol formaldehyde, dimethylamine and ammonia, (b) phenol, lignin, formaldehyde and dimethylamine, (c) phenol, formaldehyde and dimethylamine, (d) phenol, formaldehyde and dimethylaminoethanol, and (e) phenol, formaldehyde and cyclohexylamine. Other resins include those prepared from phenol, formaldehyde, and (2) lignin and methylamine, (3) cyclohexanolamine, (4) p-toluene sulphonamide and methylamine, (6) dimethylamine, and (9) ammonia and diethanolamine, from (1) xylenol, formaldehyde and methylamine, from (7) m-cresol, formaldehyde and dimethylamine, and from (8) xylenol, or (5) diphenylolcyclohexanone, formaldehyde and dimethylaminomethanol. In examples: (1) regenerated cellulose sheet in the gel state prepared from viscose is coated with a composition prepared by dissolving the resin from example (a) or a corresponding resin prepared from m-cresol instead of phenol in a mixture of aqueous acetic acid and glycerine, with or without the addition of de-acetylated chitin, the sheet is then dried and coated with a moistureproofing composition comprising pyroxylin, gum dammar, dibutyl phthalate, paraffin wax, zinc stearate, ethyl stearate, toluene, alcohol and acetone. Specifications 282,435, [Class 2 (iii)], 283,109, [Class 95], 317,452, [Class 2 (ii)], and 458,814 are referred to. A phenol-lignin condensate is prepared by heating phenol and spruce wood flour in the presence of hydrochloric acid.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US8576936 US2122433A (en) | 1936-06-17 | 1936-06-17 | Coated films and method of making the same |
Publications (1)
Publication Number | Publication Date |
---|---|
GB497335A true GB497335A (en) | 1938-12-15 |
Family
ID=22193815
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB1665337A Expired GB497335A (en) | 1936-06-17 | 1937-06-15 | Improvements in or relating to the preparation of coated materials |
Country Status (2)
Country | Link |
---|---|
US (1) | US2122433A (en) |
GB (1) | GB497335A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2650172A (en) * | 1949-01-21 | 1953-08-25 | American Viscose Corp | Moistureproofing of nonfibrous cellulosic material |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2432542A (en) * | 1944-07-13 | 1947-12-16 | Du Pont | Method of producing coated cellulosic sheets |
US2462185A (en) * | 1946-02-19 | 1949-02-22 | Du Pont | Moistureproof, heat-sealable wrapping material and process |
US2556885A (en) * | 1946-06-27 | 1951-06-12 | Du Pont | Coated products |
US3012912A (en) * | 1958-07-16 | 1961-12-12 | American Cyanamid Co | Non-fibrous regenerated cellulose film containing bis-amide polymer as anchor agent |
-
1936
- 1936-06-17 US US8576936 patent/US2122433A/en not_active Expired - Lifetime
-
1937
- 1937-06-15 GB GB1665337A patent/GB497335A/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2650172A (en) * | 1949-01-21 | 1953-08-25 | American Viscose Corp | Moistureproofing of nonfibrous cellulosic material |
Also Published As
Publication number | Publication date |
---|---|
US2122433A (en) | 1938-07-05 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US2760431A (en) | Lithographic plates and methods for manufacturing same | |
US6531593B1 (en) | Method for production of cellulose derivatives and the resulting products | |
GB497335A (en) | Improvements in or relating to the preparation of coated materials | |
US2235141A (en) | Treatment of artificial materials | |
GB458813A (en) | Process for the manufacture of compositions and coated or impregnated materials | |
GB455849A (en) | Improvements in the manufacture of artificial silk, films and like products | |
GB484984A (en) | Process for modifying the affinity of fibrous and film-like materials for dyestuffs | |
US2316146A (en) | Casein plastics | |
US2424284A (en) | Fixation of finely divided substances | |
US2246070A (en) | Manufacture of basic substituted shaped materials | |
US1885475A (en) | Artificial products from cellulose derivatives and process of preparing the same | |
US2248048A (en) | Thickener for decorating textiles of organic derivatives of cellulose | |
US1826699A (en) | Method of preparing moisturproof materials | |
GB457031A (en) | Manufacture of shaped structures from cellulose derivatives | |
US2267277A (en) | Process for rendering polysaccharidic materials water resistant | |
US2058786A (en) | Light protective wrapper | |
US2270200A (en) | Insolubilization of water-soluble cellulose ethers | |
GB506999A (en) | Improvements in or relating to the manufacture and use of new chemical substances | |
US2805952A (en) | Leather pasting | |
GB484069A (en) | Improvements in or relating to the manufacture of sheet cellulosic material | |
GB874620A (en) | Process for dyeing organic products with pigment dyestuffs | |
GB748046A (en) | Production of an improved artificial leather having a polyvinyl chloride basis | |
US2144383A (en) | Method of moistureproofing | |
US1677753A (en) | Cellulose composition | |
GB478854A (en) | Improvements in or relating to the manufacture of cellulosic pellicles |