GB474448A - Improvements in carrying out the reaction of carbon monoxide with hydrogen - Google Patents

Improvements in carrying out the reaction of carbon monoxide with hydrogen

Info

Publication number
GB474448A
GB474448A GB9015/36A GB901536A GB474448A GB 474448 A GB474448 A GB 474448A GB 9015/36 A GB9015/36 A GB 9015/36A GB 901536 A GB901536 A GB 901536A GB 474448 A GB474448 A GB 474448A
Authority
GB
United Kingdom
Prior art keywords
compound
reducible
metal
hydrogen
precipitated
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB9015/36A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IG Farbenindustrie AG
Original Assignee
IG Farbenindustrie AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to DEI54417D priority Critical patent/DE729290C/en
Application filed by IG Farbenindustrie AG filed Critical IG Farbenindustrie AG
Priority to GB9015/36A priority patent/GB474448A/en
Priority to US126664A priority patent/US2211022A/en
Publication of GB474448A publication Critical patent/GB474448A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C07C1/0425—Catalysts; their physical properties
    • C07C1/0445—Preparation; Activation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/153—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used
    • C07C29/156—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used containing iron group metals, platinum group metals or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04—Alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C07C2523/745—Iron
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Catalysts (AREA)

Abstract

In the thermal conversion of carbon monoxide and hydrogen into hydrocarbons having more than one carbon atom and/or their oxygen-containing derivatives, the catalyst is prepared by adding to a previously precipitated reducible compound of a metal of the iron group a compound of another metal, which on heating yields an oxide not reducible by hydrogen below 900 DEG C., and subsequently heating the mixture in a reducing gas to a temperature above 500 DEG C. so that a partial sintering of the catalyst takes place. The non-reducible ingredient may be a compound of an earth metal, e.g. aluminium, beryllium, manganese, zinc, thorium, cerium, or zirconium. It may be added in the form of a precipitate or of an aqueous dispersion or solution, which last may be precipitated after admixture with the iron metal compound. A third component consisting of a compound forming a reducible metal oxide, e.g. copper nitrate, may also be incorporated in the mixture. According to an example, moist precipitated ferric hydroxide is mixed with a suspension of aluminium hydroxide, dried, and reduced in hydrogen at 850 DEG C. The product contains 5 per cent of alumina with respect to the amount of metallic iron.ALSO:A catalyst for reactions between carbon monoxide and hydrogen is prepared by adding to a previously precipitated reducible compound of a metal of the iron group a compound of another metal, which on heating yields an oxide not reducible by hydrogen below 900 DEG C., and subsequently heating the mixture in a reducing gas to a temperature above 500 DEG C. so that a partial sintering of the catalyst takes place. The non-reducible ingredient may be a compound of an earth metal, e.g. aluminium, beryllium, manganese, zinc, thorium, cerium, or zirconium. It may be added in the form of a precipitate or of an aqueous dispersion or solution, which last may be precipitated after admixture with the iron metal compound. A third component such as copper nitrate, yielding a reducible metal oxide may also be incorporated in the mixture. According to an example, moist precipitated ferric hydroxide is mixed with a suspension of aluminium hydroxide, dried, and reduced in hydrogen at 850 DEG C. The product contains 5 per cent of alumina with respect to the amount of metallic iron.
GB9015/36A 1936-02-26 1936-03-26 Improvements in carrying out the reaction of carbon monoxide with hydrogen Expired GB474448A (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
DEI54417D DE729290C (en) 1936-02-26 1936-02-26 Process for converting carbon monoxide and hydrogen
GB9015/36A GB474448A (en) 1936-03-26 1936-03-26 Improvements in carrying out the reaction of carbon monoxide with hydrogen
US126664A US2211022A (en) 1936-02-26 1937-02-19 Hydrogenation of carbon monoxide

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB9015/36A GB474448A (en) 1936-03-26 1936-03-26 Improvements in carrying out the reaction of carbon monoxide with hydrogen

Publications (1)

Publication Number Publication Date
GB474448A true GB474448A (en) 1937-10-26

Family

ID=9863705

Family Applications (1)

Application Number Title Priority Date Filing Date
GB9015/36A Expired GB474448A (en) 1936-02-26 1936-03-26 Improvements in carrying out the reaction of carbon monoxide with hydrogen

Country Status (1)

Country Link
GB (1) GB474448A (en)

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