GB470703A - Process for the manufacture of phthalocyanines - Google Patents
Process for the manufacture of phthalocyaninesInfo
- Publication number
- GB470703A GB470703A GB458136A GB458136A GB470703A GB 470703 A GB470703 A GB 470703A GB 458136 A GB458136 A GB 458136A GB 458136 A GB458136 A GB 458136A GB 470703 A GB470703 A GB 470703A
- Authority
- GB
- United Kingdom
- Prior art keywords
- prepared
- potassium ferrocyanide
- phthalonitriles
- subliming
- phenoxy
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B47/00—Porphines; Azaporphines
- C09B47/04—Phthalocyanines abbreviation: Pc
- C09B47/06—Preparation from carboxylic acids or derivatives thereof, e.g. anhydrides, amides, mononitriles, phthalimide, o-cyanobenzamide
- C09B47/067—Preparation from carboxylic acids or derivatives thereof, e.g. anhydrides, amides, mononitriles, phthalimide, o-cyanobenzamide from phthalodinitriles naphthalenedinitriles, aromatic dinitriles prepared in situ, hydrogenated phthalodinitrile
- C09B47/0675—Preparation from carboxylic acids or derivatives thereof, e.g. anhydrides, amides, mononitriles, phthalimide, o-cyanobenzamide from phthalodinitriles naphthalenedinitriles, aromatic dinitriles prepared in situ, hydrogenated phthalodinitrile having oxygen or sulfur linked directly to the skeleton
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
Abstract
Phthalocyanines are prepared by heating phthalonitriles substituted by alkoxy or aryloxy groups or in which the benzene nucleus is connected in two positions to a further aryl residue in each case by an oxygen atom, with metals or metal compounds with or without diluents. Examples of starting materials are 4-ethoxy-phthalonitrile, prepared by subliming sodium 5-ethoxy-2-cyanobenzene - 1 - sulphonate with potassium ferrocyanide; 4-methoxyphthalonitrile; the 1-phenoxy-3 : 4-phthalonitrile obtained by heating with potassium ferrocyanide the sodium salt of 3-phenoxy-2-cyano-benzene-sulphonic acid; 2 : 3-dicyanodiphenylene dioxide, prepared by subliming the sodium salt of 2-cyano-diphenylene dioxide-3-sulphonic acid with potassium ferrocyanide. Starting materials which are converted into phthalonitriles of the types specified during the course of the reaction may also be used. The phthalocyanine products can be pasted from cold sulphuric or ethyl sulphuric acids, and can be sulphonated and then converted into lakes by treatment with polyvalent metal salts or lake-forming amines. They may be used for graphic wall-paper printing-and for colouring cuprammonium or viscose artificial silk. Specification 410,814 is referred to.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB458136A GB470703A (en) | 1936-02-14 | 1936-02-14 | Process for the manufacture of phthalocyanines |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB458136A GB470703A (en) | 1936-02-14 | 1936-02-14 | Process for the manufacture of phthalocyanines |
Publications (1)
Publication Number | Publication Date |
---|---|
GB470703A true GB470703A (en) | 1937-08-16 |
Family
ID=9779854
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB458136A Expired GB470703A (en) | 1936-02-14 | 1936-02-14 | Process for the manufacture of phthalocyanines |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB470703A (en) |
-
1936
- 1936-02-14 GB GB458136A patent/GB470703A/en not_active Expired
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