GB469749A - Improvements in the production and treatment of artificial filaments, yarns and similar materials containing organic derivatives of cellulose - Google Patents
Improvements in the production and treatment of artificial filaments, yarns and similar materials containing organic derivatives of celluloseInfo
- Publication number
- GB469749A GB469749A GB2051936A GB2051936A GB469749A GB 469749 A GB469749 A GB 469749A GB 2051936 A GB2051936 A GB 2051936A GB 2051936 A GB2051936 A GB 2051936A GB 469749 A GB469749 A GB 469749A
- Authority
- GB
- United Kingdom
- Prior art keywords
- plasticizer
- cellulose
- filaments
- phthalate
- stretching
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F2/00—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof
- D01F2/24—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof from cellulose derivatives
- D01F2/28—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof from cellulose derivatives from organic cellulose esters or ethers, e.g. cellulose acetate
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Artificial Filaments (AREA)
- Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
Artificial filaments, foils, films, and similar materials made of organic derivatives of cellulose and containing plasticizers are subjected to stretching in wet steam or hot water at a temperature above 100 DEG C. Preferably, the plasticizers used are compatible with the cellulose derivatives in a proportion of at least 50 per cent. The filaments or foils may be of cellulose acetate, formate, propionate, butyrate, or nitro-acetate, or methyl, ethyl, or butyl cellulose, or ethyl or oxyethyl cellulose acetate. The plasticizer may be butyl or amyl phthalate, butyl citrate, glyceryl tri-benzoate, tri-phenyl or cresyl phosphate, but is preferably dibutyl or amyl tartrate, dimethyl or ethyl phthalate, di-(methyl or ethyl glycol) phthalate, triethyl citrate, cresyl glyceryl diacetate, methyl cyclohexanyl oxalate, benzyl benzoate, benzyl alcohol, triacetin, triphenyl acetin, or an aromatic sulphonamide. The plasticizer may be incorporated in a spinning solution or it may be incorporated in the filaments after they have been formed. Hanks or bobbins may be immersed in aqueous or organic solutions or emulsions of the plasticizer. Stretching may be carried out on hanks or while the materials are travelling, e.g. from the spinning cell to the winding device, and there may be one or more stages of stretching. The plasticizer may be removed during or after the stretching operation. Water, or aqueous solutions of alcohols, or organic solvents such as benzene toluene, dichlorethylene, carbon tetrachloride, alcohols, or ethers may be used for removing the plasticizer. In an example, cellulose acetate filaments are formed from a solution containing p-toluene sulphonamide as plasticizer, and passed through a chamber containing wet steam at a temperature above 100 DEG C., and are simultaneously stretched. In other examples, diethyl phthalate and triacetin are used as plasticizer. In another example, cellulose acetate foil containing diethyl phthalate and tri-phenyl phosphate is stretched in wet steam at 105 DEG C. Specifications 438,584, 438,585, 438,586, 438,587, 438,655, 438,656, 443,707, and 443,773 are referred to.
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB710035A GB453155A (en) | 1936-01-24 | 1935-03-07 | Improvements in the production and treatment of artificial textile materials containing organic derivatives of cellulose |
GB2051936A GB469749A (en) | 1936-01-24 | 1936-01-24 | Improvements in the production and treatment of artificial filaments, yarns and similar materials containing organic derivatives of cellulose |
FR801484D FR801484A (en) | 1935-03-07 | 1936-02-01 | Improvements in the manufacture and treatment of artificial textile materials containing organic cellulose derivatives |
US120221A US2155411A (en) | 1935-03-07 | 1937-01-12 | Manufacture of cellulose derivative materials |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB2051936A GB469749A (en) | 1936-01-24 | 1936-01-24 | Improvements in the production and treatment of artificial filaments, yarns and similar materials containing organic derivatives of cellulose |
Publications (1)
Publication Number | Publication Date |
---|---|
GB469749A true GB469749A (en) | 1937-07-26 |
Family
ID=10147214
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB710035A Expired GB453155A (en) | 1935-03-07 | 1935-03-07 | Improvements in the production and treatment of artificial textile materials containing organic derivatives of cellulose |
GB2051936A Expired GB469749A (en) | 1935-03-07 | 1936-01-24 | Improvements in the production and treatment of artificial filaments, yarns and similar materials containing organic derivatives of cellulose |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB710035A Expired GB453155A (en) | 1935-03-07 | 1935-03-07 | Improvements in the production and treatment of artificial textile materials containing organic derivatives of cellulose |
Country Status (1)
Country | Link |
---|---|
GB (2) | GB453155A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2478331A (en) * | 1945-10-05 | 1949-08-09 | Celanese Corp | Production of high tenacity cellulose derivative yarns |
-
1935
- 1935-03-07 GB GB710035A patent/GB453155A/en not_active Expired
-
1936
- 1936-01-24 GB GB2051936A patent/GB469749A/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2478331A (en) * | 1945-10-05 | 1949-08-09 | Celanese Corp | Production of high tenacity cellulose derivative yarns |
Also Published As
Publication number | Publication date |
---|---|
GB453155A (en) | 1936-09-07 |
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