GB456518A - Improvements in or relating to the production of highly concentrated nitric acid - Google Patents

Improvements in or relating to the production of highly concentrated nitric acid

Info

Publication number
GB456518A
GB456518A GB1064135A GB1064135A GB456518A GB 456518 A GB456518 A GB 456518A GB 1064135 A GB1064135 A GB 1064135A GB 1064135 A GB1064135 A GB 1064135A GB 456518 A GB456518 A GB 456518A
Authority
GB
United Kingdom
Prior art keywords
nitric acid
gases
vessel
air
oxidation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1064135A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Imperial Chemical Industries Ltd
Original Assignee
Imperial Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Imperial Chemical Industries Ltd filed Critical Imperial Chemical Industries Ltd
Priority to GB1064135A priority Critical patent/GB456518A/en
Publication of GB456518A publication Critical patent/GB456518A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B21/00Nitrogen; Compounds thereof
    • C01B21/20Nitrogen oxides; Oxyacids of nitrogen; Salts thereof
    • C01B21/24Nitric oxide (NO)
    • C01B21/26Preparation by catalytic or non-catalytic oxidation of ammonia

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Treating Waste Gases (AREA)

Abstract

<PICT:0456518/III/1> Nitric acid of a concentration exceeding 90 per cent is obtained from the gases produced in the catalytic oxidation of ammonia at ordinary or increased pressure with air or oxygen-enriched air by stripping the gases of most of their water, oxidizing them so that they contain gaseous nitrogen peroxide, treating them at elevated pressure with an absorbent consisting of nitric acid of a concentration exceeding 90 per cent and oxidizing the resulting solution at a still higher pressure and at elevated temperature, the proportion of concentrated nitric acid used as an absorbent being sufficiently great and the proportion of water present as vapour in the oxidized gases or as liquid in the concentrated nitric acid being sufficiently small to ensure that no separation of nitrogen peroxide as a separate liquid phase occurs either during the absorption or subsequently. Water or dilute nitric acid may be added to the solution before oxidation provided the quantity employed is insufficient to cause phase separation. The absorption stage may operate at pressures of 3--5 atmospheres and a temperature of 0--10 DEG C. The solution of nitrogen peroxide in concentrated nitric acid may be oxidized with air at 50--200 atmospheres pressure and at 60--120 DEG C. An ammonia-air mixture is passed through a converter 1 at atmospheric pressure. The oxidized gases leaving at a temperature of 400 DEG C., pass through pipes (not shown), to a heat-exchanger 27, through a heat-exchanger 33 and to a watercooled condenser 2 in which they are rapidly cooled, a large fraction of their water content being condensed before appreciable oxidation to the peroxide stage can take place. The gases are pumped by a turbo-compressor 3 into a water cooled vessel 6 at a pressure of 3 atmospheres. Here oxidation takes place and residual water is condensed. The substantially dried and completely oxidized gases then pass to the foot of an absorption vessel 7 consisting of a bubbler cap tower irrigated with concentrated nitric acid. The gases leave the top of the tower through a spray catcher 8 and are finally scrubbed free from nitric acid or tetroxide in a scrubber 10 irrigated with a portion of the condensate from the condenser 2. The residual gases pass through the heat - exchanger 33 to power recovery in the recovery section 11 of the turbo-compressor. The tetroxide-enriched acid leaving the bottom of the tower 7 is admixed with dilute nitric acids from the condenser 6 and the scrubber 10 and the resulting solution is sent to one of a group of acid eggs 16 from which it is forced by means of compressed air into the top of the series of oxidation vessels 21, 22, 23. These vessels contain suitable packing, internal baffles and internal coils for heating or cooling. Air at about 95 atmospheres pressure is supplied to the lowermost oxidation vessel preferably in a finely divided state from a compressor 36 and reservoir 37. The bottom vessel may be maintained at a temperature of 100 DEG C., while the top vessel has a temperature of 60 DEG C. The air moves in counter-current to the acid and reaches the top nearly free from oxygen. The residual nitrogen passes through a condenser 31, a scrubber 32 and the heat-exchanger 27, is expanded to about 3 atmospheres with power recovery at 34 and subsequently joins the residual gases from the absorption vessel. The concentrated nitric acid from the bottom oxidation vessel is bleached in a steam heated bleaching column 28 by means of air at 4 atmospheres released from the acid eggs. The tetroxide containing gases from the bleaching column is fed into the main gas stream either in front or immediately after the compressor 3. The hot nitric acid is cooled in a cooler 25 a portion being sent through a valve 26 into the absorption vessel 7. The "make" acid is drawn off at valve 29.
GB1064135A 1935-04-05 1935-04-05 Improvements in or relating to the production of highly concentrated nitric acid Expired GB456518A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB1064135A GB456518A (en) 1935-04-05 1935-04-05 Improvements in or relating to the production of highly concentrated nitric acid

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB1064135A GB456518A (en) 1935-04-05 1935-04-05 Improvements in or relating to the production of highly concentrated nitric acid

Publications (1)

Publication Number Publication Date
GB456518A true GB456518A (en) 1936-11-05

Family

ID=9971585

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1064135A Expired GB456518A (en) 1935-04-05 1935-04-05 Improvements in or relating to the production of highly concentrated nitric acid

Country Status (1)

Country Link
GB (1) GB456518A (en)

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2578674A (en) * 1949-03-28 1951-12-18 Wisconsin Alumni Res Found Nitric oxide recovery system
DE750981C (en) * 1937-09-22 1952-12-01 Bamag Meguin Ag Continuous production of highly concentrated nitric acid from liquid nitrogen tetroxide, water or diluted nitric acid and oxygen under pressure
DE752321C (en) * 1940-05-10 1953-05-11 Ig Farbenindustrie Ag Process for separating water from gases containing nitrogen oxide
US3472620A (en) * 1967-11-13 1969-10-14 Belge Produits Chimiques Sa Process for the manufacture of nitric acid
US4276277A (en) * 1970-06-12 1981-06-30 Produits Chimiques Ugine Kuhlmann Manufacture of concentrated nitric acid
CN109319776A (en) * 2018-11-30 2019-02-12 黄冈师范学院 The method, apparatus and application of nitrogen oxide and iron ion catalysis oxidation recycling diamond
CN110980671A (en) * 2019-12-27 2020-04-10 济南双硝技术开发有限公司 Process method for improving concentration of acid generated by double-pressurization dilute nitric acid
CN111108064A (en) * 2017-08-24 2020-05-05 雅苒国际集团 Process for producing nitric acid

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE750981C (en) * 1937-09-22 1952-12-01 Bamag Meguin Ag Continuous production of highly concentrated nitric acid from liquid nitrogen tetroxide, water or diluted nitric acid and oxygen under pressure
DE752321C (en) * 1940-05-10 1953-05-11 Ig Farbenindustrie Ag Process for separating water from gases containing nitrogen oxide
US2578674A (en) * 1949-03-28 1951-12-18 Wisconsin Alumni Res Found Nitric oxide recovery system
US3472620A (en) * 1967-11-13 1969-10-14 Belge Produits Chimiques Sa Process for the manufacture of nitric acid
US4276277A (en) * 1970-06-12 1981-06-30 Produits Chimiques Ugine Kuhlmann Manufacture of concentrated nitric acid
CN111108064A (en) * 2017-08-24 2020-05-05 雅苒国际集团 Process for producing nitric acid
CN109319776A (en) * 2018-11-30 2019-02-12 黄冈师范学院 The method, apparatus and application of nitrogen oxide and iron ion catalysis oxidation recycling diamond
CN109319776B (en) * 2018-11-30 2023-09-15 黄冈师范学院 Method, device and application for recycling diamond through catalytic oxidation of nitrogen oxide and iron ions
CN110980671A (en) * 2019-12-27 2020-04-10 济南双硝技术开发有限公司 Process method for improving concentration of acid generated by double-pressurization dilute nitric acid

Similar Documents

Publication Publication Date Title
US2135271A (en) Method of recovering olefin oxides from gaseous mixtures and hydrolyzing to form corresponding glycols
US1989267A (en) Production of nitric acid and liquid nitrogen tetroxide
US2217429A (en) Separation of acetylene from gaseous mixtures containing it
GB456518A (en) Improvements in or relating to the production of highly concentrated nitric acid
US2088057A (en) Production of nitric acid from oxides of nitrogen
GB434302A (en) Improvements in or relating to the absorption of nitrogen oxides
US3489515A (en) Production of high percentage nitric oxide
US2169210A (en) Recovery of olefin oxides from
GB405450A (en) A process for the production of highly concentrated nitric acid
SU786879A3 (en) Method of nitric acid production
US2046162A (en) Process for producing concentrated nitric acid
US2128527A (en) Process for the absorption, in highly concentrated nitric acid, of nitrous gases formed by the combustion of ammonia
US4276277A (en) Manufacture of concentrated nitric acid
US2123467A (en) Process for the production of highly concentrated nitric acid
US2281762A (en) Process of producing sulphur trioxide and oxygen
GB803211A (en) Improvements in and relating to the production of nitric acid
US2181559A (en) Process for producing a nitrate
US2215450A (en) Process for the production of a nitrate
US3362786A (en) Sulfur trioxide production
US2092383A (en) Process for the production of alkali metal nitrates by reaction of alkali metal chlorides and nitric acid
US2138017A (en) Process for the decomposition of nitrosyl chloride
GB345662A (en) Improved manufacture of concentrated nitric acid
CS197215B2 (en) Method of producing sulphuric acid
US2184707A (en) Pressure synthesis of sulphuric acid
US2139721A (en) Concentration of nitric acid