GB456518A - Improvements in or relating to the production of highly concentrated nitric acid - Google Patents
Improvements in or relating to the production of highly concentrated nitric acidInfo
- Publication number
- GB456518A GB456518A GB1064135A GB1064135A GB456518A GB 456518 A GB456518 A GB 456518A GB 1064135 A GB1064135 A GB 1064135A GB 1064135 A GB1064135 A GB 1064135A GB 456518 A GB456518 A GB 456518A
- Authority
- GB
- United Kingdom
- Prior art keywords
- nitric acid
- gases
- vessel
- air
- oxidation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B21/00—Nitrogen; Compounds thereof
- C01B21/20—Nitrogen oxides; Oxyacids of nitrogen; Salts thereof
- C01B21/24—Nitric oxide (NO)
- C01B21/26—Preparation by catalytic or non-catalytic oxidation of ammonia
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Treating Waste Gases (AREA)
Abstract
<PICT:0456518/III/1> Nitric acid of a concentration exceeding 90 per cent is obtained from the gases produced in the catalytic oxidation of ammonia at ordinary or increased pressure with air or oxygen-enriched air by stripping the gases of most of their water, oxidizing them so that they contain gaseous nitrogen peroxide, treating them at elevated pressure with an absorbent consisting of nitric acid of a concentration exceeding 90 per cent and oxidizing the resulting solution at a still higher pressure and at elevated temperature, the proportion of concentrated nitric acid used as an absorbent being sufficiently great and the proportion of water present as vapour in the oxidized gases or as liquid in the concentrated nitric acid being sufficiently small to ensure that no separation of nitrogen peroxide as a separate liquid phase occurs either during the absorption or subsequently. Water or dilute nitric acid may be added to the solution before oxidation provided the quantity employed is insufficient to cause phase separation. The absorption stage may operate at pressures of 3--5 atmospheres and a temperature of 0--10 DEG C. The solution of nitrogen peroxide in concentrated nitric acid may be oxidized with air at 50--200 atmospheres pressure and at 60--120 DEG C. An ammonia-air mixture is passed through a converter 1 at atmospheric pressure. The oxidized gases leaving at a temperature of 400 DEG C., pass through pipes (not shown), to a heat-exchanger 27, through a heat-exchanger 33 and to a watercooled condenser 2 in which they are rapidly cooled, a large fraction of their water content being condensed before appreciable oxidation to the peroxide stage can take place. The gases are pumped by a turbo-compressor 3 into a water cooled vessel 6 at a pressure of 3 atmospheres. Here oxidation takes place and residual water is condensed. The substantially dried and completely oxidized gases then pass to the foot of an absorption vessel 7 consisting of a bubbler cap tower irrigated with concentrated nitric acid. The gases leave the top of the tower through a spray catcher 8 and are finally scrubbed free from nitric acid or tetroxide in a scrubber 10 irrigated with a portion of the condensate from the condenser 2. The residual gases pass through the heat - exchanger 33 to power recovery in the recovery section 11 of the turbo-compressor. The tetroxide-enriched acid leaving the bottom of the tower 7 is admixed with dilute nitric acids from the condenser 6 and the scrubber 10 and the resulting solution is sent to one of a group of acid eggs 16 from which it is forced by means of compressed air into the top of the series of oxidation vessels 21, 22, 23. These vessels contain suitable packing, internal baffles and internal coils for heating or cooling. Air at about 95 atmospheres pressure is supplied to the lowermost oxidation vessel preferably in a finely divided state from a compressor 36 and reservoir 37. The bottom vessel may be maintained at a temperature of 100 DEG C., while the top vessel has a temperature of 60 DEG C. The air moves in counter-current to the acid and reaches the top nearly free from oxygen. The residual nitrogen passes through a condenser 31, a scrubber 32 and the heat-exchanger 27, is expanded to about 3 atmospheres with power recovery at 34 and subsequently joins the residual gases from the absorption vessel. The concentrated nitric acid from the bottom oxidation vessel is bleached in a steam heated bleaching column 28 by means of air at 4 atmospheres released from the acid eggs. The tetroxide containing gases from the bleaching column is fed into the main gas stream either in front or immediately after the compressor 3. The hot nitric acid is cooled in a cooler 25 a portion being sent through a valve 26 into the absorption vessel 7. The "make" acid is drawn off at valve 29.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB1064135A GB456518A (en) | 1935-04-05 | 1935-04-05 | Improvements in or relating to the production of highly concentrated nitric acid |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB1064135A GB456518A (en) | 1935-04-05 | 1935-04-05 | Improvements in or relating to the production of highly concentrated nitric acid |
Publications (1)
Publication Number | Publication Date |
---|---|
GB456518A true GB456518A (en) | 1936-11-05 |
Family
ID=9971585
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB1064135A Expired GB456518A (en) | 1935-04-05 | 1935-04-05 | Improvements in or relating to the production of highly concentrated nitric acid |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB456518A (en) |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2578674A (en) * | 1949-03-28 | 1951-12-18 | Wisconsin Alumni Res Found | Nitric oxide recovery system |
DE750981C (en) * | 1937-09-22 | 1952-12-01 | Bamag Meguin Ag | Continuous production of highly concentrated nitric acid from liquid nitrogen tetroxide, water or diluted nitric acid and oxygen under pressure |
DE752321C (en) * | 1940-05-10 | 1953-05-11 | Ig Farbenindustrie Ag | Process for separating water from gases containing nitrogen oxide |
US3472620A (en) * | 1967-11-13 | 1969-10-14 | Belge Produits Chimiques Sa | Process for the manufacture of nitric acid |
US4276277A (en) * | 1970-06-12 | 1981-06-30 | Produits Chimiques Ugine Kuhlmann | Manufacture of concentrated nitric acid |
CN109319776A (en) * | 2018-11-30 | 2019-02-12 | 黄冈师范学院 | The method, apparatus and application of nitrogen oxide and iron ion catalysis oxidation recycling diamond |
CN110980671A (en) * | 2019-12-27 | 2020-04-10 | 济南双硝技术开发有限公司 | Process method for improving concentration of acid generated by double-pressurization dilute nitric acid |
CN111108064A (en) * | 2017-08-24 | 2020-05-05 | 雅苒国际集团 | Process for producing nitric acid |
-
1935
- 1935-04-05 GB GB1064135A patent/GB456518A/en not_active Expired
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE750981C (en) * | 1937-09-22 | 1952-12-01 | Bamag Meguin Ag | Continuous production of highly concentrated nitric acid from liquid nitrogen tetroxide, water or diluted nitric acid and oxygen under pressure |
DE752321C (en) * | 1940-05-10 | 1953-05-11 | Ig Farbenindustrie Ag | Process for separating water from gases containing nitrogen oxide |
US2578674A (en) * | 1949-03-28 | 1951-12-18 | Wisconsin Alumni Res Found | Nitric oxide recovery system |
US3472620A (en) * | 1967-11-13 | 1969-10-14 | Belge Produits Chimiques Sa | Process for the manufacture of nitric acid |
US4276277A (en) * | 1970-06-12 | 1981-06-30 | Produits Chimiques Ugine Kuhlmann | Manufacture of concentrated nitric acid |
CN111108064A (en) * | 2017-08-24 | 2020-05-05 | 雅苒国际集团 | Process for producing nitric acid |
CN109319776A (en) * | 2018-11-30 | 2019-02-12 | 黄冈师范学院 | The method, apparatus and application of nitrogen oxide and iron ion catalysis oxidation recycling diamond |
CN109319776B (en) * | 2018-11-30 | 2023-09-15 | 黄冈师范学院 | Method, device and application for recycling diamond through catalytic oxidation of nitrogen oxide and iron ions |
CN110980671A (en) * | 2019-12-27 | 2020-04-10 | 济南双硝技术开发有限公司 | Process method for improving concentration of acid generated by double-pressurization dilute nitric acid |
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