GB433356A - Improvements in or relating to the manufacture of quaternary ammonium salts - Google Patents
Improvements in or relating to the manufacture of quaternary ammonium saltsInfo
- Publication number
- GB433356A GB433356A GB33315/34A GB3331534A GB433356A GB 433356 A GB433356 A GB 433356A GB 33315/34 A GB33315/34 A GB 33315/34A GB 3331534 A GB3331534 A GB 3331534A GB 433356 A GB433356 A GB 433356A
- Authority
- GB
- United Kingdom
- Prior art keywords
- emulsions
- quaternary ammonium
- ammonium salts
- alkyl
- piperidine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
- C07D295/02—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms containing only hydrogen and carbon atoms in addition to the ring hetero elements
- C07D295/037—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms containing only hydrogen and carbon atoms in addition to the ring hetero elements with quaternary ring nitrogen atoms
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Hydrogenated Pyridines (AREA)
Abstract
Saturated heterocyclic bases such as piperidine are reacted with alkyl chlorides containing at least eight carbon atoms, and the N-alkyl derivatives so obtained are converted into quaternary ammonium salts by reaction with an alkylating agent which introduces an alkyl radicle of not more than six carbon atoms. In an example, piperidine is heated with cetyl chloride and the product is treated with dimethyl sulphate; the cetylmethylpiperidinium methyl sulphate so obtained is useful in making aqueous emulsions of paraffin, cetyl alcohol, olive oil and like materials, and the emulsions may then be used, as such or after addition of sodium carbonate, for the treatment of fibrous materials. The emulsions are stated to be more easily absorbed by the fibrous materials than emulsions prepared with the aid of quaternary ammonium salts derived from cyclic tertiary bases of the pyridine type. The Specification also refers by way of comparison to processes in which salts or quaternary salts of higher aliphatic amines are used as soap-substitutes in impregnating, greasing and revivifying processes and in stripping dyes.ALSO:Saturated heterocyclic bases such as piperidine are reacted with alkyl chlorides containing at least eight carbon atoms, and the N-alkyl derivatives so obtained are converted into quaternary ammonium salts by reaction with an alkylating agent which introduces an alkyl radicle of not more than six carbon atoms. In an example, piperidine is heated with cetyl chloride and the product is treated with dimethyl sulphate; the cetylmethylpiperidinium methyl sulphate so obtained is useful in making aqueous emulsions of paraffin, cetyl alcohol, olive oil and like materials, and the emulsions may then be used, as such or after addition of sodium carbonate, for the treatment of fibrous materials. The emulsions are stated to be more easily absorbed by the fibrous materials than emulsions prepared with the aid of quaternary ammonium salts derived from cyclic tertiary bases of the pyridine type.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE433356X | 1933-11-18 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB433356A true GB433356A (en) | 1935-08-13 |
Family
ID=6499212
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB33315/34A Expired GB433356A (en) | 1933-11-18 | 1934-11-19 | Improvements in or relating to the manufacture of quaternary ammonium salts |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB433356A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2417992A (en) * | 1942-04-14 | 1947-03-25 | Joseph B Niederl | N, n-dialkyl morpholinium alkylsulfates |
-
1934
- 1934-11-19 GB GB33315/34A patent/GB433356A/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2417992A (en) * | 1942-04-14 | 1947-03-25 | Joseph B Niederl | N, n-dialkyl morpholinium alkylsulfates |
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