GB407956A - Improvements in organic lubricants especially with regard to the lowering of the setting point of lubricating oils - Google Patents
Improvements in organic lubricants especially with regard to the lowering of the setting point of lubricating oilsInfo
- Publication number
- GB407956A GB407956A GB23092/32A GB2309232A GB407956A GB 407956 A GB407956 A GB 407956A GB 23092/32 A GB23092/32 A GB 23092/32A GB 2309232 A GB2309232 A GB 2309232A GB 407956 A GB407956 A GB 407956A
- Authority
- GB
- United Kingdom
- Prior art keywords
- chloride
- added
- acid
- chlorides
- naphthalene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M159/00—Lubricating compositions characterised by the additive being of unknown or incompletely defined constitution
- C10M159/12—Reaction products
- C10M159/14—Reaction products obtained by Friedel-Crafts condensation
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/06—Peroxides; Ozonides
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/08—Aldehydes; Ketones
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/08—Amides
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/08—Amides
- C10M2215/082—Amides containing hydroxyl groups; Alkoxylated derivatives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/28—Amides; Imides
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2217/04—Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2217/042—Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds between the nitrogen-containing monomer and an aldehyde or ketone
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2217/04—Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2217/043—Mannich bases
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2290/00—Mixtures of base materials or thickeners or additives
- C10M2290/02—Mineral base oils; Mixtures of fractions
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/02—Bearings
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/04—Oil-bath; Gear-boxes; Automatic transmissions; Traction drives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/04—Oil-bath; Gear-boxes; Automatic transmissions; Traction drives
- C10N2040/042—Oil-bath; Gear-boxes; Automatic transmissions; Traction drives for automatic transmissions
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/04—Oil-bath; Gear-boxes; Automatic transmissions; Traction drives
- C10N2040/044—Oil-bath; Gear-boxes; Automatic transmissions; Traction drives for manual transmissions
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/04—Oil-bath; Gear-boxes; Automatic transmissions; Traction drives
- C10N2040/046—Oil-bath; Gear-boxes; Automatic transmissions; Traction drives for traction drives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2050/00—Form in which the lubricant is applied to the material being lubricated
- C10N2050/10—Semi-solids; greasy
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
Lubricants are improved, especially as to pour point, by addition of 0.1--40.0 per cent of a substance obtained by condensing an acid chloride of m.w. above 200 and derived from an aliphatic hydrocarbon. Wax may also be added to improve the viscosity index. The chloride may be condensed alone or with other substances, e.g. liquid olefines, tars, benzol, toluol, xylene, naphthalene, ethyl-naphthalene, phenols, naphthols, aniline, naphthylamine, nitrated-aromatics, cyclic terpenes, coal tar fractions, e.g. crude benzene, middle oil, anthracene oil, aromatics obtained by destructive hydrogenation or by dehydrogenation, and cracking gases containing ethylene, propylene, and butylene. Acid chlorides specified are those of stearic, palmitic, oleic, erucic, elaidic, linoleic, behenolic, stearolic, and montanic acids and of the acids obtained by oxidizing paraffin wax by air. The chlorides may be first halogenated and then condensed, or this halogen may be removed to render the chlorides unsaturated prior to condensation. The condensation is preferably carried out at 30--120 DEG C. in presence of condensing agents such as chloride of aluminium, zinc, or iron, boron fluoride, phosphorus oxychloride, active aluminium, sodium, zinc dust, active silica, and bleaching earths. Substances splitting off water, e.g. phosphorus pentoxide, sulphuric acid, may be used when acid chlorides of hydroxy-carboxylic acids are treated. When strong condensing agents are used retarding agents, e.g. zinc oxide, soda, calcium carbonate, or ammonia may be present. The chloride may be treated, dissolved, e.g. in kerosene or heavy naphtha, and the condensed product may be treated with active silica or bleaching earths, and may be purified by water, alkali, or diluted sulphuric acid. The product may be distilled with steam or in vacuo to remove lighter inactive fractions. Products of m.w. 600--2000 are specified. In one example, 100 lb. of stearic acid chloride obtained by acting on stearic acid with thionyl chloride at 80 DEG C. is dissolved in 100 lb. of kerosene, 20 lb. of naphthalene and 7 lb. of aluminium chloride are added, and the whole is kept at 30 DEG C. for 24 hours, then at 90 DEG C. for 1--2 hours. The product is centrifuged and distilled in vacuo. 0.5 lb. of the waxy residue is added to 100 lb. of machine oil and reduces the pour points 25 DEG C., and 5 lb. is added to 95 lb. of gear oil.ALSO:Lubricants are improved, especially as to pour-point, by addition of 0.1--40.0 per cent of a substance obtained by condensing an acid chloride of m.w. above 200 and derived from an aliphatic hydrocarbon. Wax may also be added to improve the viscosity index. The chloride may be condensed alone or with other substances, e.g. liquid olefines, tars, benzol, toluol, xylene, naphthalene, ethyl-naphthalene, phenols, naphthols, aniline, naphthylamine, nitrated aromatics, cyclic terpenes, coal-tar fractions, e.g. crude benzene, middle oil, anthracene oil, aromatics obtained by destructive hydrogenation or by dehydrogenation, and cracking gases containing ethylene, propylene, and butylene. Acid chlorides specified are those of stearic, palmitic, oleic, erucic, elaidic, linoleic, behenolic, stearolic, and montanic acids and of the acids obtained by oxidizing paraffin wax by air. The chlorides may be first halogenated and then condensed, or this halogen may be removed to render the chlorides unsaturated prior to condensation. The condensation is preferably carried out at 30--120 DEG C. in presence of condensing agents such as chloride of aluminium, zinc, or iron, boron fluoride, phosphorus oxychloride, active aluminium, sodium, zinc dust, active silica, and bleaching earths. Substances splitting off water, e.g. phosphorus pentoxide, sulphuric acid, may be used when acid chlorides of hydroxy-carboxylic acids are treated. When strong condensing agents are used retarding agents, e.g. zinc oxide, soda, calcium carbonate, or ammonia may be present. The chloride may be treated dissolved, e.g. in kerosene or heavy naphtha, and the condensed product may be treated with active silica or bleaching earths, and may be purified by water, alkali, or diluted sulphuric acid. The product may be distilled with steam or in vacuo to remove lighter inactive fractions. Products of m.w. 600-2000 are specified. In one example, 100 lb. of stearic acid chloride obtained by acting on stearic acid with thionyl chloride at 80 DEG C. is dissolved in 100 lb. of kerosene, 20 lb. of naphthalene and 7 lb. of aluminium chloride are added, and the whole is kept at 30 DEG C. for 24 hours, then at 90 DEG C. for 1--2 hours. The product is centrifuged and distilled in vacuo. 0.5 lb. of the waxy residue is added to 100 lb. of machine oil and reduces the pour-point 25 DEG C., and 5 lb. is added to 95 lb. of gear oil.
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEI44265D DE634623C (en) | 1932-04-21 | 1932-04-21 | Pour point depressant |
GB23092/32A GB407956A (en) | 1932-04-21 | 1932-08-17 | Improvements in organic lubricants especially with regard to the lowering of the setting point of lubricating oils |
NL64852A NL35238C (en) | 1932-04-21 | 1933-04-03 | |
FR754456D FR754456A (en) | 1932-04-21 | 1933-04-18 | Process for the preparation of improved oils for use as lubricants, and in particular low pour point oil |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEI44265D DE634623C (en) | 1932-04-21 | 1932-04-21 | Pour point depressant |
GB23092/32A GB407956A (en) | 1932-04-21 | 1932-08-17 | Improvements in organic lubricants especially with regard to the lowering of the setting point of lubricating oils |
Publications (1)
Publication Number | Publication Date |
---|---|
GB407956A true GB407956A (en) | 1934-03-19 |
Family
ID=25981694
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB23092/32A Expired GB407956A (en) | 1932-04-21 | 1932-08-17 | Improvements in organic lubricants especially with regard to the lowering of the setting point of lubricating oils |
Country Status (4)
Country | Link |
---|---|
DE (1) | DE634623C (en) |
FR (1) | FR754456A (en) |
GB (1) | GB407956A (en) |
NL (1) | NL35238C (en) |
-
1932
- 1932-04-21 DE DEI44265D patent/DE634623C/en not_active Expired
- 1932-08-17 GB GB23092/32A patent/GB407956A/en not_active Expired
-
1933
- 1933-04-03 NL NL64852A patent/NL35238C/xx active
- 1933-04-18 FR FR754456D patent/FR754456A/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
DE634623C (en) | 1936-08-31 |
FR754456A (en) | 1933-11-07 |
NL35238C (en) | 1935-04-15 |
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