GB378345A - Improved manufacture of mixtures of sodium phosphates for treating boiler waters andother aqueous liquors - Google Patents
Improved manufacture of mixtures of sodium phosphates for treating boiler waters andother aqueous liquorsInfo
- Publication number
- GB378345A GB378345A GB660132A GB660132A GB378345A GB 378345 A GB378345 A GB 378345A GB 660132 A GB660132 A GB 660132A GB 660132 A GB660132 A GB 660132A GB 378345 A GB378345 A GB 378345A
- Authority
- GB
- United Kingdom
- Prior art keywords
- mixtures
- sodium
- mixture
- orthophosphates
- orthophosphoric acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B25/00—Phosphorus; Compounds thereof
- C01B25/16—Oxyacids of phosphorus; Salts thereof
- C01B25/26—Phosphates
- C01B25/38—Condensed phosphates
- C01B25/39—Condensed phosphates of alkali metals
- C01B25/395—Preparation and dehydrating
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F5/00—Softening water; Preventing scale; Adding scale preventatives or scale removers to water, e.g. adding sequestering agents
- C02F5/08—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents
- C02F5/086—Condensed phosphates
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Inorganic Chemistry (AREA)
- Fertilizers (AREA)
Abstract
Mixtures of tetrasodium pyrophosphate and sodium metaphosphate having a predetermined hydrogen ion concentration in aqueous solution are obtained by mixing stoichiometrically proportioned amounts of different sodium orthophosphates, or of orthophosphoric acid with the sodium salt of a replaceable acid, heating the mixture to the melting-point, and quickly cooling, as by pouring the molten mass on a cold metal surface in thin layers. The mixture to be treated may consist of mono- and disodium orthophosphates, or of orthophosphoric acid and sodium carbonate, and equations are given whereby mixtures of the pyro-and metaphosphates in any determined proportions may be obtained. A diagram is furnished showing the melting points of the various mixtures and their pH value in solution, the latter value ranging from 6,4 to 10. The products may be used for controlling the pH value of water solutions, and particularly for treating boiler waters as they give the desired alkalinity and exhibit a delayed precipitating action towards the alkaline-earth metal salts.ALSO:The hydrogen ion concentration of water solutions is controlled by the use of mixtures of tetrasodium pyrophosphate and sodium metaphosphate prepared by mixing stoichiometrically proportioned amounts of different sodium orthophosphates, or of orthophosphoric acid with the sodium salt of a replaceable acid, heating the mixture to the melting point, and quickly cooling, as by pouring the molten mass on a cold metal surface in thin layers. The mixture to be heated may consist of mono- and disodium orthophosphates, or of orthophosphoric acid and sodium carbonate, and equations are given whereby mixtures of the pyro- and meta-phosphates in any determined proportions may be obtained. A diagram is furnished showing the melting points of the various mixtures and their pH value in solution, the latter value ranging from 6.4 to 10.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB660132A GB378345A (en) | 1932-03-04 | 1932-03-04 | Improved manufacture of mixtures of sodium phosphates for treating boiler waters andother aqueous liquors |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB660132A GB378345A (en) | 1932-03-04 | 1932-03-04 | Improved manufacture of mixtures of sodium phosphates for treating boiler waters andother aqueous liquors |
Publications (1)
Publication Number | Publication Date |
---|---|
GB378345A true GB378345A (en) | 1932-08-11 |
Family
ID=9817454
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB660132A Expired GB378345A (en) | 1932-03-04 | 1932-03-04 | Improved manufacture of mixtures of sodium phosphates for treating boiler waters andother aqueous liquors |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB378345A (en) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE747770C (en) * | 1932-08-22 | 1944-10-13 | Detergents, cleaning agents and dishwashing detergents | |
DE762903C (en) * | 1934-05-17 | 1950-10-05 | Henkel & Cie Gmbh | Production of polyphosphates |
DE767012C (en) * | 1934-02-01 | 1951-07-26 | Albert Ag Chem Werke | Water softeners |
US2668147A (en) * | 1951-10-27 | 1954-02-02 | Henkel & Cie Gmbh | Process for producing a material containing sodium polyphosphates |
US2811419A (en) * | 1953-03-21 | 1957-10-29 | Knapsack Ag | Process for producing monomeric phosphates |
-
1932
- 1932-03-04 GB GB660132A patent/GB378345A/en not_active Expired
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE747770C (en) * | 1932-08-22 | 1944-10-13 | Detergents, cleaning agents and dishwashing detergents | |
DE767012C (en) * | 1934-02-01 | 1951-07-26 | Albert Ag Chem Werke | Water softeners |
DE762903C (en) * | 1934-05-17 | 1950-10-05 | Henkel & Cie Gmbh | Production of polyphosphates |
US2668147A (en) * | 1951-10-27 | 1954-02-02 | Henkel & Cie Gmbh | Process for producing a material containing sodium polyphosphates |
US2811419A (en) * | 1953-03-21 | 1957-10-29 | Knapsack Ag | Process for producing monomeric phosphates |
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