GB376929A - Process for the production of synthetic resins from alcoholamines and organic acids - Google Patents
Process for the production of synthetic resins from alcoholamines and organic acidsInfo
- Publication number
- GB376929A GB376929A GB18160/31A GB1816031A GB376929A GB 376929 A GB376929 A GB 376929A GB 18160/31 A GB18160/31 A GB 18160/31A GB 1816031 A GB1816031 A GB 1816031A GB 376929 A GB376929 A GB 376929A
- Authority
- GB
- United Kingdom
- Prior art keywords
- acid
- heated
- mixture
- anhydride
- phthalic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Polyamides (AREA)
Abstract
Polybasic carboxylic acids or anhydrides thereof are condensed with alcoholamines with or without the addition of polyhydric alcohols to give a thermo-hardening resinous product. The products may be used as softening agents for artificial and natural resins, as vulcanization accelerators and as a catalyst and softening agent with phenol-formaldehyde condensation products. As polybasic carboxylic acids there may be used phthalic acid or anhydride, adipic acid, sebacic acid, citric acid, benzophenone dicarboxylic acid, succinic acid or its homologues, aromatic di- and polycarboxylic acids alone or in mixture. As alcoholamines there may be used tri-, di- or monoethanolamine in a pure form or in mixtures such as technical ethanolamine mixtures and they may be diluted with glycerol or other polyhydric alcohols. Soaps appear to be first formed and these are transposed into esters of the amines on strong heating. Acid esters still soluble in alcohol or acid or neutral ester salts may be used as softening agents for lacquers or for synthetic resins capable of being hardened. After hardening they have adhesive properties. In examples, (1) commercial triethanolamine is condensed with adipic acid to give a product soluble in alcohol which on further heating is converted into an insoluble gummy elastic and gelatinous material. (2) Triethanolamine is heated with phthalic anhydride. (3) Diethanolamine is heated with citric acid. (4) Triethanolamine is heated with a mixture of succinic acid and phthalic acid anhydride. (5) A mixture of mono- and diethanolamine is heated with adipic acid. (6) A mixture of technical triethanolamine and glycerol is heated with a mixture of phthalic acid anhydride is heated with a mixture of a polyglycerol (corresponding to diglycerol) and tributanolamine. (8) Phthalic acid anhydride is heated with diethylmonoglycerolamine.ALSO:Condensation products of polycarboxylic acids or anhydrides, such as phthalic acid, phthalic anhydride, adipic acid, sebacic acid, citric acid, benzophenone dicarboxylic acid, and succinic acid and its homologues, and alcoholamines, such as mono-, di-, and triethanolamine, and glycerolamines, with or without the addition of polyhydric alcohols such as glycerol are suitable for vulcanization accelerators.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE611462X | 1931-04-17 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB376929A true GB376929A (en) | 1932-07-21 |
Family
ID=34876955
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB18160/31A Expired GB376929A (en) | 1931-04-17 | 1931-06-23 | Process for the production of synthetic resins from alcoholamines and organic acids |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB376929A (en) |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2421024A (en) * | 1942-03-24 | 1947-05-27 | Bell Telephone Labor Inc | Linear polymer containing cyclic imide groups |
US2440516A (en) * | 1939-05-26 | 1948-04-27 | American Cyanamid Co | Polyester-polyamide condensation products and process of producing the same |
US2463977A (en) * | 1944-03-16 | 1949-03-08 | American Cyanamid Co | Polyamide-polyester condensation products and processes of producing the same |
US2490003A (en) * | 1946-12-18 | 1949-11-29 | American Cyanamid Co | Leather-like polyester-polyamides and process of producing same |
US2609348A (en) * | 1946-05-03 | 1952-09-02 | Ass Of American Soap & Glyceri | Short-oil alkyd resin of low acid number and methods of preparing the same |
US2618659A (en) * | 1946-12-21 | 1952-11-18 | Ass Of American Soap & Glyceri | Preparation of glyceryl amines |
US3036974A (en) * | 1956-05-01 | 1962-05-29 | Basf Ag | Production of polyester amides |
EP1889819A1 (en) * | 2006-08-18 | 2008-02-20 | Rockwool International A/S | Binder for mineral fibres |
-
1931
- 1931-06-23 GB GB18160/31A patent/GB376929A/en not_active Expired
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2440516A (en) * | 1939-05-26 | 1948-04-27 | American Cyanamid Co | Polyester-polyamide condensation products and process of producing the same |
US2421024A (en) * | 1942-03-24 | 1947-05-27 | Bell Telephone Labor Inc | Linear polymer containing cyclic imide groups |
US2463977A (en) * | 1944-03-16 | 1949-03-08 | American Cyanamid Co | Polyamide-polyester condensation products and processes of producing the same |
US2609348A (en) * | 1946-05-03 | 1952-09-02 | Ass Of American Soap & Glyceri | Short-oil alkyd resin of low acid number and methods of preparing the same |
US2490003A (en) * | 1946-12-18 | 1949-11-29 | American Cyanamid Co | Leather-like polyester-polyamides and process of producing same |
US2618659A (en) * | 1946-12-21 | 1952-11-18 | Ass Of American Soap & Glyceri | Preparation of glyceryl amines |
US3036974A (en) * | 1956-05-01 | 1962-05-29 | Basf Ag | Production of polyester amides |
EP1889819A1 (en) * | 2006-08-18 | 2008-02-20 | Rockwool International A/S | Binder for mineral fibres |
WO2008020069A1 (en) * | 2006-08-18 | 2008-02-21 | Rockwool International A/S | Binder for mineral fibres |
AU2007285684B2 (en) * | 2006-08-18 | 2013-05-16 | Rockwool International A/S | Binder for mineral fibres |
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