GB373358A - Manufacture of solutions of resins - Google Patents

Manufacture of solutions of resins

Info

Publication number
GB373358A
GB373358A GB11651/31A GB1165131A GB373358A GB 373358 A GB373358 A GB 373358A GB 11651/31 A GB11651/31 A GB 11651/31A GB 1165131 A GB1165131 A GB 1165131A GB 373358 A GB373358 A GB 373358A
Authority
GB
United Kingdom
Prior art keywords
resin
dissolved
aldehyde
cyclohexanone
formaldehyde
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB11651/31A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF Schweiz AG
Original Assignee
Gesellschaft fuer Chemische Industrie in Basel CIBA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Gesellschaft fuer Chemische Industrie in Basel CIBA filed Critical Gesellschaft fuer Chemische Industrie in Basel CIBA
Publication of GB373358A publication Critical patent/GB373358A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00Processes of treating or compounding macromolecular substances
    • C08J3/02Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques
    • C08J3/09Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in organic liquids
    • C08J3/091Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in organic liquids characterised by the chemical constitution of the organic liquid
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2361/00Characterised by the use of condensation polymers of aldehydes or ketones; Derivatives of such polymers
    • C08J2361/20Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen

Landscapes

  • Chemical & Material Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Phenolic Resins Or Amino Resins (AREA)
  • Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)

Abstract

Solutions useful as lacquers contain a condensation product made from an aromatic amine and formaldehyde in the presence of about an equivalent proportion of acid, together with an aldehyde or a substance yielding aldehyde or a mixture of both, and with or without other resin-forming substances, aldehyde condensation products capable of being hardened, or other materials ordinarily used in the manufacture of lacquers. The materials may be dissolved in a common solvent, or an excess of the aldehyde or substance yielding aldehyde may be used as the solvent. The coatings obtained may be hardened by heat, and the rate of hardening may be accelerated or retarded, according to the particular ingredients, by addition of acid or basic substances such as stearic or salicylic acid, furfuramide, or triethanolamine. The aldehyde or substance yielding aldehyde may be added to the amine-formaldehyde condensation product before of after the dissolution of the latter. In the examples, (1) a fusible resin made from aniline and formaldehyde in the presence of hydrochloric acid, as described in Specification 342,325, [Group IV], is dissolved in cyclohexanone and furfurol and furfuramide are added to the solution, which may then be diluted with acetone; (2) the resin used in example 1 is dissolved in furfurol, with the addition of a little triethanolamine; (3) an infusible resin, prepared from aniline and an excess of formaldehyde in the presence of hydrochloric acid, is dissolved in cyclohexanone and chlorohydrin, the solution is diluted with toluene, and p-cresoldimethylol is added; (4) a resin prepared from anhydroformaldehyde aniline and hydrochloric acid is dissolved in cyclohexanone and the solution is diluted with acetone; prior to use, crotonic aldehyde and a rapidly hardening phenol-formaldehyde resin are added; (5) the resin used in example 3 is melted with anhydroformaldehyde aniline, and the product is dissolved in cyclohexanone and furfurol; (6) a resin similar to that used in example 1 is treated in the course of its preparation, prior to the elimination of the acid, with a mixture of phenol polyalcohols prepared by condensing an alkaline solution of phenol with formaldehyde in the cold; the mixture is made alkaline with sodium carbonate, and the precipitated resin is isolated and dissolved in cyclohexanone; the solution is diluted with acetone, and diethyl phthalate is added; (7) the resin used in example 1 is dissolved in cyclohexanone together with a mixture of phenol polyalcohols; any of the usual softening agents is added, and the mixture is diluted; prior to use, it is treated with a solution of salicylic acid in furfurol. Specifications 343,882, 372,075, and 372,076, [all in Group IV], also are referred to.ALSO:Solutions useful as lacquers contain a condensation product made from an aromatic amine and formaldehyde in the presence of about an equivalent proportion of acid, together with an aldehyde or a substance yielding aldehyde or a mixture of both, and with or without other resin-forming substances, aldehyde condensation products capable of being hardened, or other materials ordinarily used in the manufacture of lacquers. The materials may be dissolved in a common solvent, or an excess of the aldehyde or substance yielding aldehyde may be used as the solvent. The coatings obtained may be hardened by heat, and the rate of hardening may be accelerated or retarded, according to the particular ingredients, by addition of acid or basic substances such as stearic or salicylic acid, furfuramide, or triethanolamine. The aldehyde or substance yielding aldehyde may be added to the amine-formaldehyde condensation product before or after the dissolution of the latter. In the examples, (1) a fusible resin made from aniline and formaldehyde in the presence of hydrochloric acid, as described in Specification 342,325, is dissolved in cyclohexanone, and furfurol and furfuramide are added to the solution, which may then be diluted with acetone; (2) the resin used in example 1 is dissolved in furfurol, with the addition of a little triethanolamine; (3) an infusible resin, prepared from aniline and an excess of formaldehyde in the presence of hydrochloric acid, is dissolved in cyclohexanone and chlorohydrin, the solution is diluted with toluene, and p-cresoldimethylol is added; (4) a resin prepared from anhydroformaldehyde aniline and hydrochloric acid is dissolved in cyclohexanone and the solution is diluted with acetone; prior to use, crotonic aldehyde and a rapidly hardening phenol-formaldehyde resin are added; (5) the resin used in example (3) is melted with anhydroformaldehyde aniline, and the product is dissolved in cyclohexanone and furfurol; (6) a resin similar to that used in example (1) is treated in the course of its preparation, prior to the elimination of the acid, with a mixture of phenol polyalcohols prepared by condensing an alkaline solution of phenol with formaldehyde in the cold; the mixture is made alkaline with sodium carbonate, and the precipitated resin is isolated and dissolved in cyclohexanone; the solution is diluted with acetone, and diethyl phthalate is added; (7) the resin used in example (1) is dissolved in cyclohexanone together with a mixture of phenol polyalcohols; any of the usual softening agents is added, and the mixture is diluted; prior to use, it is treated with a solution of salicylic acid in furfurol. Specifications 343,882, 372,075 and 372,076 also are referred to.
GB11651/31A 1930-07-11 1931-04-20 Manufacture of solutions of resins Expired GB373358A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CH373358X 1930-07-11

Publications (1)

Publication Number Publication Date
GB373358A true GB373358A (en) 1932-05-26

Family

ID=4513506

Family Applications (1)

Application Number Title Priority Date Filing Date
GB11651/31A Expired GB373358A (en) 1930-07-11 1931-04-20 Manufacture of solutions of resins

Country Status (1)

Country Link
GB (1) GB373358A (en)

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