GB366586A - Compositions of matter containing cellulose derivatives and products obtained therefrom - Google Patents

Compositions of matter containing cellulose derivatives and products obtained therefrom

Info

Publication number
GB366586A
GB366586A GB33519/30A GB3351930A GB366586A GB 366586 A GB366586 A GB 366586A GB 33519/30 A GB33519/30 A GB 33519/30A GB 3351930 A GB3351930 A GB 3351930A GB 366586 A GB366586 A GB 366586A
Authority
GB
United Kingdom
Prior art keywords
resin
cellulose
alcohol
acetate
phenol
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB33519/30A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Acordis UK Ltd
Original Assignee
British Celanese Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by British Celanese Ltd filed Critical British Celanese Ltd
Publication of GB366586A publication Critical patent/GB366586A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L1/00Compositions of cellulose, modified cellulose or cellulose derivatives
    • C08L1/08Cellulose derivatives
    • C08L1/10Esters of organic acids, i.e. acylates
    • C08L1/12Cellulose acetate

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Laminated Bodies (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

Lacquers, varnishes and coating compositions, are prepared by incorporating a phenol-chlorketone resin with a cellulose derivative, with or without the addition of solvents, plasticizers, softeners, other resins, fire retardants, &c. The resins are obtained by condensing a phenolic body, such as phenol, cresol, xylenol and diphenylolpropane, with a chlorketone, such as monochlormethylethylketone and monochloracetone, preferably in the presence of an acid catalyst. The cellulose derivative may comprise the nitrate, acetate, formate, propionate, butyrate or other ester, or ethyl-cellulose, methylcellulose, benzyl-cellulose or other ether. Of the solvents which may be used are mentioned acetone, alcohol, benzene, ethylene dichloride, ethyl acetate, ethyl lactate, tetrachlorethane, benzyl alcohol and diacetone-alcohol. As examples of plasticizers, reference is made to diphenylolpropane, triacetin, dibutyl tartrate, diethyl phthalate and xylene monomethylsulphonamide. Other resins mentioned are the artificial resins from phenol-formaldehyde and diphenylolpropane-formaldehyde, or the natural resins manila, acaroides, pontianak, kauri, dammar, rosin, shellac and ester gums. Brominated organic compounds, e.g. brominated tricresyl phosphate, may be present as fire retardants. Examples are given of the preparation of (1) coating compositions consisting of (a) cellulose acetate, resin and acetone, (b) cellulose acetate, resin, acetone, benzene, alcohol and diacetone-alcohol, (c) cellulose nitrate, camphor, diethyl phthalate, resin, benzene, alcohol, butyl alcohol, butyl acetate and ethyl acetate ; (2) a lacquer consisting of cellulose acetate, resin, diphenylolpropane, pigment, acetone, ethyl acetate, benzene, toluene and ethyl lactate. In both Examples the resin employed is a phenolchlorketone resin and the proportions of the constituents are given.ALSO:Lacquers, varnishes, coating compositions, plastic materials, adhesives, filaments, photographic and other films are prepared by incorporating a phenol-chlorketone resin with a cellulose derivative, with or without the addition of solvents, plasticizers, softeners, other resins, fire retardants, &c. The resins are obtained by condensing a phenolic body, such as phenol, cresol, xylenol and diphenylolpropane, with a chlorketone, such as monochlormethylethylketone and monochloracetone, preferably in the presence of an acid catalyst. Examples are given of the condensation of phenol, o-cresol, m-cresol and diphenylolpropane with chloracetone in the presence of concentrated hydrochloric acid. The cellulose derivative may comprise the nitrate, acetate, formate, propionate, butyrate or other ester, or ethyl-cellulose, methyl-cellulose, benzyl-cellulose or other ether. Of the solvents which may be used are mentioned acetone, alcohol, benzene, ethylene dichloride, ethyl acetate, ethyl lactate, tetrachlorethane, benzyl alcohol and diacetone-alcohol. As examples of plasticizers, reference is made to diphenylolpropane, triacetin, dibutyl tartrate, diethyl phthalate and xylene monomethylsulphonamide. Other resins mentioned are the artificial resins from phenol-formaldehyde and diphenylolpropane-formaldehyde, or the natural resins manila, accroides, pontianak, kauri, dammar, rosin, shellac and ester gums. Brominated organic compounds, e.g. brominated tricresyl phosphate, may be present as fire retardants. Solutions containing a phenol-chlorketone resin and a cellulose derivative may be used as lacquers for coating metal, glass, etc.; or for the production of filaments by wet or dry spinning methods; or for securing cellulose derivative sheets to sheets of glass in the manufacture of reinforced glass. Plastic materials containing a cellulose derivative and a phenol-chlorketone resin may also be made into sheets of reinforcing material for reinforced glass. Examples are given of the preparation of (1) coating compositions consisting of (a) cellulose acetate, resin and acetone, (b) cellulose acetate, resin, acetone, benzene, alcohol, and diacetone-alcohol, (c) cellulose nitrate, camphor, diethyl phthalate, resin, benzene, alcohol, butyl alcohol, butyl acetate, and ethyl acetate; (2) adhesives, specially suitable for securing sheets of material having a basis of a cellulose derivative to surfaces of glass, cardboard, asbestos, metal, &c., comprising (a) cellulose acetate, resin, acetone, ethyl acetate, and ethyl lactate, (b) cellulose nitrate, camphor, dibutyl phthalate, resin, benzene, alcohol, butyl alcohol, butyl acetate and ethyl acetate; (3) a plastic composition consisting of cellulose acetate, resin, xylene monomethylsulphonamide, alcohol, and benzene; (4) a solution for making filaments by dry spinning methods containing cellulose acetate, resin, and acetone; (5) a lacquer consisting of cellulose acetate, resin, diphenylolpropane, pigment, acetone, ethyl acetate, benzene, toluene, and ethyl lactate. In each of the examples the resin employed is a phenol-chlorketone resin and the proportions of the constituents are given. The Specification as open to inspection under Sect. 91 (3) (a) also describes the use of a solution of the resin alone as an adhesive. This subject matter does not appear in the Specification as accepted.ALSO:Plastic materials and adhesives are prepared by incorporating a phenol-chlorketone resin with a cellulose derivative, with or without the addition of solvents, plasticizers, softeners, other resins, fire retardants, &c. The resins are obtained by condensing a phenolic body, such as phenol, cresol, xylenol and diphenylolpropane, with a chlorketone, such as monochlormethylethylketone and monochloracetone, preferably in the presence of an acid catalyst. The cellulose derivative may comprise the nitrate, acetate, formate, propionate, butyrate or other ester, or ethyl-cellulose, methyl-cellulose, benzyl-cellulose or other ether. Of the solvents which may be used are mentioned acetone, alcohol, benzene, ethylene dichloride, ethyl acetate, ethyl lactate, tetrachlorethane, benzyl alcohol and diacetone-alcohol. As examples of plasticizers, reference is made to diphenylolpropane, triacetin, dibutyl tartrate, diethyl phthalate and xylene monomethylsulphonamide. Other resins mentioned are the artificial resins from phenol-formaldehyde and diphenylolpropane-formaldehyde, or the natural resins manila, acaroides, pontianak, kauri, dammer, rosin, shellac and ester gums. Brominated organic compounds, e.g. brominated tricresyl phosphate, may be present as fire retardants. Solutions containing a phenolchlorketone resin and a cellulose derivative may be used for securing cellulose derivative sheets to sheets of glass in the manufacture of reinforced glass. Plastic materials containing a cellulose derivative and a phenol-chlorketone resin may also be made into sheets of reinforcing material for reinforced glass. Examples are given of the preparation of (1) adhesives, specially suitable for securing sheets of material having a basis of a cellulose derivative to surfaces of glass, cardboard, asbestos, metal, &c., comprising (a) cellulose acetate, resin, acetone, ethyl acetate and ethyl lactate, (b) cellulose nitrate, camphor, dibutyl phthalate, resin, benzene, alcohol, butyl alcohol, butyl acetate and ethyl acetate; (2) a plastic composition consisting of cellulose acetate, resin, xylene monomethylsulphonamide, alcohol and benzene. In both examples the resin employed is a phenol-chlorketone resin and the proportions of the constituents are given. The Specification as open to inspection under Sect. 91 (3) (a) also describes the use of a solution of the resin alone as an adhesive. This subject-matter does not appear in the Specification as accepted.
GB33519/30A 1929-11-07 1930-11-07 Compositions of matter containing cellulose derivatives and products obtained therefrom Expired GB366586A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US366586XA 1929-11-07 1929-11-07

Publications (1)

Publication Number Publication Date
GB366586A true GB366586A (en) 1932-02-08

Family

ID=21889885

Family Applications (1)

Application Number Title Priority Date Filing Date
GB33519/30A Expired GB366586A (en) 1929-11-07 1930-11-07 Compositions of matter containing cellulose derivatives and products obtained therefrom

Country Status (1)

Country Link
GB (1) GB366586A (en)

Similar Documents

Publication Publication Date Title
GB366586A (en) Compositions of matter containing cellulose derivatives and products obtained therefrom
US1902257A (en) Derivative of cellulose composition
US1940727A (en) Resin and coating or plastic composition containing the same
GB365093A (en) The manufacture and use of new synthetic resins
US1840597A (en) Synthetic resin and process of making the same
US2006517A (en) Method of preparing vinyl phenols
GB376839A (en) Improved synthetic resins and their manufacture
GB368801A (en) Improvements in cellulose derivative compositions
US1958488A (en) Resin and coating or plastic composition containing the same
US2015083A (en) Synthetic resin and method of preparing the same
US2022389A (en) Resin and coating or plastic composition containing the same
US1840596A (en) Synthetic resin and process of making the same
GB365094A (en) Compositions of matter containing synthetic resins and products obtained therefrom
US2038764A (en) Synthetic resin
US1902256A (en) Coating composition and film produced thereby
US1873849A (en) Synthetic resin and process of making the same
GB344413A (en) The manufacture and uses of new synthetic resins
US1954826A (en) Resin and coating or plastic compositions containing the same
US1964039A (en) Method of protecting cellulose derivative surfaces and product thereof
GB340101A (en) New synthetic resins and their uses
GB409896A (en) Improvements in or relating to synthetic resins and compositions and articles containing them
US1907554A (en) Toluene sulphonamide aldehyde resins and method of making the same
GB340102A (en) The manufacture and use of new synthetic resins
US2017993A (en) Resin and coating or plastic composition containing the same
US2041783A (en) Method for producing a synthetic resin