GB344413A - The manufacture and uses of new synthetic resins - Google Patents

The manufacture and uses of new synthetic resins

Info

Publication number
GB344413A
GB344413A GB35933/29A GB3593329A GB344413A GB 344413 A GB344413 A GB 344413A GB 35933/29 A GB35933/29 A GB 35933/29A GB 3593329 A GB3593329 A GB 3593329A GB 344413 A GB344413 A GB 344413A
Authority
GB
United Kingdom
Prior art keywords
diphenylol
resins
ethyl
formaldehyde
resin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB35933/29A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Acordis UK Ltd
Original Assignee
British Celanese Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by British Celanese Ltd filed Critical British Celanese Ltd
Publication of GB344413A publication Critical patent/GB344413A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G8/00Condensation polymers of aldehydes or ketones with phenols only
    • C08G8/04Condensation polymers of aldehydes or ketones with phenols only of aldehydes
    • C08G8/08Condensation polymers of aldehydes or ketones with phenols only of aldehydes of formaldehyde, e.g. of formaldehyde formed in situ
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G14/00Condensation polymers of aldehydes or ketones with two or more other monomers covered by at least two of the groups C08G8/00 - C08G12/00
    • C08G14/02Condensation polymers of aldehydes or ketones with two or more other monomers covered by at least two of the groups C08G8/00 - C08G12/00 of aldehydes
    • C08G14/04Condensation polymers of aldehydes or ketones with two or more other monomers covered by at least two of the groups C08G8/00 - C08G12/00 of aldehydes with phenols
    • C08G14/06Condensation polymers of aldehydes or ketones with two or more other monomers covered by at least two of the groups C08G8/00 - C08G12/00 of aldehydes with phenols and monomers containing hydrogen attached to nitrogen

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

Resinous products prepared by condensing a diphenylol cycloparaffin with formaldehyde, in the presence or absence of other synthetic resin components, e.g. diphenylol propane, urea, or toluene sulphonamide, and in the presence or absence of an acid, neutral or alkaline catalyst are used as ingredients of compositions having a basis of cellulose ester or ether. Thus, lacquers &c. may be made from a cellulose ester or ether and a resin prepared as described above; such lacquers &c. may include also other synthetic resins, e.g. fusible and soluble phenol-formaldehyde or diphenylolpropane-formaldehyde resins, preferably those prepared in the presence of an acid catalyst, phenolfurfural resins, and resins from formaldehyde or furfural and toluene sulphonamide, semi-synthetic resins, e.g. ester gum, natural resins, e.g. manila, acaroid resins, pontianak, kauri, dammar, rosin, and shellac, plasticizers, e.g. diphenylol propane, xylene monomethylsulphonamide, toluene o- or m-ethylsulphonamide, fire retardants, e.g. bromtricresyl phosphates, and the usual pigments &c. Solvents that may be used in so applying the resins include acetone, ethyl alcohol, benzene, ethylene dichloride, ethyl acetate and lactate, tetrachlorethane, benzyl alcohol, and diacetone alcohol. Examples are given describing (1) a coating composition containing cellulose acetate, diphenylol-cyclohexane-formaldehyde resin, and acetone; (2) a coating composition containing cellulose acetate, diphenylol-cyclohexane-formaldehyde resin, acetone, benzene, ethyl alcohol, and ethyl lactate; (3) a coating composition containing cellulose nitrate, diphenyl-cyclohexane-formaldehyde resin, camphor, diethyl phthalate, benzene, ethyl and butyl alcohols, and ethyl and butyl acetates; (4) a lacquer containing cellulose acetate, diphenylol-cyclohexane-formaldehyde resin, diphenylol propane, acetone, benzene, toluene, ethyl acetate and lactate, and a pigment. The manufacture of products having a basis of cellulose formate, propionate, or butyrate, or of methyl, ethyl, or benzyl cellulose is referred to. Specification 342,429 is referred to.ALSO:Resinous products are prepared by condensing a diphenylol cycloparaffin with formaldehyde. Mixed products may be obtained by including in the reaction mixture other synthetic resin components, e.g. diphenylol propane, urea, or toluene sulphonamide. The condensation may be effected in the presence of an acid, neutral, or alkaline catalyst. In an example, equimolecular proportions of diphenylol cyclohexane and formaldehyde solution are heated under reflux with the addition of a catalyst, e.g. hydrochloric or boric acid, and the product is washed with water. It may be purified after solution in caustic soda or alcohol, and then distilled at ordinary or reduced pressure to remove water &c., and after or during the distillation it may be hardened by heating at 140-150 DEG C. The diphenylol cyclohexane used may be the pure compound or a crude product obtained by condensing phenol with cyclohexanone (cf. Specification 342,429). The resinous products prepared as described above are useful as ingredients of compositions having a basis of cellulose ester or ether. Thus, lacquers, varnishes, plastic masses, &c., may be made from a cellulose ester or ether and a resin prepared as described above; such lacquers &c. may include also other synthetic resins, e.g. fusible and soluble phenol-formaldehyde or diphenylolpropane-formaldehyde resins, preferably those prepared in the presence of an acid catalyst, phenolfurfural resins, and resins from formaldehyde or furfural and toluene sulphonamide, semi-synthetic resins, e.g. ester gum, natural resins, e.g. manila, acaroid resins, pontianak, kauri, dammar, rosin, and shellac, plasticizers, e.g. diphenylol propane, xylene monomethylsulphonamide, toluene o- or m-ethylsulphonamide, fine retardants, e.g. bromtricresyl phosphates, and the usual pigments &c. Solutions comprising a cellulose derivative and a resin prepared as described above may also be used for the manufacture of artificial filaments by dry or wet spinning, or for the manufacture of films. Solutions comprising a resin prepared as described above, with or without a cellulose derivative, may also be used as adhesives, particularly for the manufacture of laminated glass, the intermediate material of which may itself have a basis of cellulose derivative. Solvents that may be used in applying the resins as described above include acetone, ethyl alcohol, benzene, ethylene dichloride, ethyl acetate and lactate, tetrachlorethane, benzyl alcohol, and diacetone alcohol. Examples are given describing: (1) a coating composition containing cellulose acetate, diphenylol-cyclohexane-formaldehyde resin, and acetone; (2) a coating composition containing cellulose acetate, p diphenylol-cyclohexaneformaldehyde resin, acetone, benzene, ethyl alcohol, and ethyl lactate; (3) a coating composition containing cellulose nitrate, diphenylol-cyclohexaneformaldehyde resin, camphor, diethyl phthalate, benzene, ethyl and butyl alcohols, and ethyl and butyl acetates; (4) an adhesive, useful in making laminated glass, containing cellulose acetate, diphenylol-cyclohexane-formaldehyde resin, acetone, and ethyl acetate and lactate; (5) an adhesive, useful in making reinforced glass, comprising cellulose nitrate, a diphenylol-cycloparaffin-formaldehyde resin, camphor, dibutyl phthalate, benzene, ethyl and butyl alcohols, and ethyl and butyl acetates; (6) a plastic composition containing cellulose acetate, diphenylol-cyclohexane-formaldehyde resin, xylene monomethyl sulphonamide, ethyl alcohol, and benzene; (7) a plastic composition containing cellulose acetate, diphenylol-cyclohexane-formaldehyde resin, diphenylol cyclohexane, ethyl alcohol, and benzene; (8) a solution, suitable for making artificial filaments by dry spinning, containing cellulose acetate, diphenylol-cyclohexaneformaldehyde resin, and acetone; (9) a lacquer containing cellulose acetate, diphenylol-cyclohexaneformaldehyde resin, diphenylol propane, acetone, benzene, toluene, ethyl acetate and lactate, and a pigment. The manufacture of products having a basis of cellulose formate, propionate, or butyrate, or of methyl, or benzyl cellulose is referred to.ALSO:Resinous products prepared by condensing a diphenylol cycloparaffin with formaldehyde, in the presence or absence of other synthetic resin components, e.g. diphenylol propane, urea, or toluene sulphonamide, and in the presence or absence of an acid, neutral, or alkaline catalyst, are used as ingredients of compositions having a basis of cellulose ester or ether. Thus, plastic masses &c. may be made from a cellulose ester or ether and a resin prepared as described above; such masses &c. may include also other synthetic resins, e.g. fusible and soluble phenol-formaldehyde or diphenylolpropaneformaldehyde resins, preferably those prepared in the presence of an acid catalyst, phenolfurfural resins, and resins from formaldehyde or furfural and toluene sulphonamide, semi-synthetic resins, e.g. ester gum, natural resins, e.g. manila, acaroid resins pontianak, kauri, dammar, rosin, and shellac, plasticizers, e.g. diphenylol propane xylene, monomethylsulphonamide, toluene o- or m-ethylsulphonamide, fire retardants, e.g. bromtricresyl phosphates, and the usual pigments &c. Solutions comprising a resin prepared as described above, with or without a cellulose derivative, may also be used as adhesives, particularly for the manufacture of laminated glass. Solvents that may be used in so applying the resins include acetone, ethyl alcohol, benzene, ethylene dichloride, ethyl acetate and lactate, tetrachlorethane, benzyl alcohol, and diacetone alcohol. Examples are given describing (1) an adhesive containing cellulose acetate, diphenylolcyclohexane-formaldehyde resin, acetone, and ethyl acetate and lactate; (2) an adhesive comprising cellulose nitrate, a diphenylolcycloparaffin-formaldehyde resin, camphor, dibutyl phthalate, benzene, ethyl and butyl alcohols, and ethyl and butyl acetates; (3) a plastic compositino containing cellulose acetate, diphenylol cyclohexane-formaldehyde resin, xylene monomethyl sulphonamide, ethyl alcohol, and benzene; (4) a plastic composition containing cellulose acetate, diphenylolcyclohexane-formaldehyde resin, diphenyl cyclohexane, ethyl alcohol, and benzene. The manufacture of products having a basis of cellulose formate, propionate, or butyrate, or of methyl, ethyl, or benzyl cellulose is referred to. Specification 342,429 is referred to.
GB35933/29A 1928-11-26 1929-11-23 The manufacture and uses of new synthetic resins Expired GB344413A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US344413XA 1928-11-26 1928-11-26

Publications (1)

Publication Number Publication Date
GB344413A true GB344413A (en) 1931-02-23

Family

ID=21876435

Family Applications (1)

Application Number Title Priority Date Filing Date
GB35933/29A Expired GB344413A (en) 1928-11-26 1929-11-23 The manufacture and uses of new synthetic resins

Country Status (1)

Country Link
GB (1) GB344413A (en)

Similar Documents

Publication Publication Date Title
US2319876A (en) Preparation of aromatic sulphonamide-phenol-dihalide reaction products
US2335701A (en) Coating composition and process of making it
GB344413A (en) The manufacture and uses of new synthetic resins
US1902257A (en) Derivative of cellulose composition
US1840597A (en) Synthetic resin and process of making the same
US2174132A (en) Producing resistant varnish coatings on wood
US1873849A (en) Synthetic resin and process of making the same
US2015083A (en) Synthetic resin and method of preparing the same
US1940727A (en) Resin and coating or plastic composition containing the same
GB340101A (en) New synthetic resins and their uses
GB340102A (en) The manufacture and use of new synthetic resins
GB376839A (en) Improved synthetic resins and their manufacture
US1840596A (en) Synthetic resin and process of making the same
GB365094A (en) Compositions of matter containing synthetic resins and products obtained therefrom
US2038764A (en) Synthetic resin
US1958488A (en) Resin and coating or plastic composition containing the same
US2022389A (en) Resin and coating or plastic composition containing the same
US1907554A (en) Toluene sulphonamide aldehyde resins and method of making the same
US1902256A (en) Coating composition and film produced thereby
GB366586A (en) Compositions of matter containing cellulose derivatives and products obtained therefrom
US1954826A (en) Resin and coating or plastic compositions containing the same
US2041783A (en) Method for producing a synthetic resin
US2079626A (en) Synthetic resin varnishes and synthetic resins
GB368801A (en) Improvements in cellulose derivative compositions
US1963973A (en) Process of preparing rapidly drying coatings