GB340102A - The manufacture and use of new synthetic resins - Google Patents

The manufacture and use of new synthetic resins

Info

Publication number
GB340102A
GB340102A GB35204/29A GB3520429A GB340102A GB 340102 A GB340102 A GB 340102A GB 35204/29 A GB35204/29 A GB 35204/29A GB 3520429 A GB3520429 A GB 3520429A GB 340102 A GB340102 A GB 340102A
Authority
GB
United Kingdom
Prior art keywords
resins
acetone
cellulose
ethyl
toluenesulphonamide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB35204/29A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Acordis UK Ltd
Original Assignee
British Celanese Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by British Celanese Ltd filed Critical British Celanese Ltd
Publication of GB340102A publication Critical patent/GB340102A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G12/00Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
    • C08G12/02Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes
    • C08G12/04Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with acyclic or carbocyclic compounds
    • C08G12/24Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with acyclic or carbocyclic compounds with sulfonic acid amides

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

Resinous products prepared by condensing furfural with an aromatic sulphonamide, e.g. benzenesulphonamide or a toluene- or xylene-sulphonamide, in the presence or absence of other synthetic resin components, e.g. formaldehyde, acetone, urea, phenol, or aniline, are used as ingredients of lacquers and varnishes having a basis of cellulose ester or ether. The lacquers &c. may include also other synthetic resins, e.g. fusible and soluble phenol-formaldehyde resins, diphenylolpropane-formaldehyde resins, preferably those prepared in the presence of an acid catalyst, phenol-furfural resins, and toluenesulphonamide - formaldehyde resins, semi-synthetic resins, e.g. ester gum, natural resins, e.g. acaroid resins, manila, pontianak, kauri, dammar, resin and shellac, plasticisers, e.g. diphenylolpropane, xylenemonomethylsulphonamide, o- or m-tolueneethylsulphonamide, fire-retardents, e.g. bromtricresyl phosphates, and the usual pigments &c. Solvents that may be used in applying the resins as described above include acetone, ethyl alcohol, benzene, ethylene dichloride, ethyl acetate and lactate, tetrachlorethane, benzyl alcohol, and diacetone alcohol. Examples are given describing (1) a coating composition comprising cellulose acetate, toluenesulphonamide-furfural resin, and acetone; (2) a coating composition comprising cellulose acetate, toluenesulphonamide-furfural resin, acetone, benzene, ethyl alcohol, and diacetone alcohol; (3) a coating composition comprising cellulose nitrate, camphor, diethyl phthalate, toluenesulphonamide-furfural resin, benzene, ethyl and butyl alcohols, and ethyl and butyl acetates; (4) a lacquer comprising cellulose acetate, toluenesulphonamide-furfural resin, diphenylolpropane, pigment, acetone, ethyl acetate and lactate, benzene, and toluene. The solvents used may be anhydrous, or a small amount of water may be included, e.g. if a cellulose acetate is used that is more soluble in aqueous acetone than in acetone alone. The manufacture of products having a basis of cellulose formate, propionate, or butyrate, or of methyl, ethyl, or benzyl cellulose is referred to. Specifications 315,807, 315,808, [both in Class 2 (iii), Dyes &c.], and 340,101 also are referred to.ALSO:Condensation products of furfural with aromatic sulphonamides.-Resinous products are prepared by condensing furfural with an aromatic sulphonamide, e.g. benzenesulphonamide or a toluene-or xylenesulphonamide. Complex products may be obtained by including in the reaction mixture other synthetic resin components, e.g. formaldehyde, acetone, urea, phenol, or aniline. The condensation may be effected in the absence of a catalyst or in the presence of an acid or alkaline catalyst. In an example, equimolecular proportions of p-toluenesulphonamide and furfural are heated under reflux at 150 DEG C. in the presence of an alkaline catalyst such as soda ash, and the resinous product is washed with water and dried in the air or by distillation. The products so obtained are useful as ingredients of compositions having a basis of cellulose ester or ether. Thus, lacquers, varnishes, plastic masses &c. may be made from a cellulose ester or ether and a resin prepared as described above; such lacquers &c. may include also other synthetic resins, e.g. fusible and soluble phenolformaldehyde resins, diphenylolpropane-formaldehyde resins, preferably those prepared in the presence of an acid catalyst, phenol-furfural resins, and toluenesulphonamide-formaldehyde resins, semi-synthetic resins, e.g. ester gum, natural resins, e.g. acaroid resins, manila, pontianak, kauri, dammar, rosin, and shellac, plasticizers, e.g. diphenylolpropane, xylenemonomethylsulphonamide, o- or m-tolueneethyl-sulphonamide, fire retardants, e.g. bromtricresyl phosphates, and the usual pigments &c. Solutions comprising a cellulose derivative and a resin prepared as described above may also be used for the manufacture of artificial filaments by dry or wet spinning, or for the manufacture of films, or as adhesives, particularly for the manufacture of laminated glass. Solvents that may be used in applying the resins as described above include acetone, ethyl alcohol, benzene, ethylene dichloride, ethyl acetate and lactate, tetrachlorethane, benzyl alcohol, and diacetone alcohol. Examples are given describing (1) a coating composition comprising cellulose acetate, toluenesulphonamide-furfural resin, and acetone; (2) a coating composition comprising cellulose acetate, toluenesulphonamide-furfural resin, acetone, benzene, ethyl alcohol, and diacetone alcohol; (3) a coating composition comprising cellulose nitrate, camphor, diethyl phthalate, toluenesulphonamide-furfural resin, benzene, ethyl and butyl alcohols, and ethyl and butyl acetates; (4) an adhesive, useful in making laminated glass, comprising cellulose acetate, toluenesulphonamide-furfural resin, acetone, and ethyl acetate and lactate; (5) a like adhesive, comprising cellulose nitrate, camphor, dibutyl phthalate, toluenesulphonamide-furfural resin, benzene, ethyl and butyl alcohols, and ethyl and butyl acetates; (6) a plastic composition comprising cellulose acetate, toluenesulphonamide-furfural resin, xylenemonomethylsulphonamide, ethyl alcohol, and benzene; (7) a solution for the manufacture of artificial filaments by dry spinning comprising cellulose acetate, toluenesulphonamide-furfural resin, and acetone; (8) a lacquer comprising cellulose acetate, toluenesulphonamide-furfural resin, diphenylolpropane, pigment, acetone, ethyl acetate and lactate, benzene, and toluene. The solvents used may be anhydrous, or a small amount of water may be included, e.g. if a cellulose acetate is used that is more soluble in aqueous acetone than in acetone alone. The manufacture of products having a basis of cellulose formate, propionate, or butyrate, or of methyl, ethyl, or benzyl cellulose is referred to. Specifications 315,807, 315,808, [both in Class 2 (iii), Dyes &c.], and 340,101 also are referred to.ALSO:Mixed resinous products are prepared by condensing furfural with an aromatic sulphonamide, e.g. benzenesulphonamide or a toluene- or xylenesulphonamide, in the presence or absence of other synthetic resin components, e.g. formaldehyde, acetone, urea, phenol, or aniline. The condensation may be effected in the absence of a catalyst or in the presence of an acid or alkaline catalyst. The products so obtained are used as ingredients of compositions having a basis of cellulose ester or ether. Thus, plastic masses &c. may be made from a cellulose ester or ether and a resin prepared as described above. Such masses may include also other synthetic resins, e.g. fusible and soluble phenol-formaldehyde resins, diphenylolpropaneformaldehyde resins, preferably those prepared in the presence of an acid catalyst, phenol-furfural resins, and toluenesulphonamide - formaldehyde resins, semi-synthetic resins, e.g. ester gum, natural resins, e.g. acaroid resins, manila, pontianak, kauri, dammar, resin, and shellac, plasticizers, e.g. diphenylolpropane, xylenemonomethylsulphonamide, o- or m-tolueneethylsulphonamide, fire-retardants, e.g. bromtricresyl phosphates, and pigments &c. Solutions comprising a cellulose derivative and a resin prepared as described above may be used as adhesives, particularly for the manufacture of laminated glass. Solvents that may be used in so applying the resins as described above include acetone, ethyl alcohol, benzene, ethylene dichloride, ethyl acetate and lactate, tetrachlorethane, benzyl alcohol, and diacetone alcohol. Examples are given describing adhesives, useful in making laminated glass, comprising (1) cellulose acetate, toluenesulphonamide-furfural resin, acetone, and ethyl acetate and lactate; (2) cellulose nitrate, camphor, dibutyl phthalate, toluenesulphonamidefurfural resin, benzene, ethyl and butyl alcohols, and ethyl and butyl acetates; a plastic composition comprising cellulose acetate, toluenesulphonamide-furfural resin, xylenemonomethylsulphonamide, ethyl alcohol, and benzene. The solvents used may be anhydrous, or a small amount of water may be included, e.g. if a cellulose acetate is used that is more soluble in aqueous acetone than in acetone alone. The manufacture of products having a basis of cellulose formate, propionate, or butyrate, or of methyl, ethyl, or benzyl cellulose is referred to. Specifications 315,807, 315,808, [both in Class 2 (iii), Dyes &c.], and 340,101 also are referred to.
GB35204/29A 1928-11-17 1929-11-18 The manufacture and use of new synthetic resins Expired GB340102A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US340102XA 1928-11-17 1928-11-17

Publications (1)

Publication Number Publication Date
GB340102A true GB340102A (en) 1930-12-24

Family

ID=21873751

Family Applications (1)

Application Number Title Priority Date Filing Date
GB35204/29A Expired GB340102A (en) 1928-11-17 1929-11-18 The manufacture and use of new synthetic resins

Country Status (1)

Country Link
GB (1) GB340102A (en)

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