GB363897A - Manufacture of new cellulose derivatives - Google Patents
Manufacture of new cellulose derivativesInfo
- Publication number
- GB363897A GB363897A GB5417/31A GB541731A GB363897A GB 363897 A GB363897 A GB 363897A GB 5417/31 A GB5417/31 A GB 5417/31A GB 541731 A GB541731 A GB 541731A GB 363897 A GB363897 A GB 363897A
- Authority
- GB
- United Kingdom
- Prior art keywords
- treated
- yarn
- diazo
- amino
- group
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/58—Material containing hydroxyl groups
- D06P3/60—Natural or regenerated cellulose
- D06P3/68—Preparing azo dyes on the material
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B11/00—Preparation of cellulose ethers
- C08B11/02—Alkyl or cycloalkyl ethers
- C08B11/04—Alkyl or cycloalkyl ethers with substituted hydrocarbon radicals
- C08B11/14—Alkyl or cycloalkyl ethers with substituted hydrocarbon radicals with nitrogen-containing groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B15/00—Preparation of other cellulose derivatives or modified cellulose, e.g. complexes
- C08B15/05—Derivatives containing elements other than carbon, hydrogen, oxygen, halogens or sulfur
- C08B15/06—Derivatives containing elements other than carbon, hydrogen, oxygen, halogens or sulfur containing nitrogen, e.g. carbamates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
- D06P1/642—Compounds containing nitrogen
- D06P1/6426—Heterocyclic compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
- D06P1/642—Compounds containing nitrogen
- D06P1/6429—Compounds containing nitrogen bound to a six-membered aromatic carbocyclic ring
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/58—Material containing hydroxyl groups
- D06P3/60—Natural or regenerated cellulose
- D06P3/66—Natural or regenerated cellulose using reactive dyes
- D06P3/663—Natural or regenerated cellulose using reactive dyes reactive group directly attached to heterocyclic group
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/22—Effecting variation of dye affinity on textile material by chemical means that react with the fibre
Abstract
The process of the parent Specification is modified by treating cellulose material such as cotton yarn with a compound containing a N = C-halogen group so as to produce a compound still containing at least one reactive halogen group, and then treating the product with a compound containing an exchangeable hydrogen or equivalent atom and at least one chromophor or group capable of forming a dyestuff or a residue capable of being converted into such a group. The product so obtained may be converted into a dyestuff by diazotizing and coupling with a coupling component, or by coupling with a diazo compound. The dyestuff may be further treated by reduction, condensation, acidylation, alkylation, further coupling with a diazo compound, diazotizing and coupling, treatment with an agent yielding metal, or a combination of two or more of these treatments. The process may be modified by first causing a compound containing at least twice the grouping N = C-halogen to react with a compound containing an exchangeable hydrogen or equivalent atom, and a chromophor or group tending to form a dyestuff or residue capable of conversion into such group, and then causing the product to react with alkali cellulose. The chromophoric substance may be a dyestuff containing amino groups and belonging to the nitro, azo, thiazole, azoxy-stilbene, pyrazolone, hydrazone, arylmethane, acridine, oxyazine, thiazine, azine, aminoanthraquinone, or indigoid group of dyestuffs, or it may be an aminoanthraquinone, aromatic diamine, aminophenol, aminonaphthol, or a derivative of these, or a nitramine, thiophenol, or amino mercaptan. The products containing chromophoric and auxochromic groups may be treated with agents yielding metals such as compounds of chromium, copper, iron, manganese, nickel, cobalt, titanium, or molybdenum. The products may be used for producing coloured effects in mixed fabrics. In an example cotton yarn is impregnated with alcoholic caustic soda and then with cyanuric chloride in xylene. The treated yarn is rinsed and dried. It is then treated with p-diamino-diphenyl-methane in dilute alcohol, diazotized and coupled with b -naphthol. The yarn is dyed yellowish red. Dianisidine may be used as the chromophoric body, and other naphthols or other coupling bodies may be used. In another example, the cyanurated yarn is treated with disodium 1 - amino - 8 - oxynaphthalene-3 : 6-disulphonate, and treated with a diazo solution such as p-nitro-diazo-benzene, diazo-meta-xylene, or diazo compounds of aniline, toluidines, chloranilines and their homologues, anisidines, phenetidines and their mono- and polyhalogen derivatives, naphthylamines, or sulphonic acids or carboxylic acids of these compounds. Instead of the chromophoric body named above, other amino naphthols or naphthalenes or their sulphonic acid compounds may be used. In another example, the cyanurated yarn is treated with an amino-naphthol or sulphonic acid derivative thereof, and then with diazotized anthranilic acid or the diazo derivatives of sulphoanthranilic acid, chlor-aminophenols, nitroaminophenols, picramic acid, or amino-oxy-naphthalene sulphonic acids. In another example, the cyanurated yarn is treated with an aqueous solution of the azo-dyestuff obtained from diazo-xylene and 2-(m-aminobenzoyl) - amino- 5- oxynaphthalen-7-sulphonic acid, or of the dyestuff obtained from tetra-azotized m-aminobenzoyl-m-phenylene diamine and 1-(3-nitro) phenyl-5-pyrazolone-3-carboxylic acid. In another example the cyanurated yarn is treated with an aqueous solution or suspension of p-nitraniline. The yarn is rinsed and the nitro group is reduced with sodium hydrosulphide; the amino group produced is diazotized and coupled with b -naphthol or other naphthol or phenol. This example may be modified by starting with phenylene or naphthylene diamines. In another example, cyanuric chloride dissolved in acetone is introduced into a mixture of p-nitraniline with ice and water. The product is filtered, washed, and dried, and then treated with alkali-cellulose in xylene. The alkali-cellulose is obtained by immersing cotton yarn in aqueous or alcoholic caustic potash or soda. The yellow-dyed yarn is reduced with sodium hydrosulphide, and then diazotized and coupled with b -naphthol, a -naphthol, resorcinol, or m-toluylenediamine. In another example, cotton yarn which has been treated with cyanuric chloride is treated in an aqueous solution of p-rosaniline and then rinsed. The yarn is dyed an intense red. Specification 347,926 is referred to.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CH342167X | 1929-04-11 | ||
CH363897X | 1930-02-21 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB363897A true GB363897A (en) | 1931-12-31 |
Family
ID=25736890
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB5417/31A Expired GB363897A (en) | 1929-04-11 | 1931-02-20 | Manufacture of new cellulose derivatives |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB363897A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2459166A (en) * | 2008-01-25 | 2009-10-21 | Secr Defence | Aminoarylated cellulosic material |
-
1931
- 1931-02-20 GB GB5417/31A patent/GB363897A/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2459166A (en) * | 2008-01-25 | 2009-10-21 | Secr Defence | Aminoarylated cellulosic material |
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