GB331100A - Process for the manufacture of oxygenated organic compounds - Google Patents
Process for the manufacture of oxygenated organic compoundsInfo
- Publication number
- GB331100A GB331100A GB1994429A GB1994429A GB331100A GB 331100 A GB331100 A GB 331100A GB 1994429 A GB1994429 A GB 1994429A GB 1994429 A GB1994429 A GB 1994429A GB 331100 A GB331100 A GB 331100A
- Authority
- GB
- United Kingdom
- Prior art keywords
- oxygen
- ferric oxide
- pressure
- water
- atm
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C47/00—Compounds having —CHO groups
- C07C47/52—Compounds having —CHO groups bound to carbon atoms of six—membered aromatic rings
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
331,100. Carpmael, A., (I. G. Farbenindustrie Akt.-Ges.). June 28, 1929. Oxygenated organic compounds. - Oxygenated organic compounds are prepared by treating aromatic hydrocarbons or their halogenated derivatives in the liquid state and at a raised temperature and pressure with molecular oxygen or a gas containing free oxygen in the presence of a substantial amount of liquid water and a small amount of an oxidation catalyst. Suitable catalysts are the oxides and hydroxides of copper, nickel, cobalt, and iron, and the oxides of manganese, cerium, osmium, uranium, vanadium, chromium, and zinc; mixtures of such catalysts may also be used. The reaction may be modified by effecting it in the presence of carbon dioxide. Examples are given as follows :-(1) toluene is treated with oxygen at 240‹ C. under 60-60 atm. pressure in the presence of water and hydrated ferric oxide (FeO.OH)3; benzaldehyde is obtained, with a little benzoic acid and traces of benzyl alcohol and dibenzyl ether; (2) as in example 1, but using a mixture of hydrated ferric oxide and uranium oxide as catalyst; benzoic acid mainly is obtained, besides the other products specified in example 1; (3) as in example 1, but using air as the oxidant and ferric oxide as catalyst; benzaldehyde and benzoic acid are obtained; (4) as in example 1, but with carbon dioxide present; benzoic acid and some benzaldehyde are obtained; (5) p-xylene is treated with oxygen at 235‹ C. under 60 atm. pressure in the presence of water and hydrated ferric oxide; p-toluic acid and ptoluic aldehyde are obtained; (6) m-xylene is similarly oxidized in the presence of vanadium pentoxide; m-toluic acid and m-toluic aldehyde are obtained, with traces of isophthalic acid; (7) ethylbenzene is treated with oxygen at 170‹ C. under 20 atm. pressure in the presence of water and hydrated ferric oxide; phenyl methyl carbinol, acetophenone, and a little benzoic acid are obtained; (8) naphthalene is treated with a mixture of nitrogen and oxygen at 270‹ C. under 85 atm. pressure in the presence of water, sodium carbonate, and a catalyst comprising hydrated ferric oxide, copper oxide, cerium dioxide, and chromium oxide; benzoic and phthalic acids are ultimately obtained; (9) anthracene is treated with oxygen at 250‹ C. under 60 atm. pressure in the presence of water, sodium carbonate, and a catalyst comprising hydrated ferric oxide and cerium dioxide; anthraquinone is obtained; (10) p-chlortoluene is oxidized as in example 1; p-chlorobenzaldehyde and p-chlorobenzoic acid are obtained.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB1994429A GB331100A (en) | 1929-06-28 | 1929-06-28 | Process for the manufacture of oxygenated organic compounds |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB1994429A GB331100A (en) | 1929-06-28 | 1929-06-28 | Process for the manufacture of oxygenated organic compounds |
Publications (1)
Publication Number | Publication Date |
---|---|
GB331100A true GB331100A (en) | 1930-06-26 |
Family
ID=10137724
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB1994429A Expired GB331100A (en) | 1929-06-28 | 1929-06-28 | Process for the manufacture of oxygenated organic compounds |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB331100A (en) |
-
1929
- 1929-06-28 GB GB1994429A patent/GB331100A/en not_active Expired
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