GB840822A - Improvements in and relating to the production of benzoic acid and substituted derivatives thereof - Google Patents
Improvements in and relating to the production of benzoic acid and substituted derivatives thereofInfo
- Publication number
- GB840822A GB840822A GB1289057A GB1289057A GB840822A GB 840822 A GB840822 A GB 840822A GB 1289057 A GB1289057 A GB 1289057A GB 1289057 A GB1289057 A GB 1289057A GB 840822 A GB840822 A GB 840822A
- Authority
- GB
- United Kingdom
- Prior art keywords
- bromine
- metal
- bromide
- cobalt
- oxidation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/255—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting
- C07C51/265—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting having alkyl side chains which are oxidised to carboxyl groups
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
The invention comprises a process for the preparation of aromatic carboxylic acids by the oxidation in the liquid phase by means of ozone or molecular oxygen, of alkyl aromatic compounds or their closely related oxygenated derivatives at elevated temperature and pressure, using a catalyst comprising a metal of variable valence, in which the proportion of bromine is less than 7.8 X 10-5 but not less than 1 X 10-7 gram atom per gram mol. of starting material. The molecular oxygen may be introduced as such or as air or diluted air. Suitable temperatures are 100-300 DEG C., and pressures up to 50 atmospheres may be used. The process may be carried out in chromium/nickel austenitic or mild steel reactors. Bromine may be introduced as such or as bromide e.g. hydrogen bromide, or a metallic or organic bromide. Metals specified are cobalt, manganese or mixtures thereof, cerium and lead. The concentration of metal may be e.g. 1-0.0005 gram atom per mol. of starting material. The metal may be introduced e.g. as the acetate, nonanoate, propionate or naphthenate, and a solvent e.g. acetic acid, propionic acid or orthodichlorobenzene may be present in the reaction mixture. Starting materials mentioned are monoalkyl benzenes, and their aldehydes, alcohols, esters and hydroperoxide, e.g. toluene ethylbenzene, cumene, n and secbutyl benzene, but not those in which the alkyl group is tertiary. Substituents which may be present in the starting materials are NO2, SO2 and SO2NH2. An example is given of the oxidation of toluene to benzoic acid using various concentrations of cobalt, and bromine in the reaction mixture. Specifications 804,612 and 810,020 are referred to.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB1289057A GB840822A (en) | 1957-04-23 | 1957-04-23 | Improvements in and relating to the production of benzoic acid and substituted derivatives thereof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB1289057A GB840822A (en) | 1957-04-23 | 1957-04-23 | Improvements in and relating to the production of benzoic acid and substituted derivatives thereof |
Publications (1)
Publication Number | Publication Date |
---|---|
GB840822A true GB840822A (en) | 1960-07-13 |
Family
ID=10013014
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB1289057A Expired GB840822A (en) | 1957-04-23 | 1957-04-23 | Improvements in and relating to the production of benzoic acid and substituted derivatives thereof |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB840822A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106631761A (en) * | 2016-09-12 | 2017-05-10 | 华东理工大学 | Method for preparing benzoic acid by oxidizing methylbenzene at atmospheric pressure and low temperature |
-
1957
- 1957-04-23 GB GB1289057A patent/GB840822A/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106631761A (en) * | 2016-09-12 | 2017-05-10 | 华东理工大学 | Method for preparing benzoic acid by oxidizing methylbenzene at atmospheric pressure and low temperature |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US2479067A (en) | Preparation of terephthalic acid | |
GB983677A (en) | A process for the preparation of terephthalic acid having extremely high purity | |
GB878802A (en) | Production of unsaturated aliphatic aldehydes and the corresponding acids | |
US1815985A (en) | Process for the manufacture of oxygenated organic compounds | |
US2853514A (en) | Process for the preparation of aromatic carboxylic acids | |
GB655074A (en) | An improved process for the preparation of terephthalic acid | |
GB840822A (en) | Improvements in and relating to the production of benzoic acid and substituted derivatives thereof | |
US2928879A (en) | Oxidation of hydrocarbons with sulfur dioxides | |
GB864803A (en) | Process for the manufacture of percarboxylic acids | |
US3064043A (en) | Oxidation of organic compounds | |
EP0041784A1 (en) | Oxidation of substituted aromatic compounds to aromatic carboxylic acids | |
US3584038A (en) | Oxidative treatment of mononuclear aromatic compounds | |
ES8104178A1 (en) | Process for preparing benzoic acid. | |
Hromec et al. | Oxidation of polyalkylaromatic hydrocarbons. 12. Technological aspects of p-xylene oxidation to terephthalic acid in water | |
US3739017A (en) | Oxidation of ethylene acetals of aromatic aldehydes | |
GB833440A (en) | Preparation of aromatic carboxylic acids | |
GB804612A (en) | Process for the oxidation of organic compounds | |
US3637829A (en) | Liquid phase oxidation of mononuclear aromatic compounds | |
US2821552A (en) | Oxidation of hydrocarbons with sulfur dioxides | |
GB907926A (en) | Improvements in or relating to the production of trimellitic acid and trimellitic anhydride | |
GB841053A (en) | Improvements in and relating to the oxidation of organic compounds | |
GB1423042A (en) | Preparation of monomethyl terephthalate and dimethyl tereph thalate | |
US3502718A (en) | Process involving oxidation | |
US3714243A (en) | Promotion of the oxidation of mono-nuclear aromatic compounds | |
US3723518A (en) | Promotion of the oxidation of mononuclear aromatic compounds |