GB313135A - Improvements relating to the treatment of metals with acid liquids - Google Patents
Improvements relating to the treatment of metals with acid liquidsInfo
- Publication number
- GB313135A GB313135A GB17551/29A GB1755129A GB313135A GB 313135 A GB313135 A GB 313135A GB 17551/29 A GB17551/29 A GB 17551/29A GB 1755129 A GB1755129 A GB 1755129A GB 313135 A GB313135 A GB 313135A
- Authority
- GB
- United Kingdom
- Prior art keywords
- tetramethyldiaminodiphenylmethane
- hydrochloride
- leuco
- acid
- mixed
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000007788 liquid Substances 0.000 title abstract 4
- 239000002184 metal Substances 0.000 title abstract 4
- 229910052751 metal Inorganic materials 0.000 title abstract 4
- 239000002253 acid Substances 0.000 title abstract 3
- 150000002739 metals Chemical class 0.000 title abstract 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 abstract 5
- 229920002678 cellulose Polymers 0.000 abstract 2
- 239000001913 cellulose Substances 0.000 abstract 2
- 230000004907 flux Effects 0.000 abstract 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 abstract 2
- 238000005554 pickling Methods 0.000 abstract 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 abstract 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 abstract 1
- OAZWDJGLIYNYMU-UHFFFAOYSA-N Leucocrystal Violet Chemical compound C1=CC(N(C)C)=CC=C1C(C=1C=CC(=CC=1)N(C)C)C1=CC=C(N(C)C)C=C1 OAZWDJGLIYNYMU-UHFFFAOYSA-N 0.000 abstract 1
- WZKXBGJNNCGHIC-UHFFFAOYSA-N Leucomalachite green Chemical compound C1=CC(N(C)C)=CC=C1C(C=1C=CC(=CC=1)N(C)C)C1=CC=CC=C1 WZKXBGJNNCGHIC-UHFFFAOYSA-N 0.000 abstract 1
- 238000007792 addition Methods 0.000 abstract 1
- 125000003277 amino group Chemical group 0.000 abstract 1
- XEPQAISLFOVRTP-UHFFFAOYSA-N bis(2-methylphenyl)methanediamine Chemical compound CC1=CC=CC=C1C(N)(N)C1=CC=CC=C1C XEPQAISLFOVRTP-UHFFFAOYSA-N 0.000 abstract 1
- 238000004140 cleaning Methods 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 150000004985 diamines Chemical class 0.000 abstract 1
- GBKRIASALFFVLI-UHFFFAOYSA-N dinaphthalen-1-ylmethanediamine Chemical compound NC(C1=CC=CC2=CC=CC=C12)(C1=CC=CC2=CC=CC=C12)N GBKRIASALFFVLI-UHFFFAOYSA-N 0.000 abstract 1
- ZZTCPWRAHWXWCH-UHFFFAOYSA-N diphenylmethanediamine Chemical compound C=1C=CC=CC=1C(N)(N)C1=CC=CC=C1 ZZTCPWRAHWXWCH-UHFFFAOYSA-N 0.000 abstract 1
- 229910052500 inorganic mineral Inorganic materials 0.000 abstract 1
- 150000002576 ketones Chemical class 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 239000011707 mineral Substances 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 125000001453 quaternary ammonium group Chemical group 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 238000005476 soldering Methods 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- 238000006467 substitution reaction Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/02—Cleaning or pickling metallic material with solutions or molten salts with acid solutions
- C23G1/04—Cleaning or pickling metallic material with solutions or molten salts with acid solutions using inhibitors
- C23G1/06—Cleaning or pickling metallic material with solutions or molten salts with acid solutions using inhibitors organic inhibitors
- C23G1/065—Cleaning or pickling metallic material with solutions or molten salts with acid solutions using inhibitors organic inhibitors sulfur-containing compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
- Detergent Compositions (AREA)
Abstract
313,135. Soc. of Chemical Industry in Basle. June 7, 1928, [Convention date]. Pickling; fluxes.-Bases of the di- and triarylmethane series are added, alone or mixed together or mixed with mineral salts, sulphite cellulose liquor, a sulphonated oil, a mono- or unsymmetrical di-acylated diamine and the corresponding ammonium bases, or sulphonated tar products, to acid liquids for cleaning metal from rust, scale, &c. for use in pickling baths or as liquid soldering fluxes. Diaminodiphenylmethane, diaminoditolylmethane, diaminodinaphthylmethane, the corresponding symmetrical and unsymmetrical primary or secondary N-substitution products, for example 4:4<1>-tetramethyldiaminodiphenylmethane, the corresponding ketones as 4 : 4<1>-tetramethyldiaminobenzophenone, 3 : 3<1> - diamino-4 : 4' - dimethyldiphenylmethane, and the leuco compounds of the triarylmethane dyestuffs containing amino-groups, such as leuco-crystal violet or leuco malachite green, or the corresponding quaternary ammonium bases of any of the above, are referred to. As examples of the process, 1000 parts by weight of 15 per cent hydrochloric acid may be mixed with 0.2 part of the hydrochloride of 4 : 4<1>-tetramethyldiaminodiphenylmethane. or with 0.1 part of the hydrochloride of 3 : 3<1>-diamino-4 : 4'-dimethyldiphenylmethane, or with a mixture of 0.1 part of the hydrochloride of 4 : 4<1>-tetramethyldiaminodiphenylmethane and 0.9 part of sulphite cellulose liquor, and the resulting liquids used at once, either hot or cold, for treating metals. The additions lessen the extent to which the metal is attacked without affecting the solvent action of the acid for rust and oxide.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH313135X | 1928-06-07 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB313135A true GB313135A (en) | 1930-04-24 |
Family
ID=4495074
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB17551/29A Expired GB313135A (en) | 1928-06-07 | 1929-06-07 | Improvements relating to the treatment of metals with acid liquids |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US1778634A (en) |
| BE (1) | BE361181A (en) |
| FR (1) | FR676096A (en) |
| GB (1) | GB313135A (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2450861A (en) * | 1945-04-16 | 1948-10-05 | Dow Chemical Co | Composition for descaling ferrous metal |
-
0
- BE BE361181D patent/BE361181A/xx unknown
-
1929
- 1929-06-03 FR FR676096D patent/FR676096A/en not_active Expired
- 1929-06-04 US US368426A patent/US1778634A/en not_active Expired - Lifetime
- 1929-06-07 GB GB17551/29A patent/GB313135A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| BE361181A (en) | |
| FR676096A (en) | 1930-02-18 |
| US1778634A (en) | 1930-10-14 |
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