GB309224A - Improvements in the manufacture of photoelectric cells - Google Patents

Improvements in the manufacture of photoelectric cells

Info

Publication number
GB309224A
GB309224A GB57928A GB57928A GB309224A GB 309224 A GB309224 A GB 309224A GB 57928 A GB57928 A GB 57928A GB 57928 A GB57928 A GB 57928A GB 309224 A GB309224 A GB 309224A
Authority
GB
United Kingdom
Prior art keywords
solution
copper
cell
grams
washed
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB57928A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
General Electric Co PLC
Original Assignee
General Electric Co PLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by General Electric Co PLC filed Critical General Electric Co PLC
Priority to GB57928A priority Critical patent/GB309224A/en
Priority to FR664791D priority patent/FR664791A/en
Priority to DEG75239D priority patent/DE586227C/en
Publication of GB309224A publication Critical patent/GB309224A/en
Expired legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J40/00Photoelectric discharge tubes not involving the ionisation of a gas
    • H01J40/02Details
    • H01J40/04Electrodes
    • H01J40/06Photo-emissive cathodes

Abstract

309,224. General Electric Co., Ltd., and Campbell, N. R. Jan. 7, 1928. Addition to 306,996. Vacuum tubes.-A photo-electric cell having a red-sensitive cathode according to the parent Specification, is filled with hydrogen. Constancy of the hydrogen filling may be ensured by providing a palladium tube in the cell. The support for the sensitive film is of a metal other than silver or platinum, and is preferably copper or zinc. A preliminary layer of silver, formed on the bottom of the cell, is washed, dried, and heated to 100‹ C. for 15 minutes. The cell is then supported with the silvered coating vertical and is filled with a coppering solution. A current of about 2 milliamperes per square centimetre is passed through the solution for 15 minutes, with a copper wire as anode and the silvered coating as cathode. The conditions should be adjusted so that the copper surface is a matt chocolate brown. The cell is washed, dried, and baked for a few minutes at 300‹ C. so as to oxidize the surface of the copper. The film of potassium is formed as described in the parent Specification, and hydrogen is admitted. The coppering solution is formed by preparing freshly precipitated copper carbonate by adding a solution of 400 grams of crystallized copper sulphate in 2 litres of water to a solution of 100 grams of anhydrous potassium carbonate in 1 litre of water. The mixed solution is allowed to stand for one hour and the precipitate is filtered off and washed. The precipitated copper carbonate is gradually added in excess to 60 grams of acid potassium tartrate dissolved in 1 litre of boiling water. The solution is filtered and allowed to stand for several days until the deposition of a blue precipitate ceases or becomes very slow. Specification 291,763 also is referred to.
GB57928A 1928-01-07 1928-01-07 Improvements in the manufacture of photoelectric cells Expired GB309224A (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
GB57928A GB309224A (en) 1928-01-07 1928-01-07 Improvements in the manufacture of photoelectric cells
FR664791D FR664791A (en) 1928-01-07 1928-11-28 Improvements in the manufacture of photoelectric cells
DEG75239D DE586227C (en) 1928-01-07 1929-01-06 Photoelectric, red-sensitive cell, the cathode of which consists of an approximately monomolecular, practically invisible thin skin of photoelectric substance on a metal layer

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB57928A GB309224A (en) 1928-01-07 1928-01-07 Improvements in the manufacture of photoelectric cells

Publications (1)

Publication Number Publication Date
GB309224A true GB309224A (en) 1929-04-08

Family

ID=584966

Family Applications (1)

Application Number Title Priority Date Filing Date
GB57928A Expired GB309224A (en) 1928-01-07 1928-01-07 Improvements in the manufacture of photoelectric cells

Country Status (3)

Country Link
DE (1) DE586227C (en)
FR (1) FR664791A (en)
GB (1) GB309224A (en)

Also Published As

Publication number Publication date
FR664791A (en) 1929-09-07
DE586227C (en) 1933-10-19

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