GB2434196A - Heating module and system controller for increasing the efficiency of heat pumps - Google Patents

Heating module and system controller for increasing the efficiency of heat pumps Download PDF

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Publication number
GB2434196A
GB2434196A GB0602909A GB0602909A GB2434196A GB 2434196 A GB2434196 A GB 2434196A GB 0602909 A GB0602909 A GB 0602909A GB 0602909 A GB0602909 A GB 0602909A GB 2434196 A GB2434196 A GB 2434196A
Authority
GB
United Kingdom
Prior art keywords
water
refrigerant
heat
heating module
heat exchanger
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
GB0602909A
Other versions
GB0602909D0 (en
Inventor
Martin Hook
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
GLOBAL ENVIRONMENTAL SOLUTIONS LIMITED
Original Assignee
GLOBAL ENVIRONMENTAL SOLUTIONS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by GLOBAL ENVIRONMENTAL SOLUTIONS filed Critical GLOBAL ENVIRONMENTAL SOLUTIONS
Publication of GB0602909D0 publication Critical patent/GB0602909D0/en
Publication of GB2434196A publication Critical patent/GB2434196A/en
Withdrawn legal-status Critical Current

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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24DDOMESTIC- OR SPACE-HEATING SYSTEMS, e.g. CENTRAL HEATING SYSTEMS; DOMESTIC HOT-WATER SUPPLY SYSTEMS; ELEMENTS OR COMPONENTS THEREFOR
    • F24D17/00Domestic hot-water supply systems
    • F24D17/02Domestic hot-water supply systems using heat pumps
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24DDOMESTIC- OR SPACE-HEATING SYSTEMS, e.g. CENTRAL HEATING SYSTEMS; DOMESTIC HOT-WATER SUPPLY SYSTEMS; ELEMENTS OR COMPONENTS THEREFOR
    • F24D3/00Hot-water central heating systems
    • F24D3/18Hot-water central heating systems using heat pumps
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24HFLUID HEATERS, e.g. WATER OR AIR HEATERS, HAVING HEAT-GENERATING MEANS, e.g. HEAT PUMPS, IN GENERAL
    • F24H4/00Fluid heaters characterised by the use of heat pumps
    • F24H4/02Water heaters
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25BREFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B30/00Heat pumps
    • F25B30/02Heat pumps of the compression type
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25BREFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B2339/00Details of evaporators; Details of condensers
    • F25B2339/04Details of condensers
    • F25B2339/047Water-cooled condensers
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25BREFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B2600/00Control issues
    • F25B2600/02Compressor control
    • F25B2600/025Compressor control by controlling speed
    • F25B2600/0253Compressor control by controlling speed with variable speed
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25BREFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B2700/00Sensing or detecting of parameters; Sensors therefor
    • F25B2700/19Pressures
    • F25B2700/193Pressures of the compressor
    • F25B2700/1931Discharge pressures
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25BREFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B2700/00Sensing or detecting of parameters; Sensors therefor
    • F25B2700/21Temperatures
    • F25B2700/2115Temperatures of a compressor or the drive means therefor
    • F25B2700/21152Temperatures of a compressor or the drive means therefor at the discharge side of the compressor
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25BREFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B2700/00Sensing or detecting of parameters; Sensors therefor
    • F25B2700/21Temperatures
    • F25B2700/2116Temperatures of a condenser
    • F25B2700/21161Temperatures of a condenser of the fluid heated by the condenser
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02BCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
    • Y02B30/00Energy efficient heating, ventilation or air conditioning [HVAC]
    • Y02B30/70Efficient control or regulation technologies, e.g. for control of refrigerant flow, motor or heating
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02BCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
    • Y02B40/00Technologies aiming at improving the efficiency of home appliances, e.g. induction cooking or efficient technologies for refrigerators, freezers or dish washers

Landscapes

  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Heat-Pump Type And Storage Water Heaters (AREA)

Abstract

A heating module 1 contains a primary 5 and a secondary 4 refrigerant to water heat exchanger, a modulated variable flow rate water pump 7, and an electronically operated system controller 2. The refrigerant enters the heating module and passes through the primary heat exchanger where the sensible heat of the refrigerant vapour is absorbed. The refrigerant vapour then passes through the secondary heat exchanger where it condenses and gives out heat energy. The water enters the secondary heat exchanger where it absorbs the heat energy given out by the refrigerant as it condenses. This heated water then passes through the primary heat exchanger where it is heated further by absorbing the sensible heat from the superheated refrigerant vapour. An existing heat pump outdoor evaporator unit 3 comprises an evaporator, an expansion valve, a fan and a compressor. The controller controls compressor speed, refrigerant flow, pressure in the existing outdoor unit, and modulates the water flow through the heat exchangers in the heating module. The controller may include an auto defrost start/stop sensor which measures ice build up on the outdoor heat exchange coil. The controller may also be set to activate an additional water heater in a water tank to eliminate Legionella bacteria. The heating module when attached or incorporated into the design of an existing air to refrigerant heat pump outdoor unit is designed to increase the efficiency of the system, reduce operating head pressure, reduce re-heat times, and provide higher water temperatures than formerly obtained for domestic hot water or heating.

Description

<p>A Heating Module and System Controller that Increases the Efficiency of
Heat Pumps for Domestic Hot Water and Heating.</p>
<p>Background</p>
<p>This invention relates to a Heating Module and System Controller designed to increase the efficiency of heat pumps for domestic hot water and heating Until recently, R22 has been the refrigerant used in heat pumps to heat water but maximum temperatures have been limited and an extra heat source has been required to achieve a satisfactory water temperature. Also, R22 has a relatively high evaporating temperature, which means that R22 air to water heat pumps are unable to operate efficiently during UK winter months.</p>
<p>R4 I 0A heat pumps give relatively high COPs even at low ambient conditions and evaporating temperatures down to -20 degrees C are possible. This much lower evaporating temperature has meant that air to air heat pump systems can run efficiently all year round.</p>
<p>Tests already conducted by myself have proved that an R4 1 OA heat pump can supply adequate air to air heating throughout the winter. Further tests that I have conducted have proved that substantial water temperatures can be obtained from an R4 1 0A air to water system.</p>
<p>However, to obtain these high temperatures, pressures in the system rose above 36 bar g. Long term operation at these high pressures would substantially reduce the life of the system.</p>
<p>Similar tests that I have conducted using an inverter drive compressor have failed to produce a water temperature that would be high enough for domestic hot water. This is because the inverter drive system controls limit head pressure by controlling compressor speed.</p>
<p>Statement of Invention</p>
<p>To overcome the above problem of refrigerant pressure increase as water temperature increases the present invention proposes the control of the condensing refrigerant to a sustainable pressure whilst also providing an increase in water temperature.</p>
<p>Condensing pressure is stabilised by passing the refrigerant through a primary refrigerant to water heat exchanger where superheat is extracted. The refrigerant then passes in to the secondary heat exchanger where condensation and sub cooling of the refrigerant takes place.</p>
<p>These heat exchangers can be plate or coaxial type, where heated water can be circulated through a primary and secondary water tank, or direct refrigerant to water heat exchangers can be around or inside the tanks.</p>
<p>Also, to overcome the problem of high condensing pressure, a System Controller modulates the flow of both water and refrigerant as the water temperature increases.</p>
<p>The System Controller monitors ice build up on the outside coil and allows for defrost on demand, thus limiting defrost time.</p>
<p>A third heat exchanger can be built into the system to allow waste domestic hot water to pre heat the stored domestic water, thus reducing reheat time.</p>
<p>Advantages The proposed invention can control the flow of the primary and secondary heat carrying fluid i.e. the refrigerant and the water, so that the operating pressure of the refrigerant can be reduced with a subsequent gain in performance. This allows an R4 1 OA air to water heating system to provide hot water at an increased temperature while ensuring long term reliability.</p>
<p>The proposed invention overcomes this problem of high discharge pressure whilst also providing increased water temperature and an increase in compressor efficiency in an air to water heating system.</p>
<p>As well as a direct refrigerant to water system that would be installed by a refrigeration engineer a system with plate or coaxial heat exchangers allows the refrigerant to be contained in a packaged system where the only connections required to be made by the installer are water connections.</p>
<p>A 16 amp electrical supply is required.</p>
<p>No adjustments are required to be performed by the installer.</p>
<p>Re heat times for 150 litre cylinders can vary between 15 minutes and one hour, depending on the size of outdoor unit.</p>
<p>The same system can be used to supply hot water for a heating as well as domestic hot water.</p>
<p>Example</p>
<p>An Example of the invention will now be described by referring to the accompanying drawings on pages 1/4, 2/4,3/4 and 4/4.</p>
<p>Figure 1 shows an existing heat pump Outdoor Evaporator Unit (3), which contains an Evaporator, Expansion Valve, Fan and Compressor. Added to this are the Heating Module (1) and System Controller (2) a primary Heat Exchanger ( 5), a secondary Heat Exchanger (4), a water Modulating Valve ( 6) and a Water Pump ( 7). In Figure 1 these are all enclosed in the Module (1). Also shown are domestic water supply and return ( 8) and ( 9) and the signal wires from the Controller, (10), (11) and (12).</p>
<p>Figure 2 shows the components of figure 1 with Primary and Secondary Heat Exchangers (5) and (4) fitted inside the Water Tanks (15 and 16) in a design which can be used for an air to refrigerant or a geothermal heat pump with a water to refrigerant Evaporator.</p>
<p>Figure 3 shows an existing heat pump (3) linked to a combined primary and secondary direct refrigerant to water heat exchangers (4 and 5) in a primary water tank (15) and second primary heat exchanger (5) in a secondary water tank (16) In Figure 1, the Controller ( 2) monitors Water Tank and Domestic Hot Water temperature, set temperature and refrigerant discharge pressure / temperature. Using this information the Controller sends a signal to the existing outdoor unit (3) and modulates the compressor cycles and the electronic expansion valve thus altering the amount of refrigerant passing through the system but also, most importantly, controlling the refrigerant pressure. The Controller uses a transducer to measure discharge pressure and sends a signal to inverter to control the compressor operating pressure.</p>
<p>In systems using hot water coils in the water tanks as in figure 2, the Controller also sends a signal to the Heating Module (1) which changes the settings on the modulating valves (6) and on the water pump ( 7) thus ensuring maximum heat exchange by adjusting the flow rate of both refrigerant and water whilst maintaining the minimum and maximum temperature difference between the two.</p>
<p>When the system starts up the refrigerant in the existing outdoor unit ( 3) passes through the existing expansion device which controls the pressure and temperature of evaporation. The refrigerant gains heat from the outside air as it boils off in the outdoor Evaporator. The refrigerant changes into a vapour and is superheated. The Compressor then raises the temperature and pressure of the refrigerant vapour.</p>
<p>Example continued</p>
<p>In Figure 1, the refrigerant vapour then enters the Heating Module (1), and passes through the primary high pressure Heat Exchanger ( 5) where the sensible heat of the refrigerant vapour is absorbed. The refrigerant vapour now enters the second component of the Heating Module, the secondary high pressure Heat Exchanger (4) where it condenses and gives off the heat energy gained from the outside air, to the water flowing through this Heat Exchanger. In a direct refrigerant to water heat exchanger these heat exchangers are around or within the water tanks.</p>
<p>Still in the Heating Module (1), the water enters the secondary Heat Exchanger ( 4) where it absorbs the heat energy from the refrigerant as it condenses.</p>
<p>This heated water, at a temperature just below the condensing temperature of the refrigerant, then passes through the primary Heat Exchanger ( 5) where it is heated further by absorbing sensible heat from the superheated refrigerant vapour.</p>
<p>In Figures 2 and 3, where the heating modules are in or around the water tanks, the two heat exchangers can be utilised together to provide a fast reheat time until the water temperature is just below the normal operating condensing temperature and then, by means of the Modulating Valve (6), work separately, in separate water tanks (15 and 16), to increase the water temperature by absorbing the higher sensible heat from the refrigerant discharge vapour.</p>
<p>In this way the greatest heat input into the water is provided by the refrigerant changing state as it condenses in the secondary Heat Exchanger (4) while a sufficient amount of sensible heat is absorbed by the water as it passes through the primary Heat Exchanger ( 5) thus raising the water leaving temperature without increasing refrigerant discharge pressure.</p>
<p>The Controller (2), as well as controlling compressor speed, refrigerant flow and pressure in the existing outdoor unit, also modulates the water flow through the Heat Exchangers in the Heating Module (1). In this way the correct temperature difference between refrigerant and water is maintained.</p>
<p>As the temperature of the water in the tank rises the Controller (2) modulates the refrigerant flow and the water flow through the Heat Exchangers (4) and (5), again to maximise heat exchange with minimum discharge pressure.</p>
<p>In the systems where the heat exchangers or the heating module are on or in the water tanks, when a preset temperature is obtained in the primary tank the Controller will switch the primary heat exchanger to operate in the secondary tank. In this way water in the secondary tank will heat to a higher temperature then the primary tank.</p>
<p>Example continued</p>
<p>The Controller will normally be fitted to a system using an inverter drive compressor but a non inverter drive compressor can also be utilised. On a standard, non inverter drive compressor the Controller modulates the refrigerant, Water Pump (7) and the Water Modulator Valve (6), which allows evaporating temperature to increase while maintaining a low discharge pressure.</p>
<p>Temperatures between 65 and 75 degrees C have been obtained in tests.</p>
<p>If required, the Controller ( 2) can be set to activate an additional water heater in the water tank to eliminate Legionella bacteria when very low temperature ambient conditions cause a drop in the system COP. This will have little impact on system running costs due to the high efficiency of the system at all other times.</p>
<p>The Controller (2) can also include an auto defrost startlstop sensor which measures ice build up on the outdoor heat exchange coil. This can be activated by pressure or infra red sensor and further improves system efficiency by providing the minimum defrost time.</p>
<p>By diverting waste hot water through the Heating Module (1) the heat exchanger can be utilised to preheat water.</p>
<p>Figure 4 shows how the Controller adjusts discharge pressure as water temperature increases.</p>

Claims (1)

  1. <p>Claims 1. A Heating Module containing a primary and secondary
    refrigerant to water heat exchanger, a modulated variable flow water pump and an electronically operated system controller.</p>
    <p>2. A System Controller as above with the primary and secondary heat exchangers immersed inside the water tanks.</p>
    <p>3. A Heating Module and System Controller, as claim I with an additional water flow regulator fitted between the secondary and primary heat exchangers.</p>
    <p>4. A Heating Module and System Controller as claims 1 and 2 with an automatic defrost sensor fitted to the existing outdoor heat exchanger.</p>
    <p>5. A Heating Module and System Controller as claim 4 with a refrigerant bypass for capacity! head pressure control on applications using a standard drive compressor.</p>
    <p>6. A Heating Module and System Controller as claims 1 and 2 with a bypass valve to allow for heat recovery from waste hot water.</p>
GB0602909A 2005-12-21 2006-02-14 Heating module and system controller for increasing the efficiency of heat pumps Withdrawn GB2434196A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GBGB0525969.2A GB0525969D0 (en) 2005-12-21 2005-12-21 A heating module and controller that increases the efficiency of heat pumps for domestic hot water and under floor heating

Publications (2)

Publication Number Publication Date
GB0602909D0 GB0602909D0 (en) 2006-03-22
GB2434196A true GB2434196A (en) 2007-07-18

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GBGB0525969.2A Ceased GB0525969D0 (en) 2005-12-21 2005-12-21 A heating module and controller that increases the efficiency of heat pumps for domestic hot water and under floor heating
GB0602909A Withdrawn GB2434196A (en) 2005-12-21 2006-02-14 Heating module and system controller for increasing the efficiency of heat pumps

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GBGB0525969.2A Ceased GB0525969D0 (en) 2005-12-21 2005-12-21 A heating module and controller that increases the efficiency of heat pumps for domestic hot water and under floor heating

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009094691A1 (en) * 2008-01-30 2009-08-06 Dux Manufacturing Limited Methods and apparatuses for operating heat pumps in hot water systems
CN104266352A (en) * 2014-08-08 2015-01-07 王盛洪 Multifunctional high-efficiency sewage heat recovery type hot water system
CN104344551A (en) * 2013-08-08 2015-02-11 李显斌 Air energy water heater, method for preventing frost formation and method for defrosting
CN104832970A (en) * 2015-04-24 2015-08-12 珠海格力电器股份有限公司 Absorption-type heat exchanger unit
CN104848325A (en) * 2015-04-24 2015-08-19 珠海格力电器股份有限公司 Absorption heat pump type heat exchanger unit
CN104879818A (en) * 2015-04-24 2015-09-02 珠海格力电器股份有限公司 Heat exchange unit
GB2582137B (en) * 2019-03-11 2023-10-04 Icax Ltd Heat pump system

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111465812A (en) * 2018-03-12 2020-07-28 株式会社Uacj Heat exchanger for refrigerator

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3989183A (en) * 1973-12-20 1976-11-02 Projectus Industripdukter Ab Method and apparatus employing a heat pump for heating fluids in different flow circuits
JP2002228258A (en) * 2001-02-06 2002-08-14 Toshiba Kyaria Kk Heat pump water heater
US6729151B1 (en) * 1999-09-24 2004-05-04 Peter Forrest Thompson Heat pump fluid heating system

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3989183A (en) * 1973-12-20 1976-11-02 Projectus Industripdukter Ab Method and apparatus employing a heat pump for heating fluids in different flow circuits
US6729151B1 (en) * 1999-09-24 2004-05-04 Peter Forrest Thompson Heat pump fluid heating system
JP2002228258A (en) * 2001-02-06 2002-08-14 Toshiba Kyaria Kk Heat pump water heater

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101932892B (en) * 2008-01-30 2012-10-24 达克斯制造有限公司 Methods and apparatuses for operating heat pumps in hot water systems
AU2008349147B2 (en) * 2008-01-30 2013-11-28 Dux Manufacturing Limited Methods and apparatuses for operating heat pumps in hot water systems
WO2009094691A1 (en) * 2008-01-30 2009-08-06 Dux Manufacturing Limited Methods and apparatuses for operating heat pumps in hot water systems
CN104344551B (en) * 2013-08-08 2017-11-21 广州万居隆电器有限公司 The method of air-source water heater and pre- antifrost, the method for defrosting
CN104344551A (en) * 2013-08-08 2015-02-11 李显斌 Air energy water heater, method for preventing frost formation and method for defrosting
CN104266352A (en) * 2014-08-08 2015-01-07 王盛洪 Multifunctional high-efficiency sewage heat recovery type hot water system
CN104266352B (en) * 2014-08-08 2017-02-08 深圳渥特思能源有限公司 Multifunctional high-efficiency sewage heat recovery type hot water system
CN104848325A (en) * 2015-04-24 2015-08-19 珠海格力电器股份有限公司 Absorption heat pump type heat exchanger unit
CN104879818A (en) * 2015-04-24 2015-09-02 珠海格力电器股份有限公司 Heat exchange unit
CN104832970A (en) * 2015-04-24 2015-08-12 珠海格力电器股份有限公司 Absorption-type heat exchanger unit
CN104879818B (en) * 2015-04-24 2018-03-30 珠海格力电器股份有限公司 Heat-exchange unit
CN104832970B (en) * 2015-04-24 2018-07-10 珠海格力电器股份有限公司 Absorption heat exchange unit
GB2582137B (en) * 2019-03-11 2023-10-04 Icax Ltd Heat pump system

Also Published As

Publication number Publication date
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GB0602909D0 (en) 2006-03-22

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Owner name: GLOBAL ENVIRONMENTAL SOLUTIONS LIMITED

Free format text: FORMER APPLICANT(S): HOOK, MARTIN

732E Amendments to the register in respect of changes of name or changes affecting rights (sect. 32/1977)
WAP Application withdrawn, taken to be withdrawn or refused ** after publication under section 16(1)