GB2365858A - Process for producing a lithium transition metal sulphide - Google Patents

Process for producing a lithium transition metal sulphide

Info

Publication number
GB2365858A
GB2365858A GB0128324A GB0128324A GB2365858A GB 2365858 A GB2365858 A GB 2365858A GB 0128324 A GB0128324 A GB 0128324A GB 0128324 A GB0128324 A GB 0128324A GB 2365858 A GB2365858 A GB 2365858A
Authority
GB
United Kingdom
Prior art keywords
transition metal
lithium transition
producing
lithium
sulphide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
GB0128324A
Other versions
GB0128324D0 (en
GB2365858B (en
Inventor
Andrew Grahame Ritchie
Peter George Bowles
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Qinetiq Ltd
Original Assignee
Qinetiq Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Qinetiq Ltd filed Critical Qinetiq Ltd
Publication of GB0128324D0 publication Critical patent/GB0128324D0/en
Publication of GB2365858A publication Critical patent/GB2365858A/en
Application granted granted Critical
Publication of GB2365858B publication Critical patent/GB2365858B/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/581—Chalcogenides or intercalation compounds thereof
    • H01M4/5815—Sulfides
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G23/00—Compounds of titanium
    • C01G23/002—Compounds containing, besides titanium, two or more other elements, with the exception of oxygen or hydrogen
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G33/00—Compounds of niobium
    • C01G33/006—Compounds containing, besides niobium, two or more other elements, with the exception of oxygen or hydrogen
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G39/00—Compounds of molybdenum
    • C01G39/006—Compounds containing, besides molybdenum, two or more other elements, with the exception of oxygen or hydrogen
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G49/00—Compounds of iron
    • C01G49/009—Compounds containing, besides iron, two or more other elements, with the exception of oxygen or hydrogen
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/581—Chalcogenides or intercalation compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/80—Compositional purity
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M2004/026—Electrodes composed of, or comprising, active material characterised by the polarity
    • H01M2004/028—Positive electrodes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Abstract

A process for the production of a lithium transition metal sulphide such as lithium iron sulphide, the process comprising reacting a transition metal sulphide with lithium sulphide in a solvent comprising molten sulphur. Lithium transition metal sulphides obtained using this process are also claimed and are useful in the production of electrodes, in particular for rechargeable lithium batteries.
GB0128324A 1999-06-17 2000-06-05 Process for producing a lithium transition metal sulphide Expired - Lifetime GB2365858B (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB9914041A GB2351075A (en) 1999-06-17 1999-06-17 Producing lithiated transition metal sulphides
PCT/GB2000/002179 WO2000078673A1 (en) 1999-06-17 2000-06-05 Process for producing a lithium transition metal sulphide

Publications (3)

Publication Number Publication Date
GB0128324D0 GB0128324D0 (en) 2002-01-16
GB2365858A true GB2365858A (en) 2002-02-27
GB2365858B GB2365858B (en) 2002-12-31

Family

ID=10855484

Family Applications (2)

Application Number Title Priority Date Filing Date
GB9914041A Withdrawn GB2351075A (en) 1999-06-17 1999-06-17 Producing lithiated transition metal sulphides
GB0128324A Expired - Lifetime GB2365858B (en) 1999-06-17 2000-06-05 Process for producing a lithium transition metal sulphide

Family Applications Before (1)

Application Number Title Priority Date Filing Date
GB9914041A Withdrawn GB2351075A (en) 1999-06-17 1999-06-17 Producing lithiated transition metal sulphides

Country Status (10)

Country Link
US (1) US6740301B1 (en)
EP (1) EP1187790B1 (en)
JP (1) JP4744755B2 (en)
AT (1) ATE253017T1 (en)
AU (1) AU5234300A (en)
CA (1) CA2375195C (en)
DE (1) DE60006236T2 (en)
ES (1) ES2207520T3 (en)
GB (2) GB2351075A (en)
WO (1) WO2000078673A1 (en)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB0029958D0 (en) * 2000-12-08 2001-01-24 Secr Defence Synthesis of lithium transition metal sulphides
EP2146931B1 (en) 2007-04-16 2014-09-24 Basf Se Method for the production of lithium-rich metal oxides
GB2464455B (en) * 2008-10-14 2010-09-15 Iti Scotland Ltd Lithium-containing transition metal sulfide compounds
JP5271035B2 (en) * 2008-10-23 2013-08-21 日本化学工業株式会社 Method for producing lithium iron sulfide and method for producing lithium sulfide transition metal
JP5403632B2 (en) * 2009-01-22 2014-01-29 独立行政法人産業技術総合研究所 Method for producing lithium iron sulfide composite
CN102797031B (en) * 2012-08-22 2015-07-08 兰州大学 Preparation method of pyrite-type ferrous disulfide nanoscale single-crystal semiconductor material
EP2977354B1 (en) * 2013-03-18 2019-03-06 National Institute of Advanced Industrial Science and Technology Lithium titanium sulfide
JP6254413B2 (en) * 2013-10-07 2017-12-27 古河機械金属株式会社 Method for producing lithium sulfide
DE102014211421A1 (en) 2014-06-13 2015-12-17 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Process for the preparation of alkali metal sulfide nanoparticles, alkali metal sulfide nanoparticles, use of the alkali metal sulfide nanoparticles and alkali metal sulfur battery
CN107074585B (en) * 2014-11-18 2018-12-25 国立研究开发法人产业技术综合研究所 Lithium-iron-phosphorus-sulphur-carbon complex and its manufacturing method
CN106129380A (en) * 2016-08-31 2016-11-16 四川剑兴锂电池有限公司 A kind of anode pole piece and the amorphous carbon lithium battery containing this positive plate
CN112670559A (en) 2019-10-15 2021-04-16 通用汽车环球科技运作有限责任公司 Solid electrolyte and method for preparing the same
DE102020125123B4 (en) 2020-09-25 2022-06-30 GM Global Technology Operations LLC Process for producing a solid electrolyte
CN112678865A (en) * 2021-01-13 2021-04-20 福建工程学院 Transition metal sulfide-based optical amplitude limiting material

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2420852A1 (en) * 1978-03-24 1979-10-19 Comp Generale Electricite LITHIUM GENERATOR
US4731307A (en) * 1986-06-10 1988-03-15 The United States Of America As Represented By The United States Department Of Energy Methods for achieving the equilibrium number of phases in mixtures suitable for use in battery electrodes, e.g., for lithiating FeS2
US4761487A (en) * 1986-06-10 1988-08-02 The United States Of America As Represented By The United States Department Of Energy Method for improving voltage regulation of batteries, particularly Li/FeS2 thermal batteries

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB385895A (en) * 1931-09-05 1933-01-05 Ig Farbenindustrie Ag Improved manufacture of anhydrous alkali polysulphides
GB453203A (en) * 1935-03-04 1936-09-04 Werner Wilfred Duecker Improvements in plastics
GB805922A (en) * 1955-10-17 1958-12-17 Texas Gulf Sulphur Co Improvements in or relating to decomposition of sulfide minerals
US3925098A (en) * 1974-11-27 1975-12-09 Electric Power Res Inst Positive electrode for electrical energy storage device
US4164069A (en) * 1978-04-28 1979-08-14 The United States Of America As Represented By The United States Department Of Energy Method of preparing a positive electrode for an electrochemical cell
US4172926A (en) * 1978-06-29 1979-10-30 The United States Of America As Represented By The United States Department Of Energy Electrochemical cell and method of assembly
GB2057412B (en) 1979-08-20 1983-05-18 Ihara Chemical Ind Co Process for preparing carbonyl sulphide
US4917871A (en) * 1987-04-09 1990-04-17 Moli Energy Limited Chevrel-phase syntheses and electrochemical cells
JPH0624983B2 (en) * 1987-10-16 1994-04-06 松下電器産業株式会社 Method for producing chevrel compound
JPH0230624A (en) * 1988-07-20 1990-02-01 Mitsui Toatsu Chem Inc Production of copper molybdenum sulfide
JPH0350108A (en) * 1989-07-17 1991-03-04 Natl Res Inst For Metals Production of metal sulfide
JPH03109212A (en) * 1989-09-21 1991-05-09 Mitsui Toatsu Chem Inc Production of sulfide having chevrel phase
DE69516351T2 (en) * 1994-09-21 2000-12-07 Matsushita Electric Ind Co Ltd Secondary lithium solid-state battery
JP3885897B2 (en) 1996-04-16 2007-02-28 古河機械金属株式会社 Method for producing silicon sulfide
JP2958445B2 (en) * 1997-03-07 1999-10-06 科学技術庁無機材質研究所長 Compound having a cubic structure represented by Li5Ag2Hf3S8 and method for producing the same
JPH11297358A (en) * 1998-04-14 1999-10-29 Matsushita Electric Ind Co Ltd Lithium secondary battery
JPH11297359A (en) * 1998-04-15 1999-10-29 Matsushita Electric Ind Co Ltd All solid lithium secondary battery

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2420852A1 (en) * 1978-03-24 1979-10-19 Comp Generale Electricite LITHIUM GENERATOR
US4731307A (en) * 1986-06-10 1988-03-15 The United States Of America As Represented By The United States Department Of Energy Methods for achieving the equilibrium number of phases in mixtures suitable for use in battery electrodes, e.g., for lithiating FeS2
US4761487A (en) * 1986-06-10 1988-08-02 The United States Of America As Represented By The United States Department Of Energy Method for improving voltage regulation of batteries, particularly Li/FeS2 thermal batteries

Also Published As

Publication number Publication date
WO2000078673A1 (en) 2000-12-28
GB2351075A (en) 2000-12-20
EP1187790A1 (en) 2002-03-20
ATE253017T1 (en) 2003-11-15
CA2375195A1 (en) 2000-12-28
CA2375195C (en) 2009-08-11
GB0128324D0 (en) 2002-01-16
US6740301B1 (en) 2004-05-25
AU5234300A (en) 2001-01-09
JP2003502265A (en) 2003-01-21
EP1187790B1 (en) 2003-10-29
ES2207520T3 (en) 2004-06-01
JP4744755B2 (en) 2011-08-10
GB2365858B (en) 2002-12-31
DE60006236D1 (en) 2003-12-04
GB9914041D0 (en) 1999-08-18
DE60006236T2 (en) 2004-07-29

Similar Documents

Publication Publication Date Title
GB2365858B (en) Process for producing a lithium transition metal sulphide
GB0029958D0 (en) Synthesis of lithium transition metal sulphides
DE69907446D1 (en) Lithium storage material containing oxygen, sulfur and transition metal, electrode containing this material and manufacturing process for this, as well as secondary lithium battery
DE60041605D1 (en) Production of lithium-containing materials
DE60008801D1 (en) LITHLED ELECTROCHEMICALLY ACTIVE CONNECTIONS AND THEIR PRODUCTION
EP1230695A4 (en) Cathode intercalation compositions, production methods and rechargeable lithium batteries containing the same
WO2009045295A3 (en) Processes for producing synthetic pyrite
EP1387420A4 (en) Graphite material for negative pole of lithium secondary battery, method of manufacturing the graphite material, and lithium secondary battery
AU2002306483A1 (en) Electrolytes with strong oxidizing additives for lithium/sulfur batteries
EP1158589A4 (en) Secondary lithium battery, negative electrode for secondary lithium battery, and process for producing the negative electrode
EP1681738A4 (en) Non-aqueous electrolyte secondary battery-use cathode material, production method therefor, non-aqueous electrolyte secondary battery-use cathode and non-aqueous electrolyte secondary battery using the cathode material
ATE306122T1 (en) ELECTRODE MATERIAL FOR POSITIVE ELECTRODES OF RECHARGEABLE LITHIUM BATTERIES
AU2003211452A1 (en) Positive electrode for nonaqueous electrolyte battery, process for producing the same and nonaqueous electrolyte battery
AU2003236308A1 (en) Positive electrode for nonaqueous electrolyte battery, process for producing the same and nonaqueous electrolyte battery
MXPA02012376A (en) Method for producing 5-aminosalicyclic acid.
BR0208170A (en) Modular melting metal production equipment
WO2004075315A3 (en) Battery containing fibrous material
AU6331399A (en) Method for feeding fines or granules into a light-arc furnace
Abraham et al. EAF Energy and Material Balance Modeling
AU2003250047A8 (en) Lithium polymer battery and method for the production of lithium polymer batteries
Goodwin Franklin construction advances
Baptizmanskii Ways of developing the production of steel for a wide range of applications
WO2001038319A8 (en) Dioxolone and its use as electrolytes
AUPR512901A0 (en) Single step vanadium redox battery electrolyte production process

Legal Events

Date Code Title Description
PE20 Patent expired after termination of 20 years

Expiry date: 20200604