GB2352730B - Metal cleaning composition - Google Patents

Metal cleaning composition

Info

Publication number
GB2352730B
GB2352730B GB9917853A GB9917853A GB2352730B GB 2352730 B GB2352730 B GB 2352730B GB 9917853 A GB9917853 A GB 9917853A GB 9917853 A GB9917853 A GB 9917853A GB 2352730 B GB2352730 B GB 2352730B
Authority
GB
United Kingdom
Prior art keywords
phenols
cleaning composition
tar acid
metal cleaning
acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Revoked
Application number
GB9917853A
Other versions
GB9917853D0 (en
GB2352730A (en
Inventor
John Hayward
Satinder Chagar
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IVAR RIVENAES Ltd
Original Assignee
IVAR RIVENAES Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IVAR RIVENAES Ltd filed Critical IVAR RIVENAES Ltd
Priority to GB9917853A priority Critical patent/GB2352730B/en
Publication of GB9917853D0 publication Critical patent/GB9917853D0/en
Priority to PCT/GB2000/002891 priority patent/WO2001009274A1/en
Priority to AU61730/00A priority patent/AU6173000A/en
Priority to EP00948166A priority patent/EP1204731B1/en
Priority to DE60010718T priority patent/DE60010718T2/en
Priority to DK00948166T priority patent/DK1204731T3/en
Priority to KR1020027000776A priority patent/KR20020010941A/en
Priority to AT00948166T priority patent/ATE266716T1/en
Publication of GB2352730A publication Critical patent/GB2352730A/en
Application granted granted Critical
Publication of GB2352730B publication Critical patent/GB2352730B/en
Anticipated expiration legal-status Critical
Revoked legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/42—Amino alcohols or amino ethers
    • C11D1/44—Ethers of polyoxyalkylenes with amino alcohols; Condensation products of epoxyalkanes with amines
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88—Ampholytes; Electroneutral compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88—Ampholytes; Electroneutral compounds
    • C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0047—Other compounding ingredients characterised by their effect pH regulated compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0073—Anticorrosion compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/042—Acids
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2003—Alcohols; Phenols
    • C11D3/2006—Monohydric alcohols
    • C11D3/2034—Monohydric alcohols aromatic
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2003—Alcohols; Phenols
    • C11D3/2041—Dihydric alcohols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2075—Carboxylic acids-salts thereof
    • C11D3/2086—Hydroxy carboxylic acids-salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/22—Carbohydrates or derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/32—Amides; Substituted amides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/33—Amino carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/36—Organic compounds containing phosphorus
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3784—(Co)polymerised monomers containing phosphorus
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
    • C23G1/02—Cleaning or pickling metallic material with solutions or molten salts with acid solutions
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
    • C23G1/02—Cleaning or pickling metallic material with solutions or molten salts with acid solutions
    • C23G1/08—Iron or steel
    • C23G1/088—Iron or steel solutions containing organic acids
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02B—INTERNAL-COMBUSTION PISTON ENGINES; COMBUSTION ENGINES IN GENERAL
    • F02B77/00—Component parts, details or accessories, not otherwise provided for
    • F02B77/04—Cleaning of, preventing corrosion or erosion in, or preventing unwanted deposits in, combustion engines
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
    • C11D1/523—Carboxylic alkylolamides, or dialkylolamides, or hydroxycarboxylic amides (R1-CO-NR2R3), where R1, R2 or R3 contain one hydroxy group per alkyl group
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88—Ampholytes; Electroneutral compounds
    • C11D1/90—Betaines
    • C11D2111/12—
    • C11D2111/16—

Abstract

A metal cleaning composition comprises at least one primary surfactant selected from nonionic and amphoteric surfactants; at least one glycol; tar acid; deionised water; and one or more pH buffer acids selected from orthphosphoric, phosphonic, glycolic, gluconic, glucoheptonic and citric acids. The composition is used to clean an automobile engine by spraying it into the air intake of the running engine. The tar acid is usually a complex mixture of diethyl phenols / methyl substituted dihydric phenols / propyl and butyl phenols / indenols / naphthols and tetralols. A preferred tar acid component used is cresylic acid. Corrosion inhibitors may also be present.
GB9917853A 1999-07-29 1999-07-29 Metal cleaning composition Revoked GB2352730B (en)

Priority Applications (8)

Application Number Priority Date Filing Date Title
GB9917853A GB2352730B (en) 1999-07-29 1999-07-29 Metal cleaning composition
DE60010718T DE60010718T2 (en) 1999-07-29 2000-07-27 COMPOSITION FOR METAL CLEANING
AU61730/00A AU6173000A (en) 1999-07-29 2000-07-27 Metal cleaning composition
EP00948166A EP1204731B1 (en) 1999-07-29 2000-07-27 Metal cleaning composition
PCT/GB2000/002891 WO2001009274A1 (en) 1999-07-29 2000-07-27 Metal cleaning composition
DK00948166T DK1204731T3 (en) 1999-07-29 2000-07-27 Composition for cleaning metals
KR1020027000776A KR20020010941A (en) 1999-07-29 2000-07-27 Metal cleaning composition
AT00948166T ATE266716T1 (en) 1999-07-29 2000-07-27 COMPOSITION FOR METAL CLEANING

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB9917853A GB2352730B (en) 1999-07-29 1999-07-29 Metal cleaning composition

Publications (3)

Publication Number Publication Date
GB9917853D0 GB9917853D0 (en) 1999-09-29
GB2352730A GB2352730A (en) 2001-02-07
GB2352730B true GB2352730B (en) 2003-04-30

Family

ID=10858187

Family Applications (1)

Application Number Title Priority Date Filing Date
GB9917853A Revoked GB2352730B (en) 1999-07-29 1999-07-29 Metal cleaning composition

Country Status (8)

Country Link
EP (1) EP1204731B1 (en)
KR (1) KR20020010941A (en)
AT (1) ATE266716T1 (en)
AU (1) AU6173000A (en)
DE (1) DE60010718T2 (en)
DK (1) DK1204731T3 (en)
GB (1) GB2352730B (en)
WO (1) WO2001009274A1 (en)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2405639A (en) * 2003-09-08 2005-03-09 R Mc Power Recovery Ltd Metal cleaning compositions
MX344139B (en) 2004-06-14 2016-12-07 Pratt & Whitney Line Maintenance Services Inc System and devices for collecting and treating waste water from engine washing.
EP2110462B8 (en) 2008-04-19 2012-09-05 Cognis IP Management GmbH Compositions for degreasing metal surfaces
EP2345702A1 (en) * 2010-01-13 2011-07-20 Cognis IP Management GmbH Paint and coating remover compositions
GB201008577D0 (en) * 2010-05-24 2010-07-07 Aquafuel Res Ltd Engine cleaning method
CN101982542B (en) * 2010-09-16 2012-05-30 吴龙生 Special cleaning agent for three-way catalyst of vehicle
US20150159122A1 (en) * 2013-12-09 2015-06-11 General Electric Company Cleaning solution and methods of cleaning a turbine engine
US9926517B2 (en) 2013-12-09 2018-03-27 General Electric Company Cleaning solution and methods of cleaning a turbine engine
CN103758640B (en) * 2014-01-27 2016-03-02 陈凤鸣 A kind of ternary catalyzing unit non-disassembly cleaning method
BR102016021259B1 (en) 2015-10-05 2022-06-14 General Electric Company METHOD AND SOLUTIONS FOR CLEANING A TURBINE ENGINE AND REAGENT COMPOSITION

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB633059A (en) * 1945-10-04 1949-12-12 George William Gregg A fluid composition for cleaning the surfaces of metals and other relatively hard materials
GB722449A (en) * 1951-05-04 1955-01-26 Bendix Aviat Corp Cadmium plated aluminum and the method of making the same
GB778902A (en) * 1953-06-11 1957-07-17 Newton Chambers & Co Improvements relating to emulsions
GB778903A (en) * 1953-05-15 1957-07-17 Newton Chambers & Co Improvements relating to emulsions
GB834707A (en) * 1957-09-02 1960-05-11 Rolls Royce Removing resin from aluminium and aluminium alloy surfaces
GB1342077A (en) * 1970-10-15 1973-12-25 Rivenaes I Cleaning engines and boilers
JPS63159758A (en) * 1986-12-24 1988-07-02 Osaka Eyazoole Kogyo Kk Seat cleaner
SU1202292A1 (en) * 1984-04-12 1997-01-27 В.Б. Колотыгина Composition for purification of engines against carbon

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SU857256A1 (en) * 1979-11-29 1981-08-23 Государственный Всесоюзный Ордена Трудового Красного Знамени Научно-Исследовательский Технологический Институт Ремонта И Эксплуатации Машинно-Тракторного Парка Detergent for cleaning metallic surface
US5468303A (en) * 1994-02-25 1995-11-21 Zt Corporation Rust, corrosion, and scale remover
CA2222896C (en) * 1995-06-02 2007-07-31 Ashland Inc. Stable microemulsion cleaners having low volatile organic content

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB633059A (en) * 1945-10-04 1949-12-12 George William Gregg A fluid composition for cleaning the surfaces of metals and other relatively hard materials
GB722449A (en) * 1951-05-04 1955-01-26 Bendix Aviat Corp Cadmium plated aluminum and the method of making the same
GB778903A (en) * 1953-05-15 1957-07-17 Newton Chambers & Co Improvements relating to emulsions
GB778902A (en) * 1953-06-11 1957-07-17 Newton Chambers & Co Improvements relating to emulsions
GB834707A (en) * 1957-09-02 1960-05-11 Rolls Royce Removing resin from aluminium and aluminium alloy surfaces
GB1342077A (en) * 1970-10-15 1973-12-25 Rivenaes I Cleaning engines and boilers
SU1202292A1 (en) * 1984-04-12 1997-01-27 В.Б. Колотыгина Composition for purification of engines against carbon
JPS63159758A (en) * 1986-12-24 1988-07-02 Osaka Eyazoole Kogyo Kk Seat cleaner

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
DATABASE WPI Section Ch, Week 199738 Derwent Publications Ltd., London, GB; Class E19, AN 1997-413657 XP002150864 & SU 1 202 292 A (KOLOTYGINA V B), 27 January 1997 (1997-01-27) *
WPI Accession no 88-224436 & JP 63 159 758 A (1988-07-02) *

Also Published As

Publication number Publication date
DE60010718D1 (en) 2004-06-17
EP1204731A1 (en) 2002-05-15
AU6173000A (en) 2001-02-19
GB9917853D0 (en) 1999-09-29
ATE266716T1 (en) 2004-05-15
WO2001009274A1 (en) 2001-02-08
GB2352730A (en) 2001-02-07
EP1204731B1 (en) 2004-05-12
DK1204731T3 (en) 2004-08-30
KR20020010941A (en) 2002-02-06
DE60010718T2 (en) 2005-06-16

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Legal Events

Date Code Title Description
732E Amendments to the register in respect of changes of name or changes affecting rights (sect. 32/1977)
773K Patent revoked under sect. 73(2)/1977

Free format text: PATENT REVOKED ON 20051201