GB2315301A

GB2315301A - Sliding bearing resistant to fretting

Info

Publication number: GB2315301A
Application number: GB9711564A
Authority: GB
Inventors: Hideo Tsuji; Hideo Ishikawa; Motomu Wada; Takayuki Shibayama
Original assignee: Daido Metal Co Ltd
Current assignee: Daido Metal Co Ltd
Priority date: 1996-07-15
Filing date: 1997-06-04
Publication date: 1998-01-28
Anticipated expiration: 2017-06-04
Also published as: GB2315301B; GB9711564D0; JPH1030639A

Abstract

A sliding bearing (2) is mounted in a housing (1), and a covering layer (2a) of an amorphous alloy is formed on at least one of the back face of the bearing and an inner surface of the housing, thereby imparting fretting resistance to the bearing structure. The alloy may be based on Ni, Co or Cr. The beaming may comprise a beaming metal such as Al- or Cu- alloy bonded to a backing metal, optionally with an overlay.

Description

BEARING STRUCTURE OF SLIDING BEARING BACKGROUND OF THE INVENTION This invention relates generally to a bearing structure of a sliding bearing, and more particularly to a bearing structure of a sliding bearing subjected to dynamic loads of an internal combustion engine or the like.

Recently, for the purpose of achieving a lightweight design, a housing, on which a sliding bearing is mounted, has been reduced in thickness, or has been made of an aluminum alloy, and therefore the housing has been reduced in rigidity. As a result, slight, repeated strains due to dynamic loads are more liable to develop in the housing than in housings of the earlier type. For example, a big end portion of a connecting rod and a main bearing portion in an internal combustion engine have been formed into a lightweight design so as to achieve a high-speed, high-temperature and high-load design. Because of slight repeated strains of the housing, a relative slight impingement and a relative slight slip develop at a back face of a sliding bearing which is mounted on the big end portion and the main bearing portion, so that the sliding bearing is liable to be damaged by fretting wear.

To deal with this fretting wear, there have heretofore been proposed a structure in which a coating of phosphate having an excellent fretting resistance is formed on the back face of the sliding bearing, another structure in which a covering layer of a resin (e.g. PTFE) having excellent lubricating properties is formed on the back face of the sliding bearing, and still another structure in which a covering layer of silver or copper is formed by plating on the back face of the sliding bearing.

JP-A-61-88020 discloses a structure in which a covering layer, made of copper, nickel, aluminum, or an alloy thereof, and having the hardness of Hv 15 to 80, is formed on a back face of a bearing. These soft metals covering layer suppress fretting wear.

JP-A-2-89813 discloses a structure in which PTFE is precipitated in a plated layer of Ni or Co simultaneously with the formation of this plated layer, thereby forming a composite plated layer serving as a covering layer. The reason for this is that since PTFE having a low friction coefficient is inferior in bonding strength to a back metal, PTFE cooperates with Ni or Co to form the composite plated layer, thereby enhancing the bonding strength. This publication discloses that by thus enhancing the close contact of the back face of the bearing with the housing, there can be provided a bearing having the enhanced fretting resistance.

With respect to the soft covering layer (disclosed in JP-A-61-88020) composed of the metal having the hardness of Hv 15 to 80, because of its inadequate rigidity, an adhesion phenomenon is liable to occur between the back face of the bearing and the housing, and fretting resulting therefrom is liable to occur. Thus, the sufficient fretting resistance could not be obtained merely by using the soft covering layer.

The covering layer (disclosed in JP-A-2-89813) composed of PTFE and metal such as Ni, is also intended to enhance the close contact between the back face of the bearing and the housing so as to enhance the fretting resistance. However, adhesion occurs between the back face of the bearing and the housing because of a slight friction still developing therebetween, so that the fretting resistance could not be enhanced satisfactorily.

Thus, the above conventional covering layers are not satisfactory in fretting resistance.

SUMMARY OF THE INVENTION The present invention has been made based on an excellent non-adhesion property of an amorphous alloy, and an object of the invention is to provide a bearing structure in which adhesion is less liable to develop between a back face of a bearing and a housing even if a slight sliding friction repeatedly occurs therebetween, thereby imparting an excellent fretting resistance to the bearing structure.

According to the present invention, there is provided a bearing structure comprising a housing, a sliding bearing which is mounted at its back face on the housing and which rotatably supports a rotation shaft on an inner face thereof, and a covering layer of an amorphous alloy is formed on at least one of the back face of the sliding bearing and an inner surface of the housing.

The housing may be made of a steel formed by forging or by a sintered alloy, a light alloy such as an aluminum alloy, or any other suitable material.

The sliding bearing may comprise a composite bearing such as a two-layer bearing having a bearing metal layer formed on a back metal, or a three-layer bearing having a bearing metal layer formed on a back metal, and an overlay layer formed on the bearing metal layer. An aluminum-based alloy or a copper-based alloy may be used as a bearing metal.

Usually, a cold rolled, soft steel sheet may be used as the back metal, but any other suitable material such as aluminum can be used as the back metal.

The covering layer may be formed on either of the back face of the sliding bearing and the inner surface of the housing, or may be formed on both of the back face of the sliding bearing and the inner surface of the housing.

The covering layer of the amorphous alloy may be formed by a bonding method (by which a thin film of the amorphous alloy is bonded), a sputtering method, or a vapor deposition method, but the formation of the covering layer by a plating method is the easiest, and therefore is most preferred. With respect to the plating method, an electric deposition (precipitation) method and an electroless plating method are suitably used depending on the kind of the amorphous alloy.

The amorphous alloy may comprise a binary alloy, a ternary alloy, or an alloy composed of more than three principal metallic components, and a suitable alloy is selected depending on the hardness of the back metal and the housing. Examples of such binary alloy include a Ni alloy such as Ni-P, Ni-B, Ni-H, Ni-W, Ni-S, Ni-Zn and Ni Mo, a Co alloy such as Co-P, Co-B, Co-H, Co-W, Co-S, Co-Zn and Co-Mo, and a Cr alloy such as Cr-H and Cr-C. These binary alloys are liable to be formed into an amorphous structure, and therefore are preferred.

Examples of such ternary alloy include a Ni-alloy such as Ni-Co-P, Ni -Co-B, Ni-Fe-P, Ni-W-P, Ni-W-B, Ni-Mo-P, Ni-Mo-B, Ni-Cu-P, Ni -Cr-P, a Co alloy such as Co-W-B, Co Ni-P and Co-Zn-P, and a Cr alloy such as Cr-W-H, Cr-Mo-H and Cr-Fe-H.

The content of the alloy element of the amorphous alloy need only to be such that the covering layer in the amorphous state can be formed. For example, in the case of forming a covering layer, composed of an amorphous alloy of Ni-P, by a plating method, the amorphism rate abruptly increases as the P content increases to about 5 wt.%, and with the P content of about 8 wt.%, the covering layer becomes amorphous almost completely. Therefore, when forming the covering layer, composed of the amorphous alloy of Ni-P, by the plating method, the content of P (alloy element) is preferably not less than 5%, and more preferably not less than about 8%.

The thickness of the covering layer can be suitably selected, but if this thickness is too small, the durability of the covering layer is not satisfactory.

Thermal conductivity of the amorphous alloy is not good, and the thick covering layer lowers a cooling efficiency of the bearing. Therefore, preferably, the thickness of the covering layer, formed on either of the inner surface of the housing and the back face of the back metal, or the sum of the thicknesses of the covering layers, formed respectively on the inner surface of the housing and the back face of the back metal, is about 2 jun to about 30 Fm.

As described above, in the invention as defined in claim 1, the covering layer of the amorphous alloy is formed on at least one of the back face of the sliding bearing and the inner surface of the housing, and with this construction, there can be provided a bearing structure of the sliding bearing in which the high fretting resistance and wear resistance of the back face of the bearing are ensured.

BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 is a sectional view showing a bearing structure embodying the present invention; and Fig. 2 is a partial sectional view of a main portion of the bearing structure of Fig. 1. DESCRIPTION OF THE PREFERRED EMBODIMENTS The present invention will now be described by way of Examples.

As shown in Figs. 1 and 2, each of sliding bearing structures, used in a test, was designed so that a sliding bearing 2 was mounted at its back face on an big end portion (housing 1) of a connecting rod of an engine for an automobile, so as to rotatably support a crankshaft on its inner face. The sliding bearing 2 was a half bearing of a semi-cylindrical shape, and a cold rolled sheet (JIS G3141 SPCC) was used as a back metal 3. A bearing alloy layer 4, consisting of the balance Cu, 3.5% Sn and 23% Pb by weight, was formed by sintering on the back metal, the bearing alloy layer 4 having a thickness of 0.3 mm.

Then, this composite bimetal was cut into a piece of a predetermined length, and these pieces were curved into a semi-cylindrical shape, thereby preparing a half bearing 2 having an inner diameter of 42 mm, an outer diameter of 45 mm and a width of 17 mm. Further, an overlay 5, consisting of the balance Pb, 10% Sn and 3% Cu by weight was formed by plating on the bearing alloy layer of this half bearing, the overlay having a thickness of 15 gm.

Further, each of covering layers 2a, shown respectively in Examples and Comparative Examples in Table 1, was formed by plating on the back face 2 of the back metal of the bearing, each covering layer having a thickness of 10 Rm. With respect to Comparative Example 1 the covering layer was not formed.

Regarding each of the covering layers, the crystal structure thereof was examined by use of X ray diffraction, with the result that it was confirmed that in each of comparative examples Nos. 2 to 8 the X ray diffraction graph had a sharp peak intensity which means a crystalline structure, and that in each of examples Nos. 1 to 10 of the present invention the X ray diffraction graph had a broad peak intensity which means an amorphous structure.

Table 1

Plating conditions Composition Bath composition (g/L) Bath tempe- of covering rature ( C) layer 1 Nickel sulfate 30 Amorphous Ni - 5%P Sodium hypophosphite 5 ~ 15 Amorphous 2 95 ~ 98 Ni - 10%P Sodium citrate 10 3 Ammonium chloride 10 Amorphous Ni - 15%P Example of the 4 Nickel sulfate 30 Amorphous invention Ni - 12%B 5 Sodium tartrate 40 45 ~ 55 Amorphous Ni - 16%B 6 Sodium borohydride 10~15 Amorphous Ni - 20%B 7 Nickel chloride 48 Amorphous Ni - 20%S Ammonium chloride 40 25 ~ 35 Amorphous 8 Sodium thiosulfate 180~250 Ni - 30%S - cont'd - Table 1 (cont'd)

Plating conditions Composition Bath composition (g/L) Bath tempe- of covering rature( C) layer Chromic acid 200 Amorphous 9 Ammonium sulfate 5 55 ~ 65 Cr-20%H Example Ammonium citrate 300 of the invention Cobalt sulfate 30 10 Sodium hypophosphite 10 95 ~ 98 Amorphous Co-10%P Sodium citrate 10 Ammonium sulfate 5 1 - No covering layer 2 Cu plating in cyan bath Crystalline Cu Comparative Example 3 Alkali Sn plating Crystalline Sn 4 Ni plating in watt bath Crystalline Ni - cont'd - -

Plating conditions Composition Bath composition (g/L) Bath tempe- of covering rature( C) layer Nickel sulfate 30 5 Sodium hypophosphite 4 95 ~ 98 Crystalline Ni-2%P Sodium citrate 10 Ammonium chloride 10 Comparative Example Nickel sulfate 30 6 Sodium tartrate 40 45 ~ 55 Crystalline Ni - 4%B Sodium borohydride 5 7 Nickel Sodium Crystalline chloride 48 thio- Ni - 8%S sulfate 120 25 ~ 35 8 Ammonium sodium Crystalline chloride 40 thio- Ni - 50%S sulfate 350 * Electroplating was used in Examples 7, 8 and 9 and Comparative Examples 2, 3, 4, 7 and 8, and electroless plating was used in Examples 1 to 6 and 10 and Comparative Examples 5 and 6.

A fretting test for each of the thus obtained Examples and Comparative Examples was carried out by a vibration testing machine under conditions shown in Table 2. Whether or not any damage due to fretting was present was judged with the naked eyes.

Table 2

Test conditions Unit Dimensions 45(outer diameter) of bearing x 17(width) x 1.5 mm (thickness) Frequency 60 Hz Number of 2 x 106 cycle cycles Material of connecting rod Forged product - Material of JIS S55C shaft As a result, as shown in Table 3, damage due to the fretting was observed with respect to Comparative Examples 1 to 8. Particularly, Comparative Example 1 with no covering layer was damaged markedly. On the other hand, no damage due to the fretting was seen in Examples 1 to 10. Table 3

Kind of covering Fretting layer 1 Ni-5%P (Amorphous) None 2 Ni-10%P (Amorphous) None 3 Ni-15%P (Amorphous) None 4 Ni-12%B (Amorphous) None 5 Ni-16%B (Amorphous) None Example of the 6 Ni-20%B (Amorphous) None invention 7 Ni-20%S (Amorphous) None 8 Ni-30%S (Amorphous) None 9 Cr-20%H Amorphous) None 10 Co-10%P (Amorphous) None 1 No covering layer Occurred 2 Cu (Crystalline) Occurred 3 Sn (Crystalline) Occurred Comparative Example 4 Ni (Crystalline) Occurred 5 Ni-2%P (Crystalline) Occurred 6 Ni-4%B (Crystalline) Occurred 7 Ni-8%S (Crystalline) Occurred 8 Ni-50%S (Crystalline) Occurred

Claims

WHAT IS CLAIMED IS: 1. A bearing structure comprising a housing, a sliding bearing which is mounted at its back face on said housing and which rotatably supports a rotation shaft on an inner face thereof, and a covering layer of an amorphous alloy formed on at least one of the back face of said sliding bearing and an inner surface of said housing.
2. A bearing structure according to claim 1, said sliding bearing being one selected from the group consisting of two-layer sliding bearings each having a back metal and a bearing metal layer bonded on the back metal, and three-layer sliding bearing each having a back metal, a bearing metal layer bonded on the back metal, and an overlay bonded on the bearing metal layer.
3. A bearing structure according to claim 1, said bearing layer being made of one selected from the group consisting of aluminum-based alloys and copper-based alloys.
4. A bearing structure according to claim 1, said covering layer being made of at least one selected from the group consisting of binary Ni-based alloys, binary Co-based alloys, binary Cr-based alloys, ternary Ni-based alloys, ternary Co-based allooy, and ternary Cr-based alloys.
5. A bearing structure according to claim 4, said binary Ni-based alloy being one selected from the group consisting of Ni-P, Ni -B, Ni-H, Ni-W, Ni-S, Ni-Zn, and Ni Mo, said binary Co-based alloy being one selected from the group consisting of Co-P, Co-B, Co-H, Co-W, Co-S, Co-Zn, and Co-Mo, said binary Cr-based alloy being one selected from the group consisting of Cr-H, and Cr-C, said ternary Ni-based alloy being one selected from the group consisting of Ni-Co-P, Ni -Co-B, Ni-Fe-P, Ni-W-P, Ni-W-B, Ni-Mo-P, Ni Mo-B, Ni-Cu-P, and Ni-Cr-P, said ternary Co-based alloy being one selected from the group consisting of Co-W-B, Co Ni-P, and Co-Zn-P, said ternary Cr-based alloy being one selected from the group consisting of Cr-W-H, Cr-Mo-H, and Cr-Fe-H.
6. A bearing structure according to claim 1, said covering layer having a thickness of 2 to 30 Rm in total.
7. A bearing structure substantially as hereinbefore described with reference to and as shown in the accompanying drawings.