JPH05239690A - Multilayer slide bearing having overlay - Google Patents

Abstract

PURPOSE:To provide a multilayer slide bearing having an overlay and improved in fatigue resistance. CONSTITUTION:The objective bearing is a structural body obtd. by integrally laminating a back plate, a bearing alloy and a lead alloy overlay. The crystalline grains of the lead alloy overlay have a pyramidal shape in which their vertexes are faced to the mating sliding member side, and, each pyramidal crystalline grain placed on the outermost surface is provided with roundness. For imparting the roundness, the means of coating the surface of the lead alloy overlay with metal reducing the m.p. of lead and executing heating treatment are suitably adopted. As the metal (alloy) reducing the m.p. of lead, one or >=two kinds selected from Sn, In, Sb, Bi or the like are used.

Description

Detailed Description of the Invention

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a multi-layer slide bearing for an internal combustion engine used in automobiles, ships, construction machines and the like.

[0002]

2. Description of the Related Art A conventional slide bearing applied to an internal combustion engine is a bimetal plate formed by joining a copper alloy layer for bearings or an aluminum alloy layer for bearings on a steel plate as a back metal. In many cases, it is formed into a shaped body (semicircular body) or the like, and the bearing alloy side thereof is covered with a lead alloy overlay. Here, the main functions of the lead alloy overlay are the compatibility between the bearing and the supported shaft such as the crankshaft, the embedding ability of foreign matter mixed in the lubricating oil into the coating layer, and the deterioration of the lubricating oil. Corrosion resistance to the generated organic acid is mentioned. For the purpose of improving these functions, as disclosed in U.S. Pat. No. 2,605,149 and Japanese Patent Publication No. 39-22498, various amounts of components such as Sn, Cu and In are used. Multilayer plain bearings with alternating lead alloy overlay layers have been manufactured and used.

[0003]

However, in recent years, in the engine for automobiles, high-speed rotation,
Bearings tend to be used under high load and harsh conditions. Therefore, Sn, Cu, In of lead alloy overlay
Even if the amount of components such as is changed variously, the crystal orientation of the plating layer is not uniform and there is a limit to the improvement of mechanical strength, and conventional lead alloy overlays have insufficient seizure resistance and fatigue resistance. There are cases. In order to solve these problems, the lead alloy crystals are formed into a pyramid with the apex facing the sliding surface side, and the base length (d) of the pyramid is set to 8 μm or less to obtain a lead alloy. An invention that improves the oil retention of the overlay surface layer and improves the seizure resistance is disclosed in Japanese Patent Laid-Open No. 3-2.
It is proposed in Japanese Patent No. 15696. The present invention was created under such a technical background, and an object thereof is to obtain a multilayer slide bearing with an overlay having improved fatigue resistance.

[0004]

The object of the present invention is to provide a crystal grain of a lead alloy overlay with a pyramidal shape whose apex is directed toward the mating sliding member side, and to provide the above-mentioned pyramidal crystal grain of each pyramidal crystal grain located on the outermost surface. It is achieved by adding roundness to the vertices. A multilayer slide bearing with a lead alloy overlay based on this idea is a structure in which the back metal, bearing alloy, and lead alloy overlay are integrally laminated, and the apex of the crystal grains of the lead alloy overlay is directed toward the mating sliding member side. Each of the pyramidal crystal grains located on the outermost surface has a rounded shape. The recommended method for rounding the vertices of the pyramidal grains is to coat the surface of the lead alloy overlay with a metal that lowers the melting point of lead and heat treat the coated metal into the lead alloy overlay. Is. The multi-layer plain bearing with lead alloy overlay provided by this method has the surface of the lead alloy overlay coated with a metal that lowers the melting point of lead and is heat-treated, so that each pyramid located on the outermost surface is formed. It is a structure in which the apex of the crystal grain is rounded. Sn, In, Sb, and B are the metals that lower the melting point of lead.
One kind or a combination of two or more kinds selected from i, Ga, Tl, and Ag (in the case of two or more kinds, it is naturally an alloy form) is used. Then, it is recommended that the amount of the coating metal is 3 to 30% by weight of the entire lead alloy overlay including the coating metal. The lead alloy overlay having the pyramidal grain structure defined as described above can be formed by selecting the plating conditions. Although the details are described in the examples, the size of the pyramid can be adjusted by the size of the cathode current density, and a larger pyramid can be obtained as the cathode current density increases.

Now, the reason why the bearing structure of the present invention is adopted will be described. By rounding the vertices of each pyramidal crystal grain located on the outermost surface of the lead alloy overlay, the concentrated load acting on the outermost surface of the overlay due to oil film pressure fluctuations or the like is dispersed and reduced. This can improve the fatigue resistance of the overlay layer. Note that the roundness of the apex of a pyramidal crystal grain is not a shape with a sharp tip, but a concept other than a concave curved surface and including a convex curved surface or a flat surface. Metals that lower the melting point of lead (Sn, In, Sb, Bi,
One or two or more selected from Ga, Tl and Ag is 3 to 30% by weight of the whole lead alloy overlay layer): If the total amount is less than 3% by weight, mechanical strength such as hardness and tensile strength is reduced. It is low and lacks the corrosion resistance to organic acids generated when the lubricating oil deteriorates. If the total amount exceeds 30% by weight, the sliding bearing is used in a temperature range of 100 to 100%.
The mechanical strength at 130 ° C is significantly reduced. Therefore, the total amount of metals that lower the melting point of lead contained in the entire lead alloy overlay layer is limited to 3 to 30% by weight, and more preferably 5 to 20% by weight. Note that Sn, In, Sb, and Bi are more preferable as the metal that lowers the melting point of lead, but the present invention is not limited to this, and Ga, Tl, and Ag that are effective can be used.

[0006]

DESCRIPTION OF THE PREFERRED EMBODIMENTS In FIG. 1, a slide bearing 1 is applied to a crankshaft journal portion, a connecting rod large end portion, and the like in an engine, and is a cylinder in which a pair of semicircular bodies 2 and 3 are combined. It is a shaped body. A rotating shaft such as a crankshaft is supported inside thereof. 2 is shown in FIG.
The II-II line indicating vertical cross-section structure in FIG. 2 is shown, and each of the semicircular shaped bodies 2 and 3 comprises a back metal layer 4, a bearing alloy layer 5 and a lead alloy overlay layer 6. The back metal 4 is made of low carbon steel, high carbon steel, stainless steel or special steel, and its thickness is determined by the set thickness of the slide bearing. Bearing alloy layer 5
Is made of a known copper-based bearing alloy or aluminum-based bearing alloy, and its layer thickness is 0.05 to 0.5 mm, and in the case of an ordinary automobile engine bearing, it is set to 0.2 to 0.4 mm. .. The lead alloy overlay layer is formed as a pyramidal crystal grain structure in which the vertices of the crystal grains are positioned toward the sliding surface side, and the vertices of the pyramidal crystal grains located on the outermost surface are rounded. This overlay layer is comprised of 70-97 wt% Pb and 3-30 wt% S as a whole.
One or two or more of n, Cu and In are contained, and the layer thickness thereof is 5 to 50 μm, and 10 to 20 μm in the case of an ordinary automobile engine bearing. Back metal layer 4
Between the bearing alloy layer 5 and the bearing alloy layer 5 is a Cu plating layer or a Ni plating layer, and between the bearing alloy layer 5 and the lead alloy overlay layer 6 is a Ni, Ag, Cu, Co, Fe or alloy plating thereof, Each can be provided as needed. FIG. 3 is a schematic cross-sectional view showing a structure in which the apexes of the pyramidal crystal grains in the lead alloy overlay 6a, which is the main layer, are directed toward the sliding surface side. FIG. 4 is a schematic cross-sectional view showing a state in which the sliding surface side of the overlay shown in FIG. 3 is coated with a metal that lowers the melting point of lead as a sublayer, and heat treatment is performed to diffuse the sublayer components into the main layer. In addition, the apex of the crystal grains on the outermost surface is rounded and modified. FIG. 5 shows FIG.
6 is an electron micrograph of the overlay shown in FIG. 6 viewed from the sliding surface side, and FIG. 6 is an electron micrograph of the smoothed outermost surface layer of the overlay shown in FIG. Figure 7
Shows an electron micrograph of a lead alloy overlay having an uneven crystal form as seen from the sliding surface side.

Test Example 1 A bearing copper alloy powder was sprinkled on a steel backing and sintered to form a sintered layer to obtain a bimetal. Next, the bimetal was cut into a predetermined size and further machined to obtain a plain bearing test piece (hereinafter referred to as a test piece) having a semicircular cross section. For this test piece, normal solvent degreasing, electrolytic degreasing,
After pretreatment in the order of pickling, a sintered copper alloy surface was coated with 1.5 μm thick Ni plating as an intermediate plating layer. The Ni plating conditions include a normal watt Ni plating bath (bath temperature 50 ° C., cathode current density 6 A / d).
m ² ) was adopted. The lead alloy overlay plating layer of the main layer is 40 to 180 g of Pb ²⁺ in a normal borofluoride bath.
/ L, Sn ^{2+ 0 to} 35 g / l, Cu ^{2+ 0 to 5} g / l, the metal ion amount was adjusted, and the bath temperature was set to 10 to 35 ° C. and the cathode current density was set to ³ to 15 A / dm ² . Under the conditions, the crystal grains were formed into a pyramidal shape. Observing this surface with an electron microscope, the base length (d) defined in the schematic diagram of the pyramid shown in FIG.
, The height (h) was measured, and by changing the plating conditions variously, the size and plating thickness of the pyramid were changed to form the lead alloy plating layer of the main layer, and the comparison product ( Sample Nos. 8 to 10) were obtained. FIG. 9 is a schematic diagram of a pyramid with rounded vertices as an example of the present invention in contrast to the schematic diagram of a pyramid as a conventional example shown in FIG. 8. The components of the lead alloy overlay, the shape of the surface layer and the size of the pyramid are shown in Table 1, the fatigue test conditions are shown in Table 2, and the test results thereof are shown in FIG.

Test Example 2 The main layer lead alloy overlay plating layer obtained by the same method as the above 1 was plated with In as a sub-layer metal for lowering the melting point of lead. The plating conditions are a sulfamic acid bath containing In ³⁺ 10 to 50 g / l, a bath temperature of 30 ° C., and a cathode current density of 1 A /
A plurality of samples were obtained by changing the plating time to dm ² . Then, the sample is subjected to a heat treatment at a temperature of 150 to 200 ° C. for 60 to 120 minutes to measure the diffusion of surface layer components and to round the apexes of the pyramidal outermost surface crystal grains (Sample No. . 1-3, 7) were obtained. In addition, Sn is used as a metal for lowering the melting point of lead on the main layer surface by the same method as described above.
A -15Sb alloy plating layer was applied. Plating conditions are Sn
Sample No. 4 was obtained with a borofluoride bath containing 2 ⁺ 40 to 50 g / l and Sb1 to 3 g / l, a bath temperature of 25 ° C., and a cathode current density of 2 A / dm ² . Furthermore, Bi ²⁺ 10 to 30 g /
In a perchloric acid bath containing 1, the bath temperature 20 ℃, cathode current density 1 ~
Sample No. 6 obtained by Bi-plating at 5 A / dm ² and different plating times was obtained. Although a heat treatment method that is more accurately controlled was used as the means for imparting roundness to the vertices of the outermost surface crystal grains, the method is not limited to this. The thickness of each layer of the obtained test piece was a lead alloy overlay layer of 20 μm, a copper bearing alloy layer of 0.3 mm, and a steel backing layer of 1.2 mm.
The components of the lead alloy overlay, the shape of the surface layer and the size of the pyramid are shown in Table 1, the fatigue test conditions are shown in Table 2, and the test results thereof are shown in FIG.

Test Example 3 Furthermore, for comparison with the conventional product, the same test piece as in Test Example 1 was used, the same pretreatment and Ni plating were performed, and then the same lead alloy plating bath as in Test Example 1 was used. Then, the plating conditions were adjusted to apply a main layer having a non-uniform crystal orientation, Sn plating was applied according to Test Example 2, and further heat treatment was performed to obtain a comparative product (Sample No. 11). The components of the lead alloy overlay, the shape of the surface layer and the size of the pyramid are shown in Table 1, the fatigue test conditions are shown in Table 2, and the test results thereof are shown in FIG.

In order to confirm the effect of each sample, a comparative test was carried out using a rotary load tester. In order to imitate the axial center locus of a high-speed rotation of an automobile engine, an unbalanced weight is attached to the rotating shaft, load is applied to the entire circumference of the bearing, and the rotation speed is increased in stages to prevent fatigue of the lead alloy overlay. This is a comparison test of surface pressure. Table 2 shows the test conditions in that case.

[0011]

As compared with the conventional lead alloy overlay consisting of pyramidal crystal grains, the surface irregularities based on the pyramidal crystal grains of the main layer surface of the lead alloy overlay are coated with a metal that lowers the melting point of lead, and heat treatment is performed. As a result, it can be seen that the product of the present invention having the outermost surface crystal grains with rounded vertices has improved fatigue resistance, as is apparent from the test results shown in FIG. Further, the conventional product in which the crystal grains of the lead alloy are not in the pyramidal shape has a smooth surface roughness, but lacks mechanical strength because the crystal structure of the plating structure is indefinite and is inferior to the product of the present invention. As described above, the present invention has excellent fatigue resistance,
It is highly promising as a plain bearing with a lead alloy overlay that can be applied to harsh conditions at high speeds and loads.

[0012]

[Table 1] Table 1

[0013]

[Table 2]

[Brief description of drawings]

FIG. 1 is a plan view of a plain bearing.

FIG. 2 is a sectional view taken along the line II-II in FIG.

FIG. 3 is a schematic cross-sectional view showing a structural structure in which the vertices of pyramidal crystal grains in the lead alloy overlay are directed toward the sliding surface side.

FIG. 4 is a structure similar to that of FIG. 3 showing a structure in which the sliding surface side of the overlay shown in FIG. 3 is coated with a metal that lowers the melting point of lead, and a diffusion heat treatment is performed to round the surface crystal grain vertices. Fig.

FIG. 5 is a micrograph (10,000 times) showing a crystal structure in which the apex of the pyramidal crystal grains on the surface of the lead alloy overlay is not rounded.

FIG. 6 is a micrograph (10,000 times) showing a crystal structure of a lead alloy overlay surface as an example of the present invention.

FIG. 7 is a photomicrograph (10,000 times) showing a crystal structure of a lead alloy overlay surface layer as a conventional example.

FIG. 8 is a schematic diagram of a conventional crystal grain pyramid.

FIG. 9 is a schematic view of a crystal grain pyramid of the present invention.

FIG. 10 is a fatigue test result.

[Explanation of symbols]

 1 Sliding bearing 4 Steel backing 5 Bearing alloy layer 6 Lead alloy overlay layer

 ─────────────────────────────────────────────────── ─── Continuation of the front page (72) Hideo Ishikawa, 1828, Minami-toyama, Komaki-shi, Aichi 1 (72) Inventor Yoshikazu Fujisawa, 1-1-1, Chuo, Wako-shi, Saitama, Ltd. (72) Inventor Makoto Tsuji, 1-4-1, Chuo, Wako-shi, Saitama, Ltd., Honda R & D Co., Ltd.

Claims (3)

[Claims] 1. In a multi-layer slide bearing in which a back metal, a bearing alloy and a lead alloy overlay are integrally laminated, crystal grains of the lead alloy overlay have a pyramidal shape with their vertices facing the mating sliding member side. , A multi-layer slide bearing having an overlay in which the vertices of each pyramidal crystal grain located on the outermost surface are rounded. 2. The surface of the lead alloy overlay is coated with a metal that lowers the melting point of lead, and is subjected to heat treatment, whereby roundness is given to the apexes of each pyramidal crystal grain located on the outermost surface. A multi-layer slide bearing having an overlay according to claim 1. 3. The metal for lowering the melting point of lead is Sn, I
A single metal selected from the group consisting of n, Sb, Bi, Ga, Tl, and Ag, or an alloy composed of two or more elements, and the amount of the coating metal is the total amount of the lead alloy overlay including the coating metal. A multi-layer plain bearing having an overlay according to claim 2, which is 3 to 30% by weight.