GB2259712A - Preparing fuel oil - water emulsion - Google Patents

Preparing fuel oil - water emulsion Download PDF

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Publication number
GB2259712A
GB2259712A GB9218253A GB9218253A GB2259712A GB 2259712 A GB2259712 A GB 2259712A GB 9218253 A GB9218253 A GB 9218253A GB 9218253 A GB9218253 A GB 9218253A GB 2259712 A GB2259712 A GB 2259712A
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GB
United Kingdom
Prior art keywords
fuel oil
burner
emulsion
steam
fuel
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
GB9218253A
Other versions
GB9218253D0 (en
Inventor
Ievan Hopkin John
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
British Steel PLC
Original Assignee
British Steel PLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from GB919119904A external-priority patent/GB9119904D0/en
Application filed by British Steel PLC filed Critical British Steel PLC
Priority to GB9218253A priority Critical patent/GB2259712A/en
Publication of GB9218253D0 publication Critical patent/GB9218253D0/en
Publication of GB2259712A publication Critical patent/GB2259712A/en
Withdrawn legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/32Liquid carbonaceous fuels consisting of coal-oil suspensions or aqueous emulsions or oil emulsions
    • C10L1/328Oil emulsions containing water or any other hydrophilic phase

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Spray-Type Burners (AREA)
  • Feeding And Controlling Fuel (AREA)

Abstract

The atomisation of a heated and pressurised heavy fuel oil in a burner is improved by emulsifying the oil with 5% or less of water by steam injection. Steam (6) and fuel oil are emulsified in an emulsifier (5) before passing to a burner 3. <IMAGE>

Description

IMPROVEMENT IN FUELS This invention relates to fuels for burners and in particular to improving the burning of fuel in burners designed for use with heavy fuel oil under pressure.
Combustion of heavy fuel oil is not an easy process to conduct efficiently and in an environmentally benign mode, owing to the fact that the heavy fuel oil usually used is the residual mixture left over when the more valuable and volatile components such as petrol and kerosene have been extracted from the crude oil at the refinery. Various techniques are employed to enable the heavy fuel oil to be burnt efficiently and generally the fuel must be preheated to a temperature of the order of llO"C and atomised. In some circumstances, where the oil is used to fire a boiler, a rotary spinning cup can be used to atomise the fuel oil, although these are associated usually with high capital and maintenance costs.Spinning cups are not generally suitable in process furnaces and often here auxiliary steam jets are used to further atomise the fuel oil after it has been ejected from the burner jet. Considerable quantities of steam can sometimes be employed in these circumstances, and figures of 0.3 to 0.4 kg of steam per kilogram of oil have been found to be necessary with high grade burners, and for burners of a lower quality equal amounts of steam and oil can be required to achieve sufficient atomisation.
It is therefore an object of the present invention to provide a means of treating heavy fuel oil so as to prove its atomisation in a burner.
According to the present invention there is provide a method of preparing a fuel oil for use in a burner to be supplied with pressurised preheated fuel by emulsifying the fuel oil with a substance which will cross its liquid vapour phase line in passing through a burner jet. The substance may be water, and the quantity of water in the emulsion may be 5% or less. The emulsion may be formed by the injection of steam into the fuel supply and the latent heat of the steam in condensing may be used to preheat the fuel supply. The emulsion may be generated and fed to a plurality of burners either associated within the same heating unit or in different heating units. The fuel oil may be a heavy fuel oil.
The invention will now be described with reference to the accompanying drawings of which Figure 1 is a schematic diagram of a fuel system feeding a burner in a process furnace, and Figure 2 is a phase diagram for water.
Turning to Figure 1, heavy fuel oil is stored in a tank 1 and is fed in the conventional manner, having been filtered by a filter 7, through a pump 2 to a burner 3. The purpose of the burner is to heat a furnace 4 which may for example contain steel slabs which are being reheated in preparation for rolling. These have not been shown. The burner 3 has been shown diagrammatically, since there are many designs of burner but in all cases to which the invention applies the fuel oil fed to the burner is under pressure. The fuel oil is released through jets in the burner into the furnace which is at substantially atmospheric pressure. The temperature in the furnace will in general be high, but the temperature of the fuel immediately after is has passed through the burner jet will not have risen substantially.Therefore the fuel oil is subjected to a relatively rapid decompression at constant temperature as it passed through the burner jet. The fuel oil has been preheated to about llO"C in the preheater 8.
So far this does not differ from normal technology. In Figure 1, however an emulsifier 5 has been inserted into the fuel supply line 9 and is fed with a supply of steam 6. The pressure of the steam is regulated to be about one bar above the pressure of 6 or 7 bars in the fuel supply line, and steam is injected into the fuel oil in a conventional manner so that it both heats the fuel oil and creates a liquid/liquid emulsion which is adjusted to be about 5% of water and 95% oil. The 5% emulsion at a pressure of six to seven bars and approximately 110-150"C is fed to the burner 3, which may be a standard burner such as can burn heavy fuel oil.
The action of the emulsion as it passes from the inside to the outside of the burner can be followed by looking at Figure 2. Figure 2 shows pressures - above atmospheric - against temperatures and line 10 divides the paper into areas 20 where water is a vapour and 21 where it is a liquid. Inspection of Figure 2 will show that the emulsion is in the range of temperatures and pressures inside rectangle A,B,C,D as fed to the burner. As it passes through the burner jets the pressure falls to substantially atmospheric. For example, for an emulsion that was at 1600C immediately before it passed through kthe burner jet the end point would be point L in figure 2 in Figure 2 and the temperature remains substantially constant as previously explained at least in the immediate facility of the burner. An instantaneous change of state of water takes place.The effect of this change of state causes the water to flash vaporise and in doing so it had been found that a very effective atomisation of the heavy fuel oil is achieved. The fuel oil has also been heated in part by the incoming steam that has created the emulsion and will burn very satisfactorily. Among the benefits that have been noticed for burners fired with such an emulsion are that the ignition lag has been reduced to almost zero, oil burn out rates have been increased and flames are shortened; the residence time of combustion products in the furnace chamber has been increased, thus in the case of a heating furnace improving the efficiency and the reducing temperature in the waste gas stack.
The reduction in the consumption of steam will be obvious from the figures already given. 5% addition of steam is used to create the emulsion; up to 100% steam was as stated previously sometimes needed to achieve adequate atomisation with a low grade burner. The emulsifier 5 is a conical injection type and it has been found possible to arrange such an emulsifier to provide a satisfactory emulsion of rates from 1800 to 3600kg of fuel oil per hour and only when the rate drops below 900kg per hour does the atomisation degrade to an unacceptable level.
Although the invention has been described by reference to a single burner fed from a single tank, one of the advantages of this method of treating fuel oil is that the supply may be emulsified at any point1 and therefore the supply to many burners from a single tank can be emulsified at a single point and the benefits of improved atomisation achieved by one modification to an existing system; the existing burners and pipe work remain intact and by the emulsifying the oil atomisation is achieved intrinsically when passing through a standard burner. It is of course possible to heat fuel as well by conventional means as by steam, and this may be necessary when it is necessary to keep the emulsion within the boundaries of the appropriate point on the phase diagram.
Although water has been used as the emulsifying liquid, and in most cases it is the clear choice, any other liquid that emulsified with oil, passed through the furnace without deleterious effects and had a high enthalpy change across the burner tip would be a candidate for use in such a system.

Claims (8)

Claims
1. A method of preparing a fuel oil for use in a burner to be supplied with pressurised preheated fuel in which the fuel oil is emulsified with a substance with will cross its liquid-vapour phase line in passing through the burner jet.
2. A method as claimed in claim 1 in which the substance is water.
3. A method as claimed in claims 1 or 2 in which the quantity of water in the emulsion is less than 5%.
4. A method as claimed in claims 2 or 3 in which the emulsion is formed by the injection of steam into the fuel supply.
5. A method as claimed in claim 4 in which the latent heat of the steam is used to preheat the fuel supply.
6. A method as claimed in any preceding claim in which an emulsion formed at a single emulsion generating point is fed to a plurality of burners.
7. A method as claimed in any preceding claim in which the fuel oil is a heavy fuel oil.
8. A method substantially as herein before described and with reference to the accompanying drawings.
GB9218253A 1991-09-18 1992-08-27 Preparing fuel oil - water emulsion Withdrawn GB2259712A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB9218253A GB2259712A (en) 1991-09-18 1992-08-27 Preparing fuel oil - water emulsion

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB919119904A GB9119904D0 (en) 1991-09-18 1991-09-18 Improvement in fuels
GB9218253A GB2259712A (en) 1991-09-18 1992-08-27 Preparing fuel oil - water emulsion

Publications (2)

Publication Number Publication Date
GB9218253D0 GB9218253D0 (en) 1992-10-14
GB2259712A true GB2259712A (en) 1993-03-24

Family

ID=26299551

Family Applications (1)

Application Number Title Priority Date Filing Date
GB9218253A Withdrawn GB2259712A (en) 1991-09-18 1992-08-27 Preparing fuel oil - water emulsion

Country Status (1)

Country Link
GB (1) GB2259712A (en)

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2327489A1 (en) * 1975-10-10 1977-05-06 Pillard Chauffage Boiler oil heating system - uses steam injection to maintain constant emulsion temp.
GB2070949A (en) * 1979-05-23 1981-09-16 Paulista Caldeiras Compac Process and method for emulsion and burning of combustible oil
FR2489170A1 (en) * 1980-09-01 1982-03-05 Minera Metalurgica Penarroya E Emulsion plant for heavy oil - esp. for mfg. homogeneous and stable emulsion of fuel oil and water which is fed to fuel burners
GB2109405A (en) * 1981-11-12 1983-06-02 Tsai Mao Wu John Fuel oil compositions and use
WO1987002376A1 (en) * 1985-10-15 1987-04-23 Petroferm Usa, Inc. Method for reducing emissions utilizing pre-atomized fuels
US4696638A (en) * 1986-07-07 1987-09-29 Denherder Marvin J Oil fuel combustion

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2327489A1 (en) * 1975-10-10 1977-05-06 Pillard Chauffage Boiler oil heating system - uses steam injection to maintain constant emulsion temp.
GB2070949A (en) * 1979-05-23 1981-09-16 Paulista Caldeiras Compac Process and method for emulsion and burning of combustible oil
FR2489170A1 (en) * 1980-09-01 1982-03-05 Minera Metalurgica Penarroya E Emulsion plant for heavy oil - esp. for mfg. homogeneous and stable emulsion of fuel oil and water which is fed to fuel burners
GB2109405A (en) * 1981-11-12 1983-06-02 Tsai Mao Wu John Fuel oil compositions and use
WO1987002376A1 (en) * 1985-10-15 1987-04-23 Petroferm Usa, Inc. Method for reducing emissions utilizing pre-atomized fuels
US4696638A (en) * 1986-07-07 1987-09-29 Denherder Marvin J Oil fuel combustion

Also Published As

Publication number Publication date
GB9218253D0 (en) 1992-10-14

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