GB2252569A - Electric connectors formed of aluminium spray coated with copper - Google Patents
Electric connectors formed of aluminium spray coated with copper Download PDFInfo
- Publication number
- GB2252569A GB2252569A GB9202213A GB9202213A GB2252569A GB 2252569 A GB2252569 A GB 2252569A GB 9202213 A GB9202213 A GB 9202213A GB 9202213 A GB9202213 A GB 9202213A GB 2252569 A GB2252569 A GB 2252569A
- Authority
- GB
- United Kingdom
- Prior art keywords
- coating
- copper
- connector
- aluminium
- copper alloy
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01R—ELECTRICALLY-CONDUCTIVE CONNECTIONS; STRUCTURAL ASSOCIATIONS OF A PLURALITY OF MUTUALLY-INSULATED ELECTRICAL CONNECTING ELEMENTS; COUPLING DEVICES; CURRENT COLLECTORS
- H01R13/00—Details of coupling devices of the kinds covered by groups H01R12/70 or H01R24/00 - H01R33/00
- H01R13/02—Contact members
- H01R13/03—Contact members characterised by the material, e.g. plating, or coating materials
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
- C23C4/04—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the coating material
- C23C4/06—Metallic material
- C23C4/08—Metallic material containing only metal elements
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
- C23C4/18—After-treatment
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01R—ELECTRICALLY-CONDUCTIVE CONNECTIONS; STRUCTURAL ASSOCIATIONS OF A PLURALITY OF MUTUALLY-INSULATED ELECTRICAL CONNECTING ELEMENTS; COUPLING DEVICES; CURRENT COLLECTORS
- H01R4/00—Electrically-conductive connections between two or more conductive members in direct contact, i.e. touching one another; Means for effecting or maintaining such contact; Electrically-conductive connections having two or more spaced connecting locations for conductors and using contact members penetrating insulation
- H01R4/58—Electrically-conductive connections between two or more conductive members in direct contact, i.e. touching one another; Means for effecting or maintaining such contact; Electrically-conductive connections having two or more spaced connecting locations for conductors and using contact members penetrating insulation characterised by the form or material of the contacting members
Abstract
A bimetallic electric connector for copper to aluminium joints is made by first forming a bulk component of aluminium (typically a stock aluminium connector) and then coating an appropriate part of its surface with copper or a conductive copper alloy (such as brass) by a thermal spray coating technique, such as plasma spraying or gas-wire metallising. The coating may be porous, in which case the use of a pore sealant e.g. an air-drying glyceride resin is recommended and this may also form a corrosion-resistant layer over the edge of the copper (or copper alloy) coating. Suitable coating and sealing techniques are commercially available. The technique is less expensive than conventional friction welding, and offers additional design flexibility. The connector illustrated in Fig. 1 comprises an aluminium tube 1 flattened at one end to form a palm 2 through which are formed holes 3, 3, the entire surface area to the left of the line 4 being coated with copper. <IMAGE>
Description
Electric Connectors and methods of making them
This invention relates to electrical connectors, more especially bimetal connectors for interconnecting aluminium and copper conductors, and methods of making them. Conductors of overhead lines and cables for the bulk distribution of electricity are normally made of aluminium (or a high-conductivity aluminium alloy, hereinafter included in the term "aluminium") on account of economic factors and its high conductivity per unit mass. On the other hand, internal wiring in consumers' premises normally uses copper conductors as they more easily form reliable connections, especially in small conductor sizes.
At some appropriate point, therefore, a transition has to be made from an aluminium conductor to a copper one.
For this purpose bimetal connectors of appropriate geometry are used, comprising an aluminium part and a part of copper or a copper alloy (such as brass). The parts need to be secured together in a way that ensures a stable low-resistance current path between them. Mechanical connections are not considered satisfactory, because of the risk of "creep" under thermal cycling resulting in the loss of contact pressure, and bonding processes involving the use of molten metal are excluded by the risk of forming brittle, high resistance Cu/Al phases at the interface and/or by the natural oxide film on the aluminium inhibiting contact.
Present practice is therefore to use bimetal connectors formed by solid-state friction-welding of aluminium and copper (or copper alloy) rods or tubes.
This is expensive and limits design flexibility as the actual aluminium/copper interface must almost inevitably be a nominally plane surface perpendicular to the axis of the initial rods/tubes.
In accordance with the invention, an electric connector comprises a bulk component made of aluminium and a coating on a part of the bulk component made of copper or a conductive copper alloy and applied by thermal spray coating.
In most cases the bulk component can be a standard connector for aluminium conductors, and the invention includes a method of making a bimetal electric connector comprising first forming a connector of aluminium and then coating part of its surface with copper or a conductive copper alloy by thermal spray coating.
Various thermal spray coating techniques can be used, such as plasma spraying, gas-wire metallising and the proprietory technique offered under the designation "Thermospray" by Metco Limited of Chobham, Surrey GU24 8RD: (and in the USA by the Metco division of Perkin-Elmer
Corp, of 1101 Prospect Avenue, Westbury NY 11590).
Coatings of pure copper are preferred, but brass might be used in some cases.
If, as is normally the case, the thermal spray coating is porous, we very much prefer to seal it by the application of a suitably penetrating high-solids liquid sealant, several of which are available and recommended for sealing thermal spray coatings used for other purposes. The sealant may also be applied as a corrosionresisting insulating layer extending across the edge of the coating, avoiding the need for the paint banding operation normally used on conventional bimetal connectors. Excess sealant may be abraded away, if found necessary, from the contact areas of the coating.
The invention can be used to make bimetal connectors of many shapes and sizes to suit particular applications.
One important style of connector comprises a tubular part for compression jointing (crimping) onto an aluminium conductor and a flat part (usually referred to as a "palm") with one or more apertures to facilitate bolting to a relatively rigid conductor or terminal of copper or brass; in this case it is preferred that the whole of the area of the palm (including the surface(s) of the hole(s), in particular) plus the transition area between the palm and the tubular part to be coated with copper or copper alloy as described. This results in the formation of a surface bimetal interface in a position where a corrosionresisting seal (either the sealant already described or a separate band of coating, such as paint) can be easily applied and easily inspected.
The invention will be further described by way of example with reference to the accompanying drawings in which figures 1 and 2 are mutually perpendicular view of one form of bimetal connector in accordance with the invention.
The connector comprises a length of electrical grade aluminium tube 1 flattened at one end to form a palm 2 through which are formed holes 3,3 (of circular or other suitable cross-section) for the reception of bolts. As so far described, the connector is a stock item for crimping to a circular aluminium conductor and bolting to other conductors of aluminium or compatible material. In accordance with the invention, the entire surface area of the connector to the left of the line 4 is coated with copper by plasma spraying to the "P55-10" process operated by Netco Limited. Following this operation, the copper coating is sealed by spraying with the 95% soldis airdrying glyceride resin solution sold by Metco Ltd under the designation Metco AG. This sealant is applied not only to seal pores throughout the copper coating but also to form an insulating and corrosion-resisting layer extending for at least a few millimetres on each side of the edge of the coating as a corrosion inhibitor. After standing in air for 15 minutes, excess sealant is wiped from the flat areas of the palm 2 with a clean dry cloth.
It may be desirable, with this particular sealant, to allow a week's storage at ambient temperature (or an hour at 1450C) after evaporation of solvent is complete) for curing, prior to use of the connector.
Claims (11)
1. An electric connector comprising a bulk component made of aluminium and a coating on a part of the bulk component made of copper or a conductive copper alloy and applied by thermal spray coating.
2. An electric connector in accordance with Claim 1 comprising a tubular part for compression jointing onto an aluminium conductor and a flat apertured palm and in which the said coating is applied to the whole of the area of the palm.
3. A connector as claimed in Claim 1 or Claim 2 in which the coating is applied by plasma spraying.
4. A connector as claimed in Claim 1 or Claim 2 in which the coating is applied by gas-wire metallising.
5. A method of making a bimetal electric connector comprising first forming a connector of aluminium and then coating part of its surface with copper or a conductive copper alloy by thermal spray coating.
6. A method as claimed in Claim 5 in which the copper or conductive copper alloy is applied by plasma spraying.
7. A method as claimed in Claim 5 in which the copper or conductive copper alloy is applied by gas-wire metallising.
8. A connector as claimed in any one of the preceding claims in which the said coating is porous and is sealed by application of a penetrating high-solids liquid sealant.
9. A connector as claimed in claim 8 in which the sealant also forms a corrosion resistant layer over the edge of the said coating.
10. A bimetal electric connector substantially as described with reference to the accompanying drawings.
11. A method of making a bimetal connector substantially as hereinbefore described by way of example.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB919102562A GB9102562D0 (en) | 1991-02-06 | 1991-02-06 | Electric connectors and methods of making them |
Publications (2)
Publication Number | Publication Date |
---|---|
GB9202213D0 GB9202213D0 (en) | 1992-03-18 |
GB2252569A true GB2252569A (en) | 1992-08-12 |
Family
ID=10689648
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB919102562A Pending GB9102562D0 (en) | 1991-02-06 | 1991-02-06 | Electric connectors and methods of making them |
GB9202213A Withdrawn GB2252569A (en) | 1991-02-06 | 1992-02-03 | Electric connectors formed of aluminium spray coated with copper |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB919102562A Pending GB9102562D0 (en) | 1991-02-06 | 1991-02-06 | Electric connectors and methods of making them |
Country Status (5)
Country | Link |
---|---|
AU (1) | AU1038092A (en) |
FR (1) | FR2672439A1 (en) |
GB (2) | GB9102562D0 (en) |
IT (1) | IT1254297B (en) |
ZA (1) | ZA92519B (en) |
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2002038245A1 (en) * | 2000-11-13 | 2002-05-16 | N.V. Bekaert S.A. | Electrical contact system |
EP1303007A2 (en) * | 2001-10-09 | 2003-04-16 | Delphi Technologies, Inc. | Kinetic sprayed electrical contacts on conductive substrates |
WO2004042119A1 (en) * | 2002-11-07 | 2004-05-21 | Outokumpu Oyj | A method for obtaining a good contact surface on an electrode support bar and a support bar |
WO2004042118A1 (en) * | 2002-11-07 | 2004-05-21 | Outokumpu Oyj | Method for the formation of a good contact surface on a cathode support bar and support bar |
WO2004042121A1 (en) * | 2002-11-07 | 2004-05-21 | Outokumpu Oyj | Method for the formation of a good contact surface on an aluminium support bar and a support bar |
WO2004042120A1 (en) * | 2002-11-07 | 2004-05-21 | Outokumpu Oyj | Method for obtaining a good contact surface on an electrolysis cell busbar and busbar |
WO2010012515A1 (en) * | 2008-08-01 | 2010-02-04 | Auto-Kabel Managementgesellschaft Mbh | Motor vehicle conductor connection element |
CN102859799A (en) * | 2010-04-23 | 2013-01-02 | 日本发条株式会社 | Conductive member and production method therefor |
CN109326899A (en) * | 2018-10-31 | 2019-02-12 | 昆山徳可汽车配件有限公司 | A kind of ultrasonic bonding of aluminum steel beam Copper-Aluminum compound terminal and its manufacturing process |
CN112736501A (en) * | 2020-12-15 | 2021-04-30 | 广东电网有限责任公司江门供电局 | Copper-aluminum integrated wire clamp and preparation method thereof |
Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB979746A (en) * | 1962-07-27 | 1965-01-06 | Westinghouse Electric Corp | Surface construction and method and means for making same |
GB1039633A (en) * | 1963-08-27 | 1966-08-17 | Metco Inc | Improvements in flame spraying |
GB1143081A (en) * | 1965-03-31 | 1969-02-19 | Aluminium Wire & Cable Company | Improvements in or relating to electrical conductor terminals |
GB1238701A (en) * | 1967-09-28 | 1971-07-07 | ||
GB1449162A (en) * | 1973-05-25 | 1976-09-15 | Wellworthy Ltd | Method for reinforcing pistons |
GB1474841A (en) * | 1974-04-22 | 1977-05-25 | Telemecanique Electrique | Socket for busbars |
GB1489510A (en) * | 1976-05-28 | 1977-10-19 | Delta Enfield Cables Ltd | Method of manufacturing cable conductors |
GB1521455A (en) * | 1975-12-31 | 1978-08-16 | Poudres & Explosifs Ste Nale | Fibre-reinforced metal panels and production thereof |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE7033692U (en) * | 1969-09-18 | 1970-12-23 | Asea Ab | CONNECTOR FOR ELECTRICAL CABLES. |
-
1991
- 1991-02-06 GB GB919102562A patent/GB9102562D0/en active Pending
-
1992
- 1992-01-22 AU AU10380/92A patent/AU1038092A/en not_active Abandoned
- 1992-01-24 ZA ZA92519A patent/ZA92519B/en unknown
- 1992-02-03 GB GB9202213A patent/GB2252569A/en not_active Withdrawn
- 1992-02-04 FR FR9201202A patent/FR2672439A1/en not_active Withdrawn
- 1992-02-05 IT ITRM920078A patent/IT1254297B/en active
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB979746A (en) * | 1962-07-27 | 1965-01-06 | Westinghouse Electric Corp | Surface construction and method and means for making same |
GB1039633A (en) * | 1963-08-27 | 1966-08-17 | Metco Inc | Improvements in flame spraying |
GB1143081A (en) * | 1965-03-31 | 1969-02-19 | Aluminium Wire & Cable Company | Improvements in or relating to electrical conductor terminals |
GB1238701A (en) * | 1967-09-28 | 1971-07-07 | ||
GB1449162A (en) * | 1973-05-25 | 1976-09-15 | Wellworthy Ltd | Method for reinforcing pistons |
GB1474841A (en) * | 1974-04-22 | 1977-05-25 | Telemecanique Electrique | Socket for busbars |
GB1521455A (en) * | 1975-12-31 | 1978-08-16 | Poudres & Explosifs Ste Nale | Fibre-reinforced metal panels and production thereof |
GB1489510A (en) * | 1976-05-28 | 1977-10-19 | Delta Enfield Cables Ltd | Method of manufacturing cable conductors |
Cited By (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2002038245A1 (en) * | 2000-11-13 | 2002-05-16 | N.V. Bekaert S.A. | Electrical contact system |
EP1303007A2 (en) * | 2001-10-09 | 2003-04-16 | Delphi Technologies, Inc. | Kinetic sprayed electrical contacts on conductive substrates |
EP1303007A3 (en) * | 2001-10-09 | 2004-02-18 | Delphi Technologies, Inc. | Kinetic sprayed electrical contacts on conductive substrates |
EA008524B1 (en) * | 2002-11-07 | 2007-06-29 | Отокумпу Оюй | Method for the formation of a good contact surface on an aluminium support bar and a support bar |
WO2004042118A1 (en) * | 2002-11-07 | 2004-05-21 | Outokumpu Oyj | Method for the formation of a good contact surface on a cathode support bar and support bar |
WO2004042121A1 (en) * | 2002-11-07 | 2004-05-21 | Outokumpu Oyj | Method for the formation of a good contact surface on an aluminium support bar and a support bar |
WO2004042120A1 (en) * | 2002-11-07 | 2004-05-21 | Outokumpu Oyj | Method for obtaining a good contact surface on an electrolysis cell busbar and busbar |
EA008523B1 (en) * | 2002-11-07 | 2007-06-29 | Отокумпу Оюй | Method for the formation of a good contact surface on a cathode support and support bar |
WO2004042119A1 (en) * | 2002-11-07 | 2004-05-21 | Outokumpu Oyj | A method for obtaining a good contact surface on an electrode support bar and a support bar |
US7425257B2 (en) | 2002-11-07 | 2008-09-16 | Outotec Oyj | Method for the formation of a good contact surface on a cathode support bar and support bar |
US7504009B2 (en) | 2002-11-07 | 2009-03-17 | Outotec Oyj | Method for the formation of a good contact surface on an aluminium support bar and a support bar |
WO2010012515A1 (en) * | 2008-08-01 | 2010-02-04 | Auto-Kabel Managementgesellschaft Mbh | Motor vehicle conductor connection element |
US8658901B2 (en) | 2008-08-01 | 2014-02-25 | Auto Kabel Managementgesellschaft Mbh | Motor vehicle conductor connection element |
CN102859799A (en) * | 2010-04-23 | 2013-01-02 | 日本发条株式会社 | Conductive member and production method therefor |
CN109326899A (en) * | 2018-10-31 | 2019-02-12 | 昆山徳可汽车配件有限公司 | A kind of ultrasonic bonding of aluminum steel beam Copper-Aluminum compound terminal and its manufacturing process |
CN112736501A (en) * | 2020-12-15 | 2021-04-30 | 广东电网有限责任公司江门供电局 | Copper-aluminum integrated wire clamp and preparation method thereof |
Also Published As
Publication number | Publication date |
---|---|
GB9202213D0 (en) | 1992-03-18 |
IT1254297B (en) | 1995-09-14 |
GB9102562D0 (en) | 1991-03-27 |
ITRM920078A0 (en) | 1992-02-05 |
AU1038092A (en) | 1992-08-13 |
ITRM920078A1 (en) | 1993-08-05 |
FR2672439A1 (en) | 1992-08-07 |
ZA92519B (en) | 1992-12-30 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
WAP | Application withdrawn, taken to be withdrawn or refused ** after publication under section 16(1) |