GB2217735A - Simultaneous dyeing and bleaching of human hair using two-component formulation - Google Patents

Simultaneous dyeing and bleaching of human hair using two-component formulation Download PDF

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Publication number
GB2217735A
GB2217735A GB8909508A GB8909508A GB2217735A GB 2217735 A GB2217735 A GB 2217735A GB 8909508 A GB8909508 A GB 8909508A GB 8909508 A GB8909508 A GB 8909508A GB 2217735 A GB2217735 A GB 2217735A
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GB
United Kingdom
Prior art keywords
component
formulation
weight
human hair
treatment
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
GB8909508A
Other versions
GB8909508D0 (en
GB2217735B (en
Inventor
Thomas Oelschlaeger
Wolfgang Wolff
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hans Schwarzkopf and Henkel GmbH
Original Assignee
Hans Schwarzkopf and Henkel GmbH
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Application filed by Hans Schwarzkopf and Henkel GmbH filed Critical Hans Schwarzkopf and Henkel GmbH
Publication of GB8909508D0 publication Critical patent/GB8909508D0/en
Publication of GB2217735A publication Critical patent/GB2217735A/en
Application granted granted Critical
Publication of GB2217735B publication Critical patent/GB2217735B/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/22—Peroxides; Oxygen; Ozone
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A61K8/731—Cellulose; Quaternized cellulose derivatives
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • A61K8/8147—Homopolymers or copolymers of acids; Metal or ammonium salts thereof, e.g. crotonic acid, (meth)acrylic acid; Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/10—Preparations for permanently dyeing the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/80—Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
    • A61K2800/88—Two- or multipart kits

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Emergency Medicine (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Cosmetics (AREA)

Description

17 -7.3 5 11w V Two-Component Formulation for tJhe Treatment of Human Hair
The invention relates to a two-component formulation for preparation of a pasty spreadable formulation for the treatment 6f human hair, a pasty spreadable formulation for the treatment of human hair, and a method for the treatment of human hair.
The invention seeks to provide a storable two-component formulation which, after being combined by mixing, is in the form of a pasty spreadable preparation (formulation) for the treatment of human hair. The preparation spread onto the hair seeks to produce coloured highlighted strands on dark human hair without bleaching or blonding operations having first taken place as is conventional. The present invention also seeks to provide a combination of the two operations previously required, and which are carried out separately, Le combining 1. bleaching or dyeing blond and 2. dyeing, into a single operation. The present invention further seeks to provide a method for the treatment of human hair which eliminates the need for the tvo separate bleaching or dyeing blond and dyeing operations.
According to one aspect of the invention there is provided a twocomponent formulation for the preparation of a pasty spreadable formulation for the treatment of human hair, comprising A. a pulverulent component comprising a) b) C) at least one wetting agent at least one inorganic andlor organic thickening agent, at least one dyestuff, d) at least one solid per-compound, e) at least one alkalizing agent, and optionally f) customary additives, and 9) complexing agents, component A being in anhydrous form, and a liquid component, comprising h) an aqueous hydrogen peroxide solution with a hydrogen peroxide content of 5 to 18% by weight, and optionally 1) complexing agents.
According to another aspect of the invention there is provided a pasty spreadable formulation for the treatment of human hair, comprising a mixture of components A and B. According to another aspect of the invention there is provided a method for the treatment of human hair, wherein the formulation comprising a mixture of components A and B is spread onto the hair; the hair, which is bleached and dyed in one step by the spreading and action of the formulation, is washed and after-treated in the customary manner.
According to a further aspect of the invention there is provided a method for the preparation of a pasty spreadable formulation, wherein components A and B Are mixed together.
Various preferred features and embodiments of the invention will now be described by way of non-limiting example.
The two-component formulation consists of a first pulverulent component A and a second liquid component B, which are conveniently each prepared and packaged separately and can be processed by intensive mixing, just before use, to a pasty spreadable formulation for the treatment of human hair. The method for the treatment of human hair can subsequently be performed.
Examples of the constituents of the first pulverulent component A are described below.
Wetting agents which can be used include conventional wetting agents which are used in cosmetics and are in dry pulverulent form. Preferred wetting agents of this type are: sodium stearate, aluminium distearate, fatty acid condensation products based on saturated or unsaturated fatty acids of various chain lengths and taurine, methyltaurine or hydroxyethanesulphonic acid, fatty -acid ethionate, sodium salt, and sodium laurylsulphate, either individually or preferably as a mixture, ahd the amount thereof in component A is preferably 1 to 20% by weight.
Inorganic and/or organic thickening agents which can be used and which are preferably present in component A in amounts of 0.1 to 10% by weight, include thickening agents conventionally used in cosmetics, such as disperse silicic acid, hydroxypropy1cellulose and derivatives thereof.
t 1 Especially preferred are acrylic acid polymers and derivatives thereof.
Dyestuffs which can be used include dyestuffs permitted for dyeing hair, examples of which may include as aromatic nitro dyestuffs, 1,4 diamino-2-nitrobenzene, 3-nitro-4-(3-hydro xypropyl)-aminophenol, 142 hydroxyethylamino)-2-nitro-4-aminc)benzene, 4-amino-2-nitrophenol, 4 nitro-o-phenylenediamine, p-nitro-o-aminophenal, 1-amino-2-nitro-4-bis (2-hydroxyethyl)-aminobenzene, 1,4-di-(2-hydroxyethylamino)-2 nitrobenzene, 3-nitro-4-aminophenol, HC Blue 2 and HC Yellow 4; azo dyestuffs, such as Direct Violet 51, Basic Yellow 57, Basic Blue 99, Basic Red 22, Basic Brown 16, Basic Brown 17, Basic Red 76 and Basic Yellow 57, and anthraquinone dyestuffs, such as Solvent Violet 12 and Disperse Blue 1.
The dyestuffs are preferably present in component A in an amount of 0.1 to 90% by weight.
Examples of solid per-compounds, which generally contain two oxygen atoms linked together and which should be water-soluble but should not be fatsoluble in order to protect the scalp, include, for example, alk2li metal and/or ammonium persulphates, percarbonates, perborates and peroxides, which are preferably present in component A in amounts of 1 to 60% by weight.
Pulverulent dry alkalizing agents which can be used include, for example, alkali metal and alkaline earth metal hydroxides, alkali metal silicates and alkali metal carbonates. Component A preferably contains enough alkalizing agent for the pH to be between 10 and 12 after mixing with component B. Customary additives which may be- used include, for example, aluminiurn silicates, magnesium silicates, calcium carbonate, magnesium carbonate, talc, alkali metal and ammonium pyrophosphates and alkali metal and ammonium hydrogen or dihydrogen phosphates, either individually or as a mixture.
The amount in the mixture of these additives in component A is preferably between zero and 50% by weight.
Complexing agents which may be used include ethylenediaminetetraacetic acid and its alkali metal and ammonium salts.
The _liquid component comprises an 'aqueous hydrogen peroxide solution with a hydrogen peroxide content of 5 to 18% by weight, and optionally complexing agents and preferably the aqueous hydrogen peroxide solution has a hydrogen peroxide content of about 6% by weight.
The pasty spreadable formulation preferably comprises 30 to 35% by weight of component A and 70 to 65% by weight of component B, wherein the percentages by weight must make up 100% by weight.
The invention will now be illustrated with reference to the following nonlimiting examples:
Example 1
Component A a) Sodium stearate al) Aluminium distearate a2) Sodium lauryIsulphate (Duponol C) b) Disperse silicic acid (Aerosil 200) bl) 0 d) dj) e) f) Hydroxypropylcellulose Basic Red 22 (Maxilonrot BL) Potassium persulphate Ammonium persulphate Sodium metasilicate Disadium salt of ethylenediaminetetraacetic acid Component B Water Hydrogen peroxide (100% strength) 11. 0 g 2.7 g 1.0 g 9.1 g 2.7 g 10.0 g 31.5 g 19.0 g 12.0 g 1.0 a 100.0 cl 188 g ____12_g Ready-to-use pasty spreadable formulation for the treatment of human hair g of the component A obtained above may be mixed thoroughly with 200 g of the component B obtained above until a homogeneous preparation is present, which may be used immediately for the treatment of human hair.
it z j 1 j i 1 1 1 Example 2
Component A a) Fatty acid isothionate, sodium salt (Hostapon KA) b) Acrylic acid polymer c) HC Yellow 4 d) Potassium persulphate di) Sodium persulphate e) Sodium carbonate f) Sodium pyrophosphate f l) White talc f 2) Magnesium carbonate (Carbopol 934) C) Diammonium hydrogen phosphate Component B Hydrogen peroxide solution containing: Water Hydrogen peroxide 0.5 g 2.0 9 20.0 9 18.0 9 10.0 9 5.0 g 8.0 9 25.0 g 8.0 g 3.5 g 100.0 q 200. 0 g 188.0 g 12. 0 g 200.0 q Ready-to-use pasty spreadable formulation for the treatment of human hair g of the component A obtained above may be mixed thoroughly with 200 g of the component B obtained above until a homogeneous preparation is present, which may be used immediately for the treatment of human hair. The hair may be conveniently treated with the formulation in the desired zones. The formulation may in general be allowed to act for about 30 to 45 minutes.
The hair may then be rinsed with water, dried and styled in the usual manner.
A

Claims (10)

CLAIMS:
1. A two-component formulation for the preparation of a pasty spreadable formulation for the treatment of human hair, comprising A. a pulverulent component comprising a) at least one wetting agent b) at least one inorganic and/or organic thickening agent, C) at least one dyestuff, d) at least one solid per-compound, e) at least one alkalizing agent, and optionally f) customary additives, and g) complexing agents, component A being in anhydrous form, and B. a liquid component, comprising h) an aqueous hydrogen peroxide solution with a hydrogen peroxide content.of 5 to 18% by weight, and optionally 1) complexing agents.
2. A two-component formulation according to claim 1 wherein the aqueous hydrogen peroxide solution of component B has a hydrogen peroxide content of about 6% by weight.
3. A pasty spreadable formulation for the treatment of human hair, comprising a mixture of components A and B according to either of claims 1 or 2.
4. A formulation according to claim 3 comprising 30 to 35% by weight of component A and 70 to 65% by weight of component B, wherein the percentages by weight must make up 100% by weight.
5. A method for the treatment of human hair, wherein the formulation according to either of claims 3 and 4 is spread onto the hair; the hair, which is bleached and dyed in one step by the spreading and action of the formulation, is washed and after-treated in the customary manner.
1 W.
_QV 1
6. A method for the preparation of a pasty spreadable formulation according to either of claims 3 and 4, wherein components A and B according to either of claims I and 2 are mixed together.
7. A two-component formulation substantially as herein described with reference to the accompanying examples.
8. A pasty spreadable formulation substantially as herein described with reference to the accompanying examples.
9. A method for the treatment of human hair substantially as herein described with reference to the accompanying examples.
10. A method for the preparation of a pasty spreadable formulation substantially as herein described with reference to the accompanying examples.
PubUshed 1989 atThe Patent O=oe. State House, 86,71 High HolbonnLondon WC1R4-PP.Pwtheroopies be obtLtnedfromTb. %Ient Wes Braneb. St Mary Cray, o--oLr4ton, Kent BM 3"' Printed by Mult1Plex techniques ltId, St CMY, Rent. Oon. 1187OMM.
GB8909508A 1988-04-30 1989-04-26 Two-component formulation for the treatment of human hair Expired - Fee Related GB2217735B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19883814685 DE3814685A1 (en) 1988-04-30 1988-04-30 TWO-COMPONENT PREPARATION FOR THE PRODUCTION OF A POWDERED, APPLICABLE PREPARATION FOR THE TREATMENT OF HUMAN HAIR

Publications (3)

Publication Number Publication Date
GB8909508D0 GB8909508D0 (en) 1989-06-14
GB2217735A true GB2217735A (en) 1989-11-01
GB2217735B GB2217735B (en) 1992-08-12

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Family Applications (1)

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GB8909508A Expired - Fee Related GB2217735B (en) 1988-04-30 1989-04-26 Two-component formulation for the treatment of human hair

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JP (1) JPH0249716A (en)
DE (1) DE3814685A1 (en)
FR (1) FR2630646B1 (en)
GB (1) GB2217735B (en)

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5688291A (en) * 1996-06-27 1997-11-18 L'avante Garde, Inc. Composition for simultaneously lightening and coloring hair
GB2386068A (en) * 2001-03-20 2003-09-10 Procter & Gamble Oxidative treatment of hair with reduced hair damage
EP1372581A1 (en) * 2001-03-19 2004-01-02 L'Avant Garde Inc. Composition for simultaneously lightening and coloring hair utilizing bleach-stable acid and basic dyes
US7922777B2 (en) 2008-12-19 2011-04-12 L'ORéAL S.A. Lightening and dyeing of human keratin fibers using an anhydrous composition comprising a monoethyanolamine/basic amino acid mixture, and device therefor
FR3060350A1 (en) * 2016-12-20 2018-06-22 L'oreal CAPILLARY COLORING COMPOSITION COMPRISING OXIDATION DYE, OXIDIZING AGENT, (BI) CARBONATE, AND AT LEAST 0.5% BY WEIGHT OF POLYPHOSPHORIC DERIVATIVE
FR3060348A1 (en) * 2016-12-20 2018-06-22 L'oreal CAPILLARY CLARIFICATION COMPOSITION COMPRISING AN OXIDIZING AGENT, CARBONATE, AND AT LEAST 0.5% BY WEIGHT OF POLYPHOSPHORIC DERIVATIVE
US11344492B2 (en) 2020-09-14 2022-05-31 Milliken & Company Oxidative hair cream composition containing polymeric colorant
US11351106B2 (en) 2020-09-14 2022-06-07 Milliken & Company Oxidative hair cream composition containing thiophene azo colorant
US11691035B2 (en) 2008-12-19 2023-07-04 L'oreal Oxidizing composition for the treatment of keratin fibers comprising at least one cationic polymer, at least one fatty amide and at least one anti-oxygen agent
US12064500B2 (en) 2016-12-20 2024-08-20 L'oreal Hair lightening composition comprising hydrogen peroxide, a peroxygenated salt, a carbonate and at least one polyphosphorus derivative

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DE3824241A1 (en) * 1988-07-16 1990-01-18 Wella Ag FIXING AGENT AND METHOD FOR PERMANENT HAIR FORMING
DE69728038T2 (en) * 1996-04-25 2005-02-17 L'oreal Process for dyeing keratin fibers with dye precursors of oxidation dyes and powdered direct dyes
CA2224627A1 (en) * 1997-11-06 1999-05-06 Joseph Lizzi Hair and skin treatment product
DE19962869A1 (en) * 1999-12-24 2001-06-28 Henkel Kgaa Use of optionally hydrated silica compounds to reduce oxidative damage to keratinic fibers, especially during bleaching and oxidation dyeing of hair
JP2001316231A (en) * 2000-05-11 2001-11-13 Kao Corp Hair dye
MXPA04009817A (en) † 2002-04-11 2004-12-13 Oreal Composition for the oxidation dyeing of human keratinous fibres.
FR2848843B1 (en) * 2002-12-20 2005-07-01 Oreal PULP ANHYDROUS COMPOSITION FOR THE DECOLORATION AND SIMULTANEOUS COLORING OF HUMAN KERATIN FIBERS.
DE10339164A1 (en) * 2003-08-26 2005-03-31 Henkel Kgaa Stabilization of hydrogen peroxide during the dissolution of alkalizing solids in hydrogen peroxide-containing systems
DE102004049600A1 (en) * 2004-10-12 2006-04-20 Wella Ag Cationic Indazolinthiazolazofarbstoffe containing colorants
DE102006043920A1 (en) * 2006-09-14 2008-03-27 Henkel Kgaa Hydrogen peroxide activation with diones
FR2925307B1 (en) 2007-12-21 2009-12-18 Oreal METHOD FOR DIRECT LIGHTENING OR OXIDATION COLORING IN THE PRESENCE OF A PARTICULAR ORGANIC AMINE AND DEVICE
FR2925311B1 (en) 2007-12-21 2009-12-18 Oreal PROCESS FOR LIGHTENING HUMAN KERATINOUS FIBERS USING ANHYDROUS COMPOSITION AND A PARTICULAR ORGANIC AMINE AND APPROPRIATE DEVICE
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FR2940107B1 (en) 2008-12-19 2011-03-18 Oreal PROCESS FOR LIGHTENING KERATINIC MATERIALS USING AN EMULSION COMPRISING AN ALKALI AGENT AND AN OXIDIZING COMPOSITION
BRPI0911109B8 (en) 2008-12-19 2017-05-30 Oreal staining or bleaching process of human keratin materials and multi-compartment device
US7927381B2 (en) 2008-12-19 2011-04-19 L'oreal S.A. Process for lightening or lightening direct dyeing or oxidation dyeing in the presence of an aqueous composition comprising at least one fatty substance, and device
FR2940100B1 (en) 2008-12-19 2011-02-18 Oreal KERATIN FIBER OXIDATION DYE COMPOSITION COMPRISING A FATTY BODY AND N, N BIS (BETA-HYDROXYETHYL) -PARAPHENYLENE DIAMINE
FR2940105B1 (en) 2008-12-19 2011-04-08 Oreal COMPOSITION COMPRISING A PARTICULAR OXYETHYLENE FIBER AND SURFACTANT, METHOD FOR COLORING THE SAME AND DEVICES THEREFOR
FR2940108B1 (en) 2008-12-19 2011-04-29 Oreal METHOD FOR LIGHTENING KERATINIC MATERIALS USING ANHYDROUS COMPOSITION COMPRISING AN ALKALI AGENT AND AN OXIDIZING COMPOSITION
US7918902B2 (en) 2008-12-19 2011-04-05 L'oreal S.A. Process for lightening or process for direct dyeing or oxidation dyeing of keratin fibers in the presence of at least one ammonium salt and device therefor
FR2940090B1 (en) 2008-12-19 2011-02-25 Oreal OXIDIZING COMPOSITION FOR THE TREATMENT OF KERATIN FIBERS COMPRISING OIL, FATTY ALCOHOL AND OXYALKYLENE FATTY ALCOHOL
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JP5815205B2 (en) 2008-12-19 2015-11-17 ロレアル Method for lightening or direct lightening or oxidation dyeing in the presence of organic amine and inorganic base, and device therefor
FR2940104B1 (en) 2008-12-19 2011-08-19 Oreal HAIR PROCESSING METHOD USING DIRECT EMULSION COMPRISING OXIDIZING AGENT AND COMPOSITION CONTAINING ALKALINE AGENT
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FR2954127B1 (en) 2009-12-22 2015-10-30 Oreal COLORING AND / OR DECOLOURING AGENT OF TWO-PART KERATINOUS FIBERS, COMPRISING A BODY AND A SEQUESTRING AGENT.
FR2954159B1 (en) 2009-12-22 2012-02-10 Oreal A KERATIN FIBER COLORING AND / OR DECOLOURING AGENT COMPRISING A COMPOSITION COMPRISING AN ALKALINIZING AGENT AND AN ANHYDROUS COMPOSITION COMPRISING AN OXIDANT, EITHER OF THE COMPOSITIONS CONTAINING A FATTY BODY

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Cited By (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5688291A (en) * 1996-06-27 1997-11-18 L'avante Garde, Inc. Composition for simultaneously lightening and coloring hair
WO1997049379A1 (en) * 1996-06-27 1997-12-31 L'avant Garde Inc. Composition for simultaneously lightening and coloring hair
EP1372581A1 (en) * 2001-03-19 2004-01-02 L'Avant Garde Inc. Composition for simultaneously lightening and coloring hair utilizing bleach-stable acid and basic dyes
EP1372581A4 (en) * 2001-03-19 2005-04-20 Avant Garde Inc L Composition for simultaneously lightening and coloring hair utilizing bleach-stable acid and basic dyes
US7189265B2 (en) 2001-03-19 2007-03-13 L'avant Garde, Inc. Composition for simultaneously lightening and coloring hair utilizing bleach-stable acid and basic dyes
GB2386068A (en) * 2001-03-20 2003-09-10 Procter & Gamble Oxidative treatment of hair with reduced hair damage
US7922777B2 (en) 2008-12-19 2011-04-12 L'ORéAL S.A. Lightening and dyeing of human keratin fibers using an anhydrous composition comprising a monoethyanolamine/basic amino acid mixture, and device therefor
US11691035B2 (en) 2008-12-19 2023-07-04 L'oreal Oxidizing composition for the treatment of keratin fibers comprising at least one cationic polymer, at least one fatty amide and at least one anti-oxygen agent
FR3060348A1 (en) * 2016-12-20 2018-06-22 L'oreal CAPILLARY CLARIFICATION COMPOSITION COMPRISING AN OXIDIZING AGENT, CARBONATE, AND AT LEAST 0.5% BY WEIGHT OF POLYPHOSPHORIC DERIVATIVE
WO2018114873A1 (en) * 2016-12-20 2018-06-28 L'oreal Hair lightening composition comprising an oxidizing agent, a carbonate and at least 5% by weight of polyphosphorus derivative
FR3060350A1 (en) * 2016-12-20 2018-06-22 L'oreal CAPILLARY COLORING COMPOSITION COMPRISING OXIDATION DYE, OXIDIZING AGENT, (BI) CARBONATE, AND AT LEAST 0.5% BY WEIGHT OF POLYPHOSPHORIC DERIVATIVE
US12064500B2 (en) 2016-12-20 2024-08-20 L'oreal Hair lightening composition comprising hydrogen peroxide, a peroxygenated salt, a carbonate and at least one polyphosphorus derivative
US11344492B2 (en) 2020-09-14 2022-05-31 Milliken & Company Oxidative hair cream composition containing polymeric colorant
US11351106B2 (en) 2020-09-14 2022-06-07 Milliken & Company Oxidative hair cream composition containing thiophene azo colorant
US11458089B2 (en) 2020-09-14 2022-10-04 Milliken & Company Oxidative hair cream composition containing polymeric colorant
US11633344B2 (en) 2020-09-14 2023-04-25 Miliken & Company Oxidative hair cream composition containing thiophene azo colorant
US11684560B2 (en) 2020-09-14 2023-06-27 Milliken & Company Oxidative hair cream composition containing polymeric colorant
US12042556B2 (en) 2020-09-14 2024-07-23 Milliken & Company Oxidative hair cream composition containing polymeric colorant

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GB8909508D0 (en) 1989-06-14
JPH0249716A (en) 1990-02-20
GB2217735B (en) 1992-08-12
DE3814685C2 (en) 1990-08-16
FR2630646A1 (en) 1989-11-03
FR2630646B1 (en) 1993-07-23
DE3814685A1 (en) 1988-09-01

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