GB2177255A - VLSI MOSFET circuits using refractory metal and/or refractory metal silicide - Google Patents

VLSI MOSFET circuits using refractory metal and/or refractory metal silicide Download PDF

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Publication number
GB2177255A
GB2177255A GB8606040A GB8606040A GB2177255A GB 2177255 A GB2177255 A GB 2177255A GB 8606040 A GB8606040 A GB 8606040A GB 8606040 A GB8606040 A GB 8606040A GB 2177255 A GB2177255 A GB 2177255A
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gate
layer
refractory metal
silicide
regions
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GB8606040A
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GB8606040D0 (en
GB2177255B (en
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Vu Quoc Ho
Hussein Mostafa Naguib
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Nortel Networks Ltd
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Northern Telecom Ltd
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
    • H01L29/66Types of semiconductor device ; Multistep manufacturing processes therefor
    • H01L29/66007Multistep manufacturing processes
    • H01L29/66075Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials
    • H01L29/66227Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials the devices being controllable only by the electric current supplied or the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched, e.g. three-terminal devices
    • H01L29/66409Unipolar field-effect transistors
    • H01L29/66477Unipolar field-effect transistors with an insulated gate, i.e. MISFET
    • H01L29/66568Lateral single gate silicon transistors
    • H01L29/66575Lateral single gate silicon transistors where the source and drain or source and drain extensions are self-aligned to the sides of the gate
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
    • H01L21/18Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
    • H01L21/28Manufacture of electrodes on semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/268
    • H01L21/283Deposition of conductive or insulating materials for electrodes conducting electric current
    • H01L21/285Deposition of conductive or insulating materials for electrodes conducting electric current from a gas or vapour, e.g. condensation
    • H01L21/28506Deposition of conductive or insulating materials for electrodes conducting electric current from a gas or vapour, e.g. condensation of conductive layers
    • H01L21/28512Deposition of conductive or insulating materials for electrodes conducting electric current from a gas or vapour, e.g. condensation of conductive layers on semiconductor bodies comprising elements of Group IV of the Periodic Table
    • H01L21/28518Deposition of conductive or insulating materials for electrodes conducting electric current from a gas or vapour, e.g. condensation of conductive layers on semiconductor bodies comprising elements of Group IV of the Periodic Table the conductive layers comprising silicides
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2924/00Indexing scheme for arrangements or methods for connecting or disconnecting semiconductor or solid-state bodies as covered by H01L24/00
    • H01L2924/0001Technical content checked by a classifier
    • H01L2924/0002Not covered by any one of groups H01L24/00, H01L24/00 and H01L2224/00

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  • Engineering & Computer Science (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Manufacturing & Machinery (AREA)
  • Computer Hardware Design (AREA)
  • Ceramic Engineering (AREA)
  • Electrodes Of Semiconductors (AREA)
  • Insulated Gate Type Field-Effect Transistor (AREA)
  • Thin Film Transistor (AREA)

Abstract

In the fabrication of VLSI MOSFET circuits, the sheet resistance of polysilicon gates and interconnects and the sheet resistance of shallow source and drain junctions are reduced by using refractory metal or refractory metal silicide. To optimize the use of refractory metal or silicide at the junction and gate regions, the refractory metal or silicide (26) at the gate (24, 26) is made thicker than a junction silicide layer (30) the source and drain (16, 18) by first forming a gate (24, 26) having a refractory metal or silicide content and subsequently forming a thin layer (30, 32) of refractory metal or silicide over the source, drain, and gate regions. <IMAGE>

Description

SPECIFICATION VLSI mosfet circuits using refractory metal and/or refractory metal silicide This invention relates to the fabrication of very large scale integrated (VLSI) metal oxide semiconductor field effect transistor (MOSFET) circuits.
In the fabrication of high performance VLSI MOSFET circuits polycrystalline silicon (polysilicon) is normally used for gate interconnect regions. However, the high resistivity of polysilicon gives rise to RC time delays which limit device performance. Also, as the MOSFETs are scaled down to the sub-micron regime, the shallow source and drain junctions result in high sheet resistances.
To reduce the delay due to high sheet resistance of polysilicon gate and interconnects, refractory metal silicide or composite refractory metal silicide/polysilicon compositions have been proposed for gate and interconnects. ("1 um MOSFET VLSI technology: part VII - metal silicide interconnection technology - a future perspective", IEEE, Journal of Solid State Circuits, SC-14, page 291, 1971, Crowder et a).
In addition, to lower the sheet resistance of shallow source and drain junctions, the silicidation of source, drain and polysilicon gate has been attempted and the resulting so-called SALICIDE structure is known, ("An optimally designed process for sub-micron MOSFETS'', IEDM, Technical Digest, page 647, 1981, Shibata et al). In this SALICIDE technology, source, drain and polysilicon gates of MOS FETS are formed with a silicide layer at the same time. Sidewall oxide regions are used to separate the source and drain from the gate.
In the silicidation process, a noble or refractory metal is deposited over the entire surface and then selectively reacted with the underlying silicon at the source, drain and polysilicon gate. After the reaction, the unreacted metal is etched off selectively by chemical etchants.
However in practice, a thin layer of metal must be used for the silicidation for two reasons. Firstly during the silicidation process, silicon is consumed as metal silicide is formed.
The thickness of silicon which is to be consumed must be equal or thicker than the deposited metal thickness, depending on the phase of silicide formed. For example, in the case of titanium silicide (TiSi2) the polysilicon thickess is double the thickness of metal. To avoid the formation of Schottky junctions with consequent junction leakage, the thickness of metal should be less than a quarter of the source and junction depths. The other reason for using a thin metal layer is to avoid the formation of silicide over sidewall oxide used to isolate the gate from the source and drain.
Any silicide over this region would electrically short the source and drain to the gate.
Thus for VLSI MOSFET circuits with source and drain junctions approaching 0.1 micron in depth, the thickness of metal used should be less than 200 angstrom units. For a polysilicon gate of about 0.3 micron thickness, the thin layer of 500 angstrom units of silicide which can be formed from 200 angstom units of metal deposited on the gate is not enough to lower the sheet resistance to the required order of about 1 ohm/square. In fact, since the lowest resistivity of silicide is of the order of 20 um ohm.cm, the sheet resistance of silicide (500 angstrom units) on polysilicon (2000 angstrom units) is higher than 4 ohm/sqare. Therefore the SALICIDE technology does not provide optimal sheet resistance of gate and interconnects for submicron devices.
To overcome these problems there is proposed according to one aspect of the present invention a process for fabricating VLSI MOS FET circuits using refractory metal and/or refractory metal silicide, the process comprising the steps of: forming a layer of gate oxide on a silicon substrate; forming a conducting gate layer on the gate oxide, the conducting gate layer having a refractory metal or refractory metal silicide content; defining a gate region in the conducting gate layer; forming source and drain regions in the substrate; and forming a thin refractory metal or silicide junction layer on the gate, source and drain regions.
The conducting gate layer can be formed by first depositing a layer of polysilicon and then depositing a layer of refractory metal or refractory metal silicide. The conducting gate layer is alternatively deposited as a single layer of refractory metal such as Mo or W or refractory metal silicide.
The refractory metal silicide can be deposited directly by one of a plurality of techniques such as co-evaporating, co-sputtering, sputtering of a composite target, or chemical vapour deposition (CVD). The refractory metal can be deposited by evaporation, sputtering or CVD.
The structure should be annealed after gate definition although the heat of subsequent oxidation and diffusion stages can also function to lower the gate sheet resistance. The gate regions within the gate conducting layer can be defined by reactive ion etching. The source and drain regions can be produced by ion implantation followed by annealing. Surface iso lating oxide regions for electricity isolating the gate from the source and drain regions can be formed by depositing an oxide layer over the wafer and etching back the oxide by reactive ion etching. Oxide is completely removed over the gate, source and drain regions but not at gate sidewall regions where the oxide is initially relatively thick.
The thin junction silicide layer formed over the source, drain and gate regions can be deposited as a refractory metal such as Ti and then sintered to form metal silicide where the metal overlies silicon. Other metals such as Co, Ni, Pt, and Pd can also be used. Unreacted metal from over the field and isolating oxide regions is subsequently dissolved. Alternatively refractory metal such as tungsten and molybdenum can be selectively deposited onto the source, drain and gate regions to shunt the sheet resistance of the underlying layer.
The refractory metal used to form the gate conducting layer can be one of the group of metals consisting of titanium, tantalum, tungsten and molybdenum. If subsequent processing is not performed at high temperatures greater than 900 C, the noble metals platinum and palladium can alternatively be used in the gate conducting layer. The thickness of the refractory metal or refractory metal silicide layer within the gate conducting layer is preferably in the range 1500 to 2500 angstrom units and the refractory metal or silicide junction layer is preferably in the range 300 to 1000 angstrom units.
Device interconnects can be formed simultaneously with the gate conducting layer.
An embodiment of the invention will now be described by way of example with reference to the accompanying drawings in which: Figure 1 is a sectional view showing a VLSI MOSFET according to the invention; and Figures 2 to 4 show successive stages in the fabrication of the Fig. 1 transistor using a fabrication technique according to the invention.
Fig. 1 shows in detail a metal-oxide-semiconductor field effect transistor (MOSFET) formed on a p-type silicon substrate 10. Isolating field oxide regions 12 are underlain by p-type regions 14. Within the substrate are n -type source and drain regions 16, 18. Extending between the source and drain regions and overlying a channel region 20 within the substrate 10 is a gate oxide layer 22. Over the gate oxide layer is a gate having a lower 2500 angstrom units thick polysilicon layer 24 and a 2500 angstrom unit thick titanium silicide upper layer 26. At side edges of the gate are isolating oxide regions 28. Laterally adjacent the oxide regions 28 are 300 angstrom units thick titanium silicide layers 30 overlying the source and drain regions 16, 18.
A corresponding thin titanium silicide layer 32 also overlies the gate.
Referring to Fig. 2, to fabricate the device, boron ions are implanted at locations 14 to establish channel stop or isolation regions and a device active area is defined by thermally oxidizing regions of the silicon substrate 10 at 10000C using a known local oxidation of silicon (LOCOS) technique. As shown in Fig. 3, the polysilicon layer 24 is then deposited by low pressure chemical vapour deposition (LPCVD) at 6250C and is doped with a phosphorus from a POCI3 gaseous source to give a sheet resistance of 40 ohm/square. Next, the titanium silicide layer 26 is deposited by DC magnetron sputtering at ambient temperature using a composite target. After annealing in argon at 9000C for 30 minutes, the combined titanium silicide/polysilicon layer yields a sheet resistance of 1 ohm/square.If MoSi2 and WSi2 are used instead of titanium silicide, a temperature of 10000C for 30 minutes is required. The resulting structure retains the properties of a polysilicon/silicon dioxide interface in that the work function of polysilicon on oxide is very well known and a smooth interface can be obtained with good oxide layer integrity. The structure is compatible with other high temperature processing steps used in the fabrication of integrated circuits. The combined silicide/polysilicon gate layer 24, 26 is then patterned in a reactive ion etching (RIE) system using a chlorine based gas etchant to define the device gate. The gate patterning can also be performed prior to annealing.
Referring to Fig. 4, shallow junction source and drain regions 16, 18 are formed at the source and drain by implanting As ions with an energy of 50 kev and a dose of 5 X 1015/cm2 followed by a subsequent annealing step for 30 minutes at 925 C. The sidewall oxide regions 28 are produced by low pressure chemical vapour depositing a 0.5 micron silicon dioxide layer over the source, drain and gate and then etching back the layer using reactive ion etching in a fluorine based plasma. Since oxide is thicker at the gate sidewalls and since material is etched vertically by reactive ion etching, then although oxide is totally removed from over the gate, the sidewall oxide portions remain.
The thin titanium silicide layer 32 is then formed by sputter depositing a 300 angstrom unit layer of titanium and then sintering the titanium layer at 600 C. Where the titanium overlies silicon at the gate, source and drain regions, a thin layer of titanium silicide is formed. Titanium which overlies field and sidewall oxide regions remains unreacted and is removed by etching with a solution composed of H2O2:NH4OH:H20 with a volume ratio of 1:1:5. After removing the unreacted titanium, the titanium silicide is again sintered at 8000C to further lower the sheet resistance.
Although in the specific embodiment described the silicide present in the gate and over the source and drain is titanium silicide, other silicides such as those of tungsten, molybdenum and tantalum can also be used and in addition to these refractory metals some noble metals such as platinum and palladium can make effective junction silicides.
Although when using titanium in the formation of the thin junction silicide layer, unreacted titanium must be removed from over the isolating oxides, the step of metal removal may be unnecessary when using other metals.
Thus for example, tungsten (W) can be chemically vapour deposited selectively over source, drain and gate from an ambient of WF6. No etching is required since no metal deposition occurs on the oxide regions.
In a further method, the silicide layer over source and drain is formed simultaneously with, and over regions accurately vertically aligned with, the source and drain regions by first depositing the layer of refractory metal and then bombarding the regions with ions of selected conductivity type at an elevated temperature. The ions, for example As+ ions in nchannel devices and BF2+ ions for p-channel devices both penetrate the silicon to form a doped source or drain region and have sufficient energy to promote interface mixing between the refractory metal and the underlying silicon with the resulting formation of silicide.
Although in the embodiment specifically described the gate conducting layer is formed by deposition and doping of a polysilicon layer followed by the deposition of a metal silicide layer, the gate conducting layer can alternatively be deposited as a single layer of refractory metal silicide of uniform composition.
Although the thin layer of metal of the junction silicide layer is consumed by the formation of silicide over the source and drain, the metal deposited onto the gate merely renders an upper layer of the gate rich in the metal. If a deposition/etch method is used then an upper metai-rich part of the gate layer may be removed when the metal overlying the oxide layers is etched away. The refractory or noble metal used in the gate silicide formation may be different from that used in the gate conducting layer.

Claims (17)

1. In a process for fabricating VLSI circuits using refractory metal silicide, the steps of: forming regions of field oxide on a semiconductor substrate; forming gate oxide within device wells defined by the field oxide; forming a conducting gate layer on the gate oxide and defining gate regions therein, the conducting gate layer having a refractory metal or refractory metal silicide content; forming source and drain regions in the semiconductor; the process characterized by forming a thin junction silicide layer (30, 32) on the source, drain and gate regions (16, 18).
2. A process as claimed in claim 1 further characterized by forming the gate layer by depositing a first layer of polysilicon (24) and a second layer of refractory metal silicide (26).
3. A process as claimed in claim 1 further characterized by forming the gate layer by depositing a refractory metal silicide.
4. A process as claimed in claim 1 further characterized by forming the gate layer by depositing onto the gate oxide a layer of a refractory metal being one of the group of refractory metals consisting of molybdenum and tungsten.
5. A process as claimed in claim 1 further characterized by forming the gate layer by depositing a first layer of polysilicon and a second layer of refractory metal which is one of the group of metals consisting of titanium, tantalum, tungsten and molybdenum.
6. A process as claimed in claim 1 further characterized by forming the silicide of the conducting gate layer by depositing layers of refractory metal and polysilicon and reacting the refractory metal with the polysilicon.
7. A process as claimed in claim 1, 2 or 3 further characterized by depositing the gate silicide layer by DC magnetron sputtering followed by annealing.
8. A process as claimed in claim 1, to 6 further characterized by defining the gate regions within the gate layer by reactive ion etching.
9. A process as claimed in any of claims 1 to 8 further characterized by forming isolating oxide regions (28) between the gate regions (24, 26) and the source and drain regions (16, 18) before the thin junction silicide layer is formed.
10. A process as claimed in claim 9 further characterized by forming the isolating oxide regions (28) between the gate regions (24, 26) and the source and drain regions (16, 18) by depositing an oxide layer over the wafer and etching back the oxide so as to completely remove the oxide over the gate (24, 26), the source (16) and the drain (18) and to leave said isolating oxide regions (28) adjacent said sidewalls.
11. A process as claimed in claim 10 further characterized by forming the junction metal silicide layer (32) by depositing a thin metal layer over the source (16), drain (18), gate (24, 26) and oxide (28) regions, sintering the thin metal layer (32) to form silicide where the metal overlies source, drain and gate and dissolving unreacted metal from over the isolating regions (28).
12. A process as claimed in claim 10 further characterized by forming the thin junction silicide layer by selectively depositing a tungsten layer over source, drain and gate only and annealing.
13. A process as claimed in any of claims 1 to 12 further characterized by producing the source and drain junctions by ion implantation and then annealing the implanted region prior to formation of the thin junction silicide layer.
14. A process as claimed in any of claims 1 to 13 further characterized in that the metal of said thin junction silicide layer (30, 32) is one of the group consisting of molybdenum, titanium, tantalum, tungsten, platinum and palladium.
15. A process as claimed in any of claims 1 to 15 further characterized in that the thickness of the gate layer (24, 26) is in the range 1000 angstrom units to 3000 angstrom units.
16. A process as claimed in any of claims 1 to 16 further characterized in that the thickness of the junction silicide layer (30, 32) is in the range 100 angstrom units to 2000 angstrom units.
17. An integrated circuit including a MOS FET having a silicon substrate, a source and drain formed in the substrate with a channel region extending therebetween and a gate overlaying the channel region and separated therefrom by an insulating layer, at least a part of the gate being a refractory metal or refractory metal silicide layer, the gate, the source and the drain having a top junction refractory metal or silicide layer, and characterized in that the gate refractory metal or silicide layer (24, 26) is of greater thickness than the junction refractory metal or refractory metal silicide layer (32).
GB8606040A 1985-06-28 1986-03-12 Vlsi mosfet circuits using refractory metal and/or refractory metal silicide Expired GB2177255B (en)

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CA000486052A CA1235824A (en) 1985-06-28 1985-06-28 Vlsi mosfet circuits using refractory metal and/or refractory metal silicide

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GB2177255A true GB2177255A (en) 1987-01-14
GB2177255B GB2177255B (en) 1989-04-26

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0295121A1 (en) * 1987-06-11 1988-12-14 General Electric Company Method for fabricating a self-aligned lightly doped drain semiconductor device with silicide
EP0319215A2 (en) * 1987-12-04 1989-06-07 AT&T Corp. Fabrication of FET integrated circuits
GB2253090A (en) * 1991-02-22 1992-08-26 Westinghouse Brake & Signal Electrical contacts for semiconductor devices
EP1149409A2 (en) * 1998-09-21 2001-10-31 Ultratech Stepper Inc. Method for forming a silicide region on a silicon body

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6266679A (en) * 1985-09-19 1987-03-26 Fujitsu Ltd Manufacture of semiconductor device

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GB2104728A (en) * 1981-08-27 1983-03-09 Western Electric Co Method of making cobalt disilicide electrode
EP0090318A2 (en) * 1982-03-30 1983-10-05 Siemens Aktiengesellschaft Process for manufacturing integrated circuits comprising MOS field-effect transistors using silicon gate technology having silicide layers on diffusion regions as low-ohmic conductors
EP0091775A2 (en) * 1982-04-08 1983-10-19 Kabushiki Kaisha Toshiba A method of manufacturing a semiconductor device comprising an interconnection layer
GB2134706A (en) * 1980-11-07 1984-08-15 Hitachi Ltd Composite conductor structure for semiconductor devices
GB2139420A (en) * 1983-05-05 1984-11-07 Standard Telephones Cables Ltd Semiconductor devices
GB2151847A (en) * 1983-12-23 1985-07-24 Hitachi Ltd Semiconductor device with metal silicide layer and fabrication process thereof.

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JPH0237093B2 (en) * 1981-01-26 1990-08-22 Tokyo Shibaura Electric Co HANDOTAISOCHINOSEIZOHOHO
JPS5799775A (en) * 1980-12-12 1982-06-21 Toshiba Corp Manufacture of semiconductor device
JPS5818965A (en) * 1981-07-28 1983-02-03 Toshiba Corp Manufacture of semiconductor device
EP0490877A3 (en) * 1985-01-22 1992-08-26 Fairchild Semiconductor Corporation Interconnection for an integrated circuit

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2134706A (en) * 1980-11-07 1984-08-15 Hitachi Ltd Composite conductor structure for semiconductor devices
GB2104728A (en) * 1981-08-27 1983-03-09 Western Electric Co Method of making cobalt disilicide electrode
EP0090318A2 (en) * 1982-03-30 1983-10-05 Siemens Aktiengesellschaft Process for manufacturing integrated circuits comprising MOS field-effect transistors using silicon gate technology having silicide layers on diffusion regions as low-ohmic conductors
EP0091775A2 (en) * 1982-04-08 1983-10-19 Kabushiki Kaisha Toshiba A method of manufacturing a semiconductor device comprising an interconnection layer
GB2139420A (en) * 1983-05-05 1984-11-07 Standard Telephones Cables Ltd Semiconductor devices
GB2151847A (en) * 1983-12-23 1985-07-24 Hitachi Ltd Semiconductor device with metal silicide layer and fabrication process thereof.

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0295121A1 (en) * 1987-06-11 1988-12-14 General Electric Company Method for fabricating a self-aligned lightly doped drain semiconductor device with silicide
EP0319215A2 (en) * 1987-12-04 1989-06-07 AT&T Corp. Fabrication of FET integrated circuits
EP0319215A3 (en) * 1987-12-04 1990-01-03 American Telephone And Telegraph Company Fabrication of fet integrated circuits
GB2253090A (en) * 1991-02-22 1992-08-26 Westinghouse Brake & Signal Electrical contacts for semiconductor devices
EP1149409A2 (en) * 1998-09-21 2001-10-31 Ultratech Stepper Inc. Method for forming a silicide region on a silicon body
EP1149409A4 (en) * 1998-09-21 2001-12-05 Ultratech Stepper Inc Method for forming a silicide region on a silicon body

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Publication number Publication date
JPS624371A (en) 1987-01-10
GB8606040D0 (en) 1986-04-16
CA1235824A (en) 1988-04-26
GB2177255B (en) 1989-04-26

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