GB2161472A - Preparing particulate ceramic materials - Google Patents

Abstract

A process for preparing a particulate ceramic material comprises (a) adding carbon dioxide or an aqueous solution of a soluble carbonate to first aqueous solution of a nitrate or chloride of at least one of Ba, Sr, Ca and Mg to adjust the pH thereof to 7 - 10 to form a carbonate precipitate; and (b) adding an aqueous solution of a soluble hydroxide to a second aqueous solution of a nitrate or chloride of at least one of Ti, Zr, Sn and Pb to adjust the pH thereof to 7 - 10 to form a hydroxide precipitate. The slurries containing the precipitates are mixed and filtered and the resultant filter cake washed with water and dried to form a powder, which is then dried and ground. The ground material is useful for making dielectric elements for capacitors. a

Description

SPECIFICATION Process for preparing particulate ceramic materials This invention relates to a process for preparing particulate raw ceramic materials having fine crystal grain sizes.

As the size of electronic devices becomes increasingly smaller, efforts are being made to reduce the size of components to be incorporated in such devices. An example of such a component is a ceramic capacitor, and since it is impossible to achieve a significant increase in dielectric constant using current technology, the only way to reduce the size of a ceramic capacitor is by decreasing its thickness. However, if the thickness of a ceramic capacitor is simply reduced, its dielectric loss is increased and a greater change in capacitance occurs as a result of changes in DC or AC bias. In particular, if the crystal grain size of the ceramic is as great as 8 Wm, relatively large voids (some may be as large as 20 uWm) occur between grains and this causes a drop in the breakdown voltage of the capacitor.

In order to reduce the thickness of a ceramic capacitor without incurring these disadvantages, the capacitor must be made of a ceramic having a finer crystal grain size. As the crystal grain size is reduced, the voids occurring between grains become smaller thus improving the breakdown voltage of the capacitor.

Desirably, the grain size should be close to 0.6 ,am which is the thickness of the 90 domain wall. This reduces the occurrence of a cubic to tetragonal transformation during a temperature lowering stage of the firing step; and also prevents the capacitance of the device from dropping as a function of time (aging). As a further advantage, the ratio of the c- to a-axis of the ceramic crystal approaches 1.00 thus reducing the change in capacitance resulting from variations in DC or AC bias. A yet further advantage is improved mechanical strength.

Conventionally, powder form raw ceramic materials are prepared by the solid-phase reaction technique using dried raw materials such as BaCO3, CaCO3, SrCO3, TiO2, ZrO2 and SnO2. One synthesis method starts with calcination of raw materials such as BaTiO3 and CaZrO3, which are mixed and subsequently fired. In another synthesis method, two or three raw materials selected from the group BaCO3, CaCO3, SrCO3, TiO2 and ZrO2 are mixed in given proportions and the mixture is calcined. However, both methods have one serious defect that is attributable to the use of dried BaCO3, CaCO3, SrCO3, TiO2 and ZrO2 as raw materials.

These materials are first subjected to a precipitation step to obtain fine colloidal particles, but when they are dried )and subsequently calcined, if so desired) after filtration, the particles agglomerate to form secondary grains having sizes between 0.5 and 2 clam. A blend of two or more raw materials comprising such agglomerated secondary particles cannot be ground to a size smaller than 1 ,m. When such a blend is formed into a suitable shape and sintered, the resulting product has crystal grains as large as 8 to 20 iim and suffers from the problems mentioned above (i.e., low breakdown voltage, and variations in capacitance with time, as well as with changes in AC and DC bias).

In order to produce a fine-grained ceramic, raw materials comprising fine colloidal grains, such as are obtained by precipitation, must be mixed. This can be realized by either the oxalate or alkoxide method.

According to the oxalate method, ions such as Ti and Ba ions are reacted with oxalic acid to precipitate barium titanyl oxalate [BaTiO(C204)-4H2O]; the precipitate is thermally decomposed to BaTiO3 at a temperature higher than 700"C. While the fineness of the grains obtained by this method is fairly satisfactory, no elements other than Ba and Ti can be precipitated simultaneously. Therefore, the oxalate method is unable to produce commercially useful multi-component ceramics. Another disadvantage that makes the oxalate method unsuitable for practical purposes is the high cost of the oxalate formed.

The alkoxide method involves difficulties in preparing alkoxides of various metals, and the alkoxidesthat can be obtained are very expensive. Another factor that reduces the commercial value of this method is the use of organic solvents, because protection must be provided against explosion of solvent vapor.

Both the oxalate and alkoxide methods depend on reactions in solution, but in the absence of a crystal growth inhibitor, the grains growto sizes between about 1 and 2 m during sintering. These methods provide fine primary particles but, since they cannot be agglomerated to larger secondary particles, a large amount of binder must be used to agglomerate the fine primary particles. As a result, however, the shaped material shrinks so greatly during firing that the desired ceramic product cannot be produced.

In short, the conventional techniques for preparing raw ceramic materials are defective in that they satisfy non, or only some, of the requirements mentioned below: (1) all the components for making a composite system are precipitated by a reaction in solution, and the growth of crystal grains can be restrained as required; (2) the respective raw materials can be mixed in solution; (3) the fine primary grains can be agglomerated to secondary particles in order to reduce the use of a binder in the forming step; and (4) the desired raw ceramic materials can be prepared safely and at a low cost.

A principal aim of the present invention is to provide a process for preparing fine-grained raw ceramic materials which does not suffer from the defects of the conventional techniques.

A preferred form of the present invention for preparing particulate ceramic material comprises the steps of (a) adding carbon dioxide or an aqueous solution of a soluble carbonate such as sodium carbonate or ammonium carbonate to a first aqueous solution of a nitrate or chloride of one or more of Ba, Sr, Ca and Mg in a first vessel to adjust the pH of said first aqueous solution to between 7 and 10 thereby forming a carbonate precipitate; (b) adding an aqueous solution of a soluble hydroxide such as sodium hydroxide or ammonium hydroxide to a second aqueous solution of a nitrate or chloride of one or more Ti, Zr, Sn and Pb in a second vessel to adjust the pH of said second aqueous solution to between 7 and 10 thereby forming a hydroxide precipitate; (c) combining slurries containing the precipitates so formed in said first and second vessels; (d) mixing the combined slurries;; (e) passing the slurries through a filter; (f) washing the filter cake with water; (g) drying the filter cake to form a powder; (h) calcining the dried pwder; and (i) grinding the calcined powder.

Preferably, at least one more element selected from the group Nb, Y and rare earth metals may be used in the second vessel. This is effective in regulating the crystal growth during sintering and provides grains of a size not more than 1 am.

The other advantage of these crystal growth regulators is that they work as depressors to flatten the peak value of the dielectric constant (which occurs at about 1200for BaTiO3). Among the rare earth metals, cesium (Ce) and neodymium (Nd) are weak depressors and are rather effective for the purpose of obtaining high dielectric constant values. Lanthanum (La) and niobium (Nb) are effective in flattening the temperature characteristics of dielectric constant, and for this purpose, Nb is particularly effective. Niobium naturally occurs as a mixture with tantalum (Ta), but the tantalum as an impurity will not impair the effectiveness of Nb greatly. Therefore, a mixture of Nb and Ta may be used in the present invention.

In a more preferred embodiment, another element selected from the group Mn, Al, Si, bi and Zn may be incorporated in the second vessel as a mineralizer. Other elements that are suitable mineralizers include Fe, Cr, Co and Cu.

The invention will now be more fully described with reference to the accompanying drawings in which: Figure lisa schematic representation of a secondary grain obtained by the process of the present invention; Figure 2 is a micrograph of the surface of an article prepared according to the present invention; Figure 3 is a micrograph of the polished surface of a laminated ceramic capacitor element fabricated according to the present invention; Figure 4 is a micrograph of the polished surface of a laminated ceramic capacitor element fabricated from a powder prepared by the conventional solid-phase sintering technique; Figures 5 /aJ and 5 (b) 5(b) show the temperature characteristics of the dielectric dissipation factor (tan 8) and percentage change of the dielectric constant of laminated ceramic capacitors;; Figure 6shows the percentage change in capacitance upon application of AC bias voltage; Figure 7shows the percentage change in capacitance upon application of DC bias voltage; and Figure 8 shows the aging characteristics of capacitance.

According to the process of the present invention, the first and second vessels are charged with predetermined proportions of raw materials; after thorough precipitation, the resulting slurries are mixed; and the mixture is calcined and ground to provide a particulate raw ceramic material having the intended proportions of the respective components.

The mixture of slurries precipitated in the first step comprises primary particles adjacent to each other having sizes between about 0.01 and 0.02 pm. In a subsequent step, the mixture is passed through a filter, washed with water and dried to provide an active material wherein the respective raw materials intermingle in a colloidal and hence highly reactive state.

This material is then calcined, thereby providing a raw ceramic material of ABO3 type having predetermined proportions of components. The agglomeration of the primary particles to secondary grains also occurs in the calcining step. A ceramic material comprising secondary particles has a smaller specific surface area (m2/gr) and requires less binder for making a green sheet. The reduced use of a binder leads to a smaller shrinkage during the firing of the shaped ceramic product. Each secondary particle consists of a mixture of the primary particles of the respective raw materials, so the ceramic obtained by firing the shaped material comprises sufficiently fine particles (1-2 CLm). In other words, the agglomeration of primary particles to secondary particles will do no harm to the purpose of obtaining fine-grained ceramic product.A typical secondary grain is illustrated in Figure 1; a single secondary grain (1) consists of more than one primary particle (2).

The calcination is preferably carried out in the temperature range of 700 to 1 ,200 C. If the calcination temperature is less than 700"C, the desired powder of raw ceramic material is not synthesized. If the temperature exceeds 1 ,200 C, the agglomeration to secondary particles becomes excessive.

The powder form raw ceramic material as obtained by the process of the present invention is generally an oxide of ABO3 type. However, this does not mean that the precipitates formed in the first and second vessels correspond to A and B, respectively. The criteria for selecting the constituent elements used in the respective vessels are as follows: the elements used in the first vessel are such that they can be precipitated as carbonate; and those used in the second vessel are such that they can be precipitated as hydroxide.

The alkalinity in the second vessel is controlled to result in a pH within the range of 7 to 10. Outside this range, the constituent elements used will dissolve out and fail to form a precipitate. The pH value used in the first vessel is preferably in agreement with the value used in the second vessel. This is in order to achieve the following two objects: the slurries containing the precipitates formed in the first and second vessels and which are to be mixed should have the same pH value, and the hydroxide precipitated in the second vessel should not dissolve out as a result of mismatch with the pH in the first vessel.

An aqueous solution of hydrogen peroxide (H202) may be added to the second vessel as a stabilizer which serves to prevent precipitation due to the hydrolysis of the solution. In the presence of aqueous H2O2, Ti, Zr, Ce and Mn are precipitated as Ti(OOH) (OH)3, Zr(OOH) (OH)3, Ce (OH)3 and Mn(OH)4, respectively. Such precipitates have the advantage of facilitating filtration and washing operations in the subsequent step.

Analysis of the molar ratio of A to B in the powder of raw ceramic material of ABO3 type prepared by the process of the present invention revealed that as the content of B increased, the crystal grain size increased to form interstitial gaps between adjacent grains. For the purpose of the present invention, the preferred A two Bmolarratio ranges from 1.00:1.00 to 1.00:1.05.

The advantages of the present invention will become more apparent by reading the following non-limiting working Examples.

Example 1 The following starting materials were used.

Compounds Weight F9) BaCt2 100 TiCt4 71.58 Snot4 8.379 SiCe4 0.7469 MnCt4 4H2O 0.273 In a first vessel, ammonium carbonate [(NH4)2CO3] was added to an aqueous solution of Back2 to adjust the pH of the mixture to between 9 and 9.5 for providing a BaCO3 precipitate.

The second vessel was charged with a mixture of aqueous solutions of Tic4, Snot4, SiCt4 and MnCt4 4H2O. After adding 15 mt of a stabilizer (30% aqueous H2O2), ammonium hydroxide (NH40H) was added to adjust the pH of the mixture to between 9 and 9.5 for producing a precipitate containing Ti, Sn, Si and Mn.

The slurries containing the precipitates formed in the two vessels were combined and the mixture was subjected to filtration and washing with water. The filter cake was crushed in a ball mill, passed through a filter and dried to provide a fine-grained (0.02 Fm) raw ceramic material.

This material was calcined at 900"C for 1 hour to provide a Ba(TiSn)O3 powder. The powder was granulated in the presence of a binder (polyvinyl alcohol) and formed into a disk (diameter: 10 mm+, thickness: 1 mm) at a pressure of 1,000 kg/cm2. The disk was then fired at 1,300 C for 2 hours to form a disk-shaped article. A coating of silver paste was applied to both sides of this ceramic product to form electrodes. This product was then baked at 8000C for 30 minutes to produce a capacitor.

The dielectric constant (e) and dielectric dissipation factor (tan 8) of this capacitor were measured at 1 KHz and 1 Vr.m.s. The temperature characteristics of its dielectric constant (TC) were determined for the temperature range of +10"C to +85"C on the basis of the value at +250C. The results are shown in the following table together with the breakdown voltage.

tan 8 TC Breakdown Voltage { /0) (kvimm) 18,000 2.0 +20~+70% 35 Example 2 The following starting materials were used.

Compounds Weight (%) BaCl2 100 SrCt2 1.85 MgCl2 0.84 TiCl4 72.26 SnCl4 3.17 ZrOCt2 8H2O 9.19 MnCt2 4H2O 0.84 CeCt3 1.43 ZnCt2 0.33 In the first vessel, aqueous solutions of BaCl2, SrCl2, MgCt2 and CeCt3 were mixed. To the mixture, sodium carbonate (Na2CO3) was added to adjust the pH of the mixture to between 9 and 9.5 for forming BaCO3, SrCO3, MgCO3 and CeCO3 precipitates.

The second vessel was charged with a mixture of aqueous solutions of TiCl4, SnCl4, ZrOCl2.8H2O, MnCl2-4H2O and ZnCt2. After adding 15 me of a stabilizer (30% aqueous H2O2), sodium hydroxide (NaOH) was added to adjust the pH of the mixture to between 9 and 9.5 for producing a precipitate containing Ti, Sn, Zr, Mn and Zn.

The slurries containing the precipitates formed in the two vessels were combined and the mixture was subjected to filtration and washing with water. The filter cake was crushed in a ball mili, passed through a filter and dried to provide a fine-grained (0.02 pm) raw ceramic material.

This material was calcined at 900 C for 1 hour to provide a (BaSrMg) (TiSnZr)O3 powder. The powder was treated as in Example 1 to produce a capacitor except that the firing temperature was 1,150 C. The capacitor had the following electrical properties.

tan 8 TC Breakdown voltage {o/O) (kvlmm) 6,000 1.5 +15% ~ 38 38 -48% Example 3 The following starting materials were used.

Compounds Weight (g) Ba(NO3)2 100 Ca(NO3)2 4H2O 7.848 Ticl4 73.206 ZrOCt2 8H2O 10.68 SnCt4 0.8436 Bi(NO3)3-5H2O 1.0488 Pb(NO3)2 1.0827 Sm(NO3)3 6H2O 0.255 The first vessel was charged with a mixture of aqueous solutions of Ba(NO3)2 and Ca(NO3)2-4H2O. To the mixture, sodium carbonate (Na2CO3) was added under bubbling of carbon dioxide (CO2) to adjust the pH of the mixture to between 7 and 10 for providing BaCO3 and CaCO3 precipitates.

The second vessel was charged with a mixture of aqueous solutions of Ticl4, ZrOCt2-8H2O, SnCt4, Bi(NO3)3-5H2O, Pb(NO3)2 and Sm(NO3)3-6H2O. After adding 15 me of a stabilizer (30% aqueous H2O2), sodium hydroxide (NaOH) was added to adjust the pH of the mixture to between 7 and 10 for producing a precipitate containing Ti, Zr, Sn, Bi, Pb and Sm.

The slurries containing the precipitates formed in the two vessels were combined and the mixture was subjected to filtration and washing with water. The filter cake was crushed in a ball mill, passed through a filter and dried to provide a fine-grained (0.015 m) raw ceramic material.

This material was calcined at 800 C for 1 hour to provide a (Ba, Ca, Pb) (Ti, Zr, Sn, Bi)O3 powder. The powder was treated as in Example 1 to produce a capacitor except that the firing temperature was 1,120 C.

The capacitor had the following electrical properties.

E tan 3 TC Breakdown voltage (O/o) rkvimm) 7,900 1.5 + 10% ~ 40 40 -49% A laminated capacitor was also fabricated from the calcined fine-grained raw ceramic material by the following procedure. First, a binder and a dispersantwere kneaded into the powder to form a paste. A dielectric ceramic layer 20 m thick was formed from this paste by the printing technique. Onto this layer, a coating of Ag-Pd (weight ratio, 70:30) paste was printed as an internal electrode. This was repeated to form 10 laminations of the dielectric ceramic layer. The resulting laminated structure was fired at 1,1 200C for 2 hours, and an electrode for external connection was formed on both sides of the structure.A laminated capacitor measuring 4 mm x 3 mm x 0.15 mm resulted, and it had a static capacitance of 0.43 FF. Each of the dielectric ceramic layers fired had a thickness of 12 Fm.

Example 4 The following starting materials were used.

Compounds Weight (g) BaCt2 2H2O 15.195 NdCt3 6H2O 103.38 TiCt4 61.227 Bi(NO3)3 5H2O 19.425 MnCt4 4H2O 0.29 SiCt4 0.27 In the first vessel, ammonium carbonate [(NH4)2CO3] was added to an aqueous solution of BaCt2-2H2O so as to adjust the pH of the mixture to between 9 and 9.5 for providing a BaCO3 precipitate.

The second vessel was charged with a mixture of aqueous solutions of NdC.6H2O, Ticl4, Bi(NO3)3-5H2O, MnCt4-5H2O, MnCt4-4H2O and Sicl4. After adding 10 mb of a stabilizer (30% aqueous H2O2), ammonium hydroxide (NH40H) was added to adjust the pH of the mixture to between 9 and 9.5 for producing a precipitate containing Nd, Ti, Bi, Mn and Si.

The slurries containing the precipitates formed in the two vessels were combined and the mixture was subjected to filtration and washing with water. The filter cake was crushed in a ball mill, passed through a filter and dried to provide a fine-grained (0.01 m) raw ceramic material.

This material was calcined at 800 C for 1 hour to provide a Ba(Nd, Ti, Bi)O7 powder. The powder was treated as in Example 1 except that the firing temperature was 1,100 C. The resulting capacitor was checked for its electrical properties as in Example 1, except that the temperature characteristics (TC) of the dielectric constant were determined for the temperature range of -55 to +125 C, on the basis of the value at +25 C.

e tan 3 TC Breakdown Voltage p/o) (kvlmm) 90 0.01 + % 75 Example 5 The following starting materials were used.

Compounds Weight (g) CaCt2 58.482 TiCt4 100 Nb2Ct5 17.805 In the first vessel, sodium carbonate (Na2CO3) was added to an aqueous solution of CaCt2 so as to adjust the pH of the mixture to between 9 and 9.5 for providing a CaCO3 precipitate.

The second vessel was charged with a mixture of aqueous solutions of TiCt4 and Nb2C5. After adding 25 mt of a stabilizer (30% aqueous H2O2), sodium hydroxide (NaOH) was added to adjust the pH of the mixture to between 9 and 9.5 for providing a precipitate containing Ti and Nb.

The slurries containing the precipitates formed in the two vessels were combined and the mixture was subjected to filtration and washing with water. The filter cake was crushed in a ball mill, passed through a filter and dried to provide a fine-grained (0.01 pm) raw ceramic material.

This material was calcined at 800"C for 1 hour to provide a Ca(Ti, Nb)O3 powder. The powder was treated as in Example 1 except that the firing temperature was 1,1 000C, and the resulting capacitor was checked for its electrical properties as in Example 1, except that the temperature characteristics (TC) of the dielectric constant were determined for the range of -55 to + 125 C on the basis of the value at +25"C.

tan 3 TC Breakdown Voltage p/O) zppml C) (kvlmm) 150 0.02 780 68 Example 6 The following starting materials were used.

Compounds Weight (g) BaCt2 2H2O 53.17 TiCt4 41.29 CeCl3 2.32 ZrOCW2-8H2O 3.04 MnCt2 4H2O 0.18 In the first vessel, ammonium carbonate [(NH4)2CO3] was added to an aqueous solution of BaCt2-2H2O so as to adjust the pH of the mixture to between 9 and 9.5 for producing a BaCO3 precipitate.

The second vessel was charged with a mixture of aqueous solutions of Tic4, CeC43, ZrOC42-8H2O and MnC.4H2O. After adding 10 mt of a stabilizer (30% aqueous H2O2), ammonium hydroxide (NH40H) was added to adjust the pH of the mixture to between 9 and 9.5 for producing a precipitate containing Ti, Ce, Zr and Mn. In Example 6, Ce was added as both a crystal growth regulator and depressor.

The slurries containing the precipitates formed in the two vessels were combined, and the mixture was subjected to filtration and washing with water. The filter cake was crushed in a ball mill to provide fine grains of sizes between 0.01 and 0.02,am. They were subsequently filtered, dired and calcined at 1,000 C for 1 hour.

A binder (polyvinyl acetate) and a solvent (toluene) were kneaded into the calcined powder to form a slurry. A green ceramic sheet was made of this slurry by doctor blading, and a coating of palladium paste was printed on the green sheet to form an internal electrode. Thirty green sheets with the palladium coat were stacked one on top of another and thermally bonded to form an integrai structure. It was fired in air at 1,300"C for 2 hours to fabricate a laminated ceramic capacitor element.

Observation of the surface of the ceramic article with a microscope showed that the crystal grains in the ceramic were in the range of 0.8 and 1.0 ijm. A micrograph of the surface of the ceramic article is shown in Figure 2.

A cross section was cut from the capacitor element and polished. A micrograph of the polished surface is shown in Figure 3, from which one can see that the capacitor element prepared from the raw ceramic powder obtained in Example 6 had fewer pores.

A comparative laminated ceramic capacitor element was prepared from a calcined powder obtained by the conventional solid phase sintering technique. A cross section was cut from this element and polished. A micrograr; of the polished surface is shown in Figure 4, from which one can see the presence of more pores than in low cross section shown in Figure 3.

An electrode for external connection was formed on both sides of the laminated capacitor element of the present invention to fabricate laminated ceramic capacitors.

The dielectric constant (E) of the capacitors was in the range of 10,000 to 11,000. The temperature characteristics of the dielectric dissipation factor (tan 8) and the percent change of dielectric constant are shown in Figures 5 (a) and (b), respectively.

The percent changes in capacitance of the samples upon application of AC and DC bias voltages are shown in the graphs of Figures 6 and 7, respectively.

The aging characteristics of capacitance are depicted in the graph of Figure 8.

The temperature characteristics of the dielectric dissipation factor (tan 8) and percent change of dielectric constant, as well as the change in capacitance due to applications of AC and DC bias voltages were also measured for the comparative samples and are shown by dashed lines in Figures 5 (a), (b), Figures 6 and 7, respectively.

The dielectric dissipation factor (tan 3) of the comparative samples was 3.58%, and their aging characteristics of capacitance were in the range of 7 to 8%.

Claims (10)

1. A process for preparing particulate raw ceramic material comprising the steps of: (a) adding carbon dioxide or an aqueous solution of a soluble carbonate to first aqueous solution of a nitrate or chloride of one or more of Ba, Sr, Ca and Mg to adjust the pH of said first aqueous solution to between 7 and 10, thereby forming a carbonate precipitate; (b) adding an aqueous solution of a soluble hydroxide to a second aqueous solution of a nitrate or chloride of one or more of Ti, Zr, Sn and Pb to adjust the pH of said second aqeuous solution to between 7 and 10, thereby forming a hydroxide precipitate; (c) mixing slurries containing the respective precipitates, and calcining and grinding the mixed precipitate.

2. A process for preparing particulate raw ceramic material comprising the steps of: (a) adding carbon dioxide or an aqueous solution of a soluble carbonate to first aqueous solution of a nitrate or chloride of one or more of Ba, Sr, Ca and Mg to adjust the pH of said first aqueous solution to between 7 and 10, thereby forming a carbonate precipitate; (b) adding an aqueous solution of a soluble hydroxide to a second aqueous solution of a nirate or chloride of one or more of Ti, Zr, Sn and Pb to adjust the pH of said second aqueous solution to between 7 and 10, thereby forming a hydroxide precipitate; (c) combining slurries containing the precipitates formed from said first and second solutions; (d) mixing the combined slurries; (e) passing the slurries through a filter; (f) washing the resultant filter cake with water;; (g) drying the filter cake to form a powder; (h) calcining the dried powder; and (i) grinding the calcined powder.

3. A process according to Claim 1 or 2, wherein the first aqueous solution of nitrate or chloride further contains at least one element selected from Nb, Y and rare earth metals.

4. A process according to Claim 1, 2 or 3, wherein the second aqueous solution of nitrate or chloride further contains at least one element selected from Mn, Al, Si, Bi and Zn.

5. A process according to any preceding Claim, wherein the powder is calcined at a temperature in the range of from 700 to 1,200"C.

6. A process according to Claim 1 and substantially as herein described.

7. A process for preparing a particulate raw ceramic material substantially as herein described in any one of Examples 1 to 6 but not in any comparative parts thereof.

8. A particulate raw ceramic material when produced by a process as claimed in any preceding ciaim.

9. A capacitor having a dielectric element produced from a material as claimed in Claim 9.

10. The features as herein disclosed, or their equivalents in any patentable novel selection.